Abstract
The three types of dispersions, emulsions, microemulsions, and foams, are all stabilized by adsorbed layers of surface-active substances. The role of these layers will be discussed at length, because they are central in the behavior of dispersions. Adsorption layers make the link between the different dispersions; they are at the origin of numerous similarities encountered between them. The basic knowledge will be recalled in this chapter, starting with the simplest case of interfaces between pure fluids. More details can be found in classical textbooks (Adamson and Gast 1997; Evans and Wennerström 1999; de Gennes et al. 2004).
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References
Adamson, A. W., & Gast, A. P. (1997). Physical chemistry of surfaces (6th ed.). New York: Wiley.
Alexandrov, N. A., Marinova, K. G., Gurkov, T. D., Danov, K. D., Kralchevsky, P. A., Stoyanov, S. D., Blijdenstein, T. B., Arnaudov, L. N., Pelan, E. G., & Lips, A. (2012). Interfacial layers from the protein HFBII hydrophobin: Dynamic surface tension, dilatational elasticity and relaxation times. Journal of Colloid and Interface Science, 376, 296–306. https://doi.org/10.1016/j.jcis.2012.03.031.
Alvarez, G., Poteau, S., Argillier, J.-F., Langevin, D., & Salager, J.-L. (2009). Heavy oil-water interfacial properties and emulsion stability: Influence of dilution. Energy & Fuels, 23(1), 294–299. https://doi.org/10.1021/ef800545k.
Andelman, D., Brochard, F., Knobler, C., & Rondelez, F. (1994). Structure and phase transitions in monolayers. In W. M. Gelbart, A. Ben-Shaul, & D. Roux (Eds.), Micelles, membranes, microemulsions and monolayers (pp. 559–602). New York: Springer.
Arriaga, L. R., Drenckhan, W., Salonen, A., Rodrigues, J. A., Iniguez-Palomares, R., Rio, E., & Langevin, D. (2012a). On the long-term stability of foams stabilised by mixtures of nano-particles and oppositely charged short chain surfactants. Soft Matter, 8(43), 11085–11097. https://doi.org/10.1039/c2sm26461g.
Arriaga, L. R., Monroy, F., & Langevin, D. (2012b). The polymer glass transition in nanometric films. European Physics Letters, 98(3), 38007. https://doi.org/10.1209/0295-5075/98/38007.
Arriaga, L. R., Varade, D., Carriere, D., Drenckhan, W., & Langevin, D. (2013). Adsorption, organization, and rheology of catanionic layers at the air/water interface. Langmuir, 29(10), 3214–3222. https://doi.org/10.1021/la304868n.
Aumaitre, E., Vella, D., & Cicuta, P. (2011). On the measurement of the surface pressure in Langmuir films with finite shear elasticity. Soft Matter, 7(6), 2530–2537. https://doi.org/10.1039/c0sm01213k.
Bain, C. D. (2008). The overflowing cylinder sixty years on. Advances in Colloid and Interface Science, 144(1–2), 4–12. https://doi.org/10.1016/j.cis.2008.08.006.
Bain, C. D., Claesson, P. M., Langevin, D., Meszaros, R., Nylander, T., Stubenrauch, C., Titmuss, S., & von Klitzing, R. (2010). Complexes of surfactants with oppositely charged polymers at surfaces and in bulk. Advances in Colloid and Interface Science, 155(1–2), 32–49. https://doi.org/10.1016/j.cis.2010.01.007.
Barthès-Biesel, D., Diaz, A., & Dhenin, E. (2002). Effect of constitutive laws for two-dimensional membranes on flow-induced capsule deformation. Journal of Fluid Mechanics, 460, 211–222. https://doi.org/10.1017/s0022112002008352.
Benjamins, J., Feijter, J. A. D., Evans, M. T. A., Graham, D. E., & Phillips, M. C. (1975). Dynamic and static properties of proteins adsorbed at air-water-interface. Faraday Discussions, 59, 218–229. https://doi.org/10.1039/dc9755900218.
Bernardini, C., Stoyanov, S. D., Arnaudov, L. N., & Stuart, M. A. C. (2013). Colloids in Flatland: A perspective on 2D phase-separated systems, characterisation methods, and lineactant design. Chemical Society Reviews, 42(5), 2100–2129. https://doi.org/10.1039/c2cs35269a.
Binks, B. P. (2007). Colloidal particles at liquid interfaces. Physical Chemistry Chemical Physics, 9(48), 6298–6299. https://doi.org/10.1039/b716587k.
Blijdenstein, T. B. J., de Groot, P. W. N., & Stoyanov, S. D. (2010). On the link between foam coarsening and surface rheology: Why hydrophobins are so different. Soft Matter, 6(8), 1799–1808. https://doi.org/10.1039/b925648b.
Bonfillon, A., Sicoli, F., & Langevin, D. (1994). Dynamic surface tension of ionic surfactant solutions [Article]. Journal of Colloid and Interface Science, 168(2), 497–504.
Boussinesq, J. (1913). On the existence of a superficial viscosity grade, in the thin layer of transition which separates a liquid from another adjacent fluid. Annales de Chimie et de Physique, 29, 349–357.
Braslau, A., Deutsch, M., Pershan, P. S., Weiss, A. H., Alsnielsen, J., & Bohr, J. (1985). Surface-roughness of water measured by x-ray reflectivity. Physical Review Letters, 54(2), 114–117. https://doi.org/10.1103/PhysRevLett.54.114.
Brosseau, Q., Vrignon, J., & Baret, J. C. (2014). Microfluidic dynamic interfacial tensiometry (μ DIT). Soft Matter, 10(17), 3066–3076. https://doi.org/10.1039/c3sm52543k.
Buff, F. P., Lovett, R. A., & Stillinger, F. H. (1965). Interfacial density profile for fluids in critical region. Physical Review Letters, 15(15), 621–623. https://doi.org/10.1103/PhysRevLett.15.621.
Cagna, A., Esposito, G., Quinquis, A. S., & Langevin, D. (2018). On the reversibility of asphaltene adsorption at oil-water interfaces. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 548, 46–53. https://doi.org/10.1016/j.colsurfa.2018.03.038.
Caruso, B., Mangiarotti, A., & Wilke, N. (2013). Stiffness of lipid monolayers with phase coexistence. Langmuir, 29(34), 10807–10816. https://doi.org/10.1021/la4018322.
Checco, A., Guenoun, P., & Daillant, J. (2003). Nonlinear dependence of the contact angle of nanodroplets on contact line curvature. Physical Review Letters, 91(18). https://doi.org/10.1103/PhysRevLett.91.186101.
Cohen-Stuart, M. A., & Kleijn, J. M. (2001). Kinetics of polyelectrolyte adsorption. In T. Radeva (Ed.), Physical chemistry of polyelectrolytes (pp. 281–304). New York: Marcel Dekker.
Colegate, D. M., & Bain, C. D. (2005). Adsorption kinetics in micellar solutions of nonionic surfactants. Physical Review Letters, 95(19), 198302. https://doi.org/10.1103/PhysRevLett.95.198302.
Danov, K. D., Radulova, G. M., Kralchevsky, P. A., Golemanov, K., & Stoyanov, S. D. (2012). Surface shear rheology of hydrophobin adsorption layers: Laws of viscoelastic behaviour with applications to long-term foam stability. Faraday Discussions, 158, 195–221. https://doi.org/10.1039/c2fd20017a.
de Gennes, P. G. (1979). Scaling concepts in polymers physics. Ithaca: Cornell University Press.
de Gennes, P. G. (1987). Polymers at an interface – A simplified view. Advances in Colloid and Interface Science, 27(3–4), 189–209. https://doi.org/10.1016/0001-8686(87)85003-0.
de Gennes, P.-G., Brochard-Wyart, F., & Quéré, D. (2004). Capillarity and wetting phenomena. New York: Springer.
Diamant, H., & Andelman, D. (1996). Kinetics of surfactant adsorption at fluid-fluid interfaces. Journal of Physical Chemistry, 100(32), 13732–13742.
Dickinson, E. (1998). Proteins at interfaces and in emulsions – Stability, rheology and interactions. Journal of the Chemical Society-Faraday Transactions, 94(12), 1657–1669. https://doi.org/10.1039/a801167b.
Dickinson, E. (1999). Adsorbed protein layers at fluid interfaces: Interactions, structure and surface rheology. Colloids and Surfaces B-Biointerfaces, 15(2), 161–176. https://doi.org/10.1016/s0927-7765(99)00042-9.
Dillmann, P., Maret, G., & Keim, P. (2012). Comparison of 2D melting criteria in a colloidal system. [Article]. Journal of Physics-Condensed Matter, 24(46), 464118. https://doi.org/10.1088/0953-8984/24/46/464118.
Dimitrijev-Dwyer, M., & Middelberg, A. P. J. (2011). The extensional viscoelasticity of protein-coated interfaces. Soft Matter, 7(17), 7772–7781. https://doi.org/10.1039/c1sm05253e.
Djabbarah, N. F., & Wasan, D. T. (1982). Dilational viscoelastic properties of fluid interfaces. 3. Mixed surfactant systems. Chemical Engineering Science, 37(2), 175–184. https://doi.org/10.1016/0009-2509(82)80152-8.
Edwards, D. A., Brenner, H., & Wasan, D. T. (1991). Interfacial transport processes and rheology. Butterworth-Heinemann.
Erwin, B. M., Rogers, S. A., Cloitre, M., & Vlassopoulos, D. (2010). Examining the validity of strain-rate frequency superposition when measuring the linear viscoelastic properties of soft materials. Journal of Rheology, 54(2), 187–195. https://doi.org/10.1122/1.3301247.
Ese, M. H., Galet, L., Clausse, D., & Sjoblom, J. (1999). Properties of Langmuir surface and interfacial films built up by asphaltenes and resins: Influence of chemical demulsifiers. Journal of Colloid and Interface Science, 220(2), 293–301. https://doi.org/10.1006/jcis.1999.6549.
Espinosa, G., & Langevin, D. (2009). Interfacial shear rheology of mixed polyelectrolyte-surfactant layers. Langmuir, 25(20), 12201–12207. https://doi.org/10.1021/la901730f.
Evans, F., & Wennerström, W. (1999). The colloidal domain (2nd ed.). New York: Wiley.
Evans, E., Rawicz, W., & Smith, B. A. (2013). Concluding remarks back to the future: Mechanics and thermodynamics of lipid biomembranes. Faraday Discussions, 161(0), 591–611. https://doi.org/10.1039/c2fd20127e.
Franklin, B. (1773). From Benjamin Franklin to William Brownrigg, 7 November 1773. https://founders.archives.gov/documents/Franklin/01-20-02-0250. [Original source:The Papers of Benjamin Franklin , Vol. 20, January 1 through December 31, 1773, New Haven and London: Yale University Press, 1976, pp. 463–474.]
Freer, E. M., Yim, K. S., Fuller, G. G., & Radke, C. J. (2004). Interfacial rheology of globular and flexible proteins at the hexadecane/water interface: Comparison of shear and dilatation deformation. Journal of Physical Chemistry B, 108(12), 3835–3844. https://doi.org/10.1021/jp037236k.
Freer, E. M., Wong, H., & Radke, C. J. (2005). Oscillating drop/bubble tensiometry: Effect of viscous forces on the measurement of interfacial tension. Journal of Colloid and Interface Science, 282(1), 128–132. https://doi.org/10.1016/j.jcis.2004.08.058.
Fuller, G. G., & Vermant, J. (2012). Complex fluid-fluid interfaces: Rheology and structure. In J. M. Prausnitz (Ed.), Annual review of chemical and biomolecular engineering (Vol. 3, pp. 519–543).
Gaines, G. (1966). Insoluble monolayers at liquid-gas interfaces. New York: Interscience.
Georgieva, D., Cagna, A., & Langevin, D. (2009a). Link between surface elasticity and foam stability. Soft Matter, 5(10), 2063–2071. https://doi.org/10.1039/b822568k.
Georgieva, D., Schmitt, V., Leal-Calderon, F., & Langevin, D. (2009b). On the possible role of surface elasticity in emulsion stability. Langmuir, 25(10), 5565–5573. https://doi.org/10.1021/la804240e.
Gibbs, J. W. (1928). The collected works (Vol. 1). London: Longmans, Green and co.
Golemanov, K., Denkov, N. D., Tcholakova, S., Vethamuthu, M., & Lips, A. (2008a). Surfactant mixtures for control of bubble surface mobility in foam studies. Langmuir, 24(18), 9956–9961. https://doi.org/10.1021/la8015386.
Golemanov, K., Tcholakova, S., Denkov, N., Ananthapadmanabhan, K., & Lips, A. (2008b). Breakup of bubbles and drops in steadily sheared foams and concentrated emulsions. Physical Review E, 78(5), 051405.
Goodrich, F. C. (1981). The theory of capillary excess viscosities. Proceedings of the Royal Society of London Series A-Mathematical Physical and Engineering Sciences, 374(1758), 341–370.
Gourier, C., Daillant, J., Braslau, A., Alba, M., Quinn, K., Luzet, D., Blot, C., Chatenay, D., Grübel, G., Legrand, J.-F., & Vignaud, G. (1997). Bending energy of amphiphilic films at the nanometer scale. Physical Review Letters, 78(16), 3157–3160.
Hauner, I. M., Deblais, A., Beattie, J. K., Kellay, H., & Bonn, D. (2017). The dynamic surface tension of water. Journal of Physical Chemistry Letters, 8(7), 1599–1603. https://doi.org/10.1021/acs.jpclett.7b00267.
He, Y., Shang, Y., Liu, H., Langevin, D., & Salonen, A. (2012). Surfactant adsorption onto interfaces: Measuring the surface excess in time. Langmuir, 28(6), 3146–3151. https://doi.org/10.1021/la2047454.
He, Y., Yazhgur, P., Salonen, A., & Langevin, D. (2015). Adsorption-desorption kinetics of surfactants at liquid surfaces. Advances in Colloid and Interface Science, 222, 377–384. https://doi.org/10.1016/j.cis.2014.09.002.
Hegemann, J., Knoche, S., Egger, S., Kott, M., Demand, S., Unverfehrt, A., Regage, H., & Kierfeld, J. (2018). Pendant capsule elastometry. Journal of Colloid and Interface Science, 513, 549–565. https://doi.org/10.1016/j.jcis.2017.11.048.
Helfrich, W. (1973). Elastic properties of lipid bilayers – Theory and possible experiments. Zeitschrift Fur Naturforschung C-A Journal of Biosciences, C, 28(11–1), 693–703.
Horozov, T. S., Binks, B. P., Aveyard, R., & Clint, J. H. (2006). Effect of particle hydrophobicity on the formatlon and collapse of fumed silica particle monolayers at the oil-water interface. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 282, 377–386. https://doi.org/10.1016/j.colsurfa.2005.11.085.
Hotrum, N. E., Stuart, M. A. C., van Vliet, T., & van Aken, G. A. (2003). Flow and fracture phenomena in adsorbed protein layers at the air/water interface in connection with spreading oil droplets. Langmuir, 19(24), 10210–10216. https://doi.org/10.1021/la035188p.
Israelachvili, J. N., Mitchell, D. J., & Ninham, B. W. (1976). Theory of self assembly of hydrocarbon amphiphiles into micelles and bilayers. Journal of the Chemical Society-Faraday Transactions II, 72, 1525–1568.
Jaensson, N., & Vermant, J. (2018). Tensiometry and rheology of complex interfaces. Current Opinion in Colloid & Interface Science, 37, 136–150. https://doi.org/10.1016/j.cocis.2018.09.005.
Jayalakshmi, Y., Ozanne, L., & Langevin, D. (1995). Viscoelasticity of surfactant monolayers. Journal of Colloid and Interface Science, 170(2), 358–366.
Jeribi, M., Almir-Assad, B., Langevin, D., Henaut, I., & Argillier, J. F. (2002). Adsorption kinetics of asphaltenes at liquid interfaces. Journal of Colloid and Interface Science, 256(2), 268–272. https://doi.org/10.1006/jcis.2002.8660.
Joly, M. (1964). Chapter 1 – Surface Viscosity. In J. F. Danielli, K. G. A. Pankhurst, & A. C. Riddiford (Eds.), Recent progress in surface science (Vol. 1, pp. 1–50). Elsevier.
Kim, Y. H., & Wasan, D. T. (1996). Effect of demulsifier partitioning on the destabilization of water-in-oil emulsions. Industrial & Engineering Chemistry Research, 35(4), 1141–1149. https://doi.org/10.1021/ie950372u.
Klix, C. L., Maret, G., & Keim, P. (2015). Discontinuous shear modulus determines the glass transition temperature. Physical Review X, 5(4), 041033. https://doi.org/10.1103/PhysRevX.5.041033.
Knoche, S., Vella, D., Aumaitre, E., Degen, P., Rehage, H., Cicuta, P., & Kierfeld, J. (2013). Elastometry of deflated capsules: Elastic moduli from shape and wrinkle analysis. Langmuir, 29(40), 12463–12471. https://doi.org/10.1021/la402322g.
Kovalchuk, V. I., Aksenenko, E. V., Makievski, A. V., Fainerman, V. B., & Miller, R. (2019). Dilational interfacial rheology of tridecyl dimethyl phosphine oxide adsorption layers at the water/hexane interface. Journal of Colloid and Interface Science, 539, 30–37. https://doi.org/10.1016/j.jcis.2018.12.019.
Kramer, L. (1971). Theory of light scattering from fluctuations of membranes and monolayers. Journal of Chemical Physics, 55(5), 2097–2105. https://doi.org/10.1063/1.1676380.
Kwak, J. C. T. (Ed.). (1998). Polymer-surfactant systems (Vol. 77). New York/Basel: Marcel Dekker.
Kwan, J. J., & Borden, M. A. (2012). Lipid monolayer collapse and microbubble stability. Advances in Colloid and Interface Science, 183, 82–99. https://doi.org/10.1016/j.cis.2012.08.005.
Landau, L., & Lifshitz, E. (1959). Theory of elasticity. Addison Wesley.
Landau, L., & Lifshitz, E. M. (1980). Statistical physics, chapter XII. Pergamon Press.
Langevin, D. (Ed.). (1992a). Light scattering by liquid surfaces and complementary techniques. New York: Marcel Dekker.
Langevin, D. (1992b). Adsorbed monolayers. In D. Langevin (Ed.), Light scattering by liquid surfaces and complementary techniques (Vol. 41, pp. 161–201). New York: Marcel Dekker.
Langevin, D. (1992c). Multiphase microemulsion systems. In Light scattering by liquid surfaces and complementary techniques (Vol. 41, pp. 233–264). New York: Marcel Dekker.
Langevin, D. (1992d). Thin liquid films. In D. Langevin (Ed.), Light scattering by liquid surfaces and complementary techniques (Vol. 41, pp. 265–286). New York: Marcel Dekker.
Langevin, D., & Argillier, J. F. (2016). Interfacial behavior of asphaltenes. Advances in Colloid and Interface Science, 233, 83–93. https://doi.org/10.1016/j.cis.2015.10.005.
Langevin, D., & Monroy, F. (2010). Interfacial rheology of polyelectrolytes and polymer monolayers at the air-water interface. Current Opinion in Colloid & Interface Science, 15(4), 283–293. https://doi.org/10.1016/j.cocis.2010.02.002.
Larson, R. G. (1999). The structure and rheology of complex fluids. New York: Oxford University Press.
Lee, L. T., Mann, E. K., Langevin, D., & Farnoux, B. (1991). Neutron reflectivity and ellipsometry studies of a polymer molecular layer spread on the water-surface. Langmuir, 7(12), 3076–3080.
Lee, L. T., Mann, E. K., Guiselin, O., Langevin, D., Farnoux, B., & Penfold, J. (1993). Polymer surfactant films at the air-water-interface. 2. A neutron reflectivity study. Macromolecules, 26(25), 7046–7052.
Lee, S., Kim, D. H., & Needham, D. (2001a). Equilibrium and dynamic interfacial tension measurements at microscopic interfaces using a micropipet technique. 1. A new method for determination of interfacial tension. Langmuir, 17(18), 5537–5543. https://doi.org/10.1021/la0103259.
Lee, S., Kim, D. H., & Needham, D. (2001b). Equilibrium and dynamic interfacial tension measurements at microscopic interfaces using a micropipet technique. 2. Dynamics of phospholipid monolayer formation and equilibrium tensions at water-air interface. Langmuir, 17(18), 5544–5550. https://doi.org/10.1021/la0103261.
Lee, Y. C., Stebe, K. J., Liu, H. S., & Lin, S. Y. (2003). Adsorption and desorption kinetics of CmE8 on impulsively expanded or compressed air-water interfaces. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 220(1–3), 139–150. https://doi.org/10.1016/s0927-7757(03)00075-x.
Lemaire, C., & Langevin, D. (1992). Longitudinal surface waves at liquid interfaces. Measurement of monolayer viscoelasticity. Colloids and Surfaces, 65(2–3), 101–112.
Levich, V. G. (1962). Physicochemical Hydrodynamics. Englewoods Cliffs: Prentice Hall.
Lingwood, D., & Simons, K. (2010). Lipid rafts as a membrane-organizing principle. Science, 327(5961), 46–50. https://doi.org/10.1126/science.1174621.
Lu, J. R., Hromadova, M., Thomas, R. K., & Penfold, J. (1993). Direct determination by neutron reflection of the structure of triethylene glycol monododecyl ether layers at the air/water interface. Langmuir, 9(9), 2417–2425.
Lu, J. R., Purcell, I. P., Lee, E. M., Simister, E. A., Thomas, R. K., Rennie, A. R., & Penfold, J. (1995). The composition and structure of sodium dodecyl-sulfate dodecanol mixtures adsorbed at the air-water-interface – A neutron reflection study. Journal of Colloid and Interface Science, 174(2), 441–455. https://doi.org/10.1006/jcis.1995.1412.
Lucassen, J., & Hansen, R. S. (1967). Damping of waves on monolayer-covered surfaces. 2. Influence of bulk-to-surface diffusional interchange on ripple characteristics. Journal of Colloid and Interface Science, 23(3), 319. https://doi.org/10.1016/0021-9797(67)90175-0.
Mackie, A. R., Gunning, A. P., Wilde, P. J., & Morris, V. J. (1999). Orogenic displacement of protein from the air/water interface by competitive adsorption. Journal of Colloid and Interface Science, 210(1), 157–166. https://doi.org/10.1006/jcis.1998.5941.
Maldonado-Valderrama, J., Wege, H. A., Rodriguez-Valverde, M. A., Galvez-Ruiz, M. J., & Cabrerizo-Vilchez, M. A. (2003). Comparative study of adsorbed and spread beta-casein monolayers at the water-air interface with the pendant drop technique. Langmuir, 19(20), 8436–8442. https://doi.org/10.1021/la034242z.
Maldonado-Valderrama, J., Galvez-Ruiz, M. J., Martin-Rodriguez, A., & Cabrerizo-Vilchez, M. A. (2004). Adsorbed and spread beta-casein monolayers at oil-water interfaces. Langmuir, 20(15), 6093–6095. https://doi.org/10.1021/la0498307.
Mamatkulov, S. I., Allolio, C., Netz, R. R., & Bonthuis, D. J. (2017). Orientation-induced adsorption of hydrated protons at the air-water interface. Angewandte Chemie-International Edition, 56(50), 15846–15851. https://doi.org/10.1002/anie.201707391.
Mann, E. K., Henon, S., Langevin, D., & Meunier, J. (1992). Molecular layers of a polymer at the free-water surface – Microscopy at the brewster-angle. Journal de Physique II, 2(9), 1683–1704.
Maru, H. C., & Wasan, D. T. (1979). Dilational viscoelastic properties of fluid interfaces. 2. Experimental study. Chemical Engineering Science, 34(11), 1295–1307.
Mecke, K. R., & Dietrich, S. (1999). Effective Hamiltonian for liquid-vapor interfaces. Physical Review E, 59(6), 6766–6784. https://doi.org/10.1103/PhysRevE.59.6766.
Meunier, J. (1992). Light reflectivity and ellipsometry. In D. Langevin (Ed.), Light scattering by liquid surfaces and complementary techniques (pp. 333–364). New York: Dekker, M.
Miller, R., Wustneck, R., Kragel, J., & Kretzschmar, G. (1996). Dilational and shear rheology of adsorption layers at liquid interfaces. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 111(1–2), 75–118.
Miyano, K. (1992). Externally excited surface waves. In D. Langevin (Ed.), Light scattering by liquid surfaces and complementary techniques (pp. 311–331). New York: Dekker, M.
Mora, S., Daillant, J., Mecke, K., Luzet, D., Braslau, A., Alba, M., & Struth, B. (2003). X-ray synchrotron study of liquid-vapor interfaces at short length scales: Effect of long-range forces and bending energies. Physical Review Letters, 90(21), 216101. https://doi.org/10.1103/PhysRevLett.90.216101.
Murray, B. S., & Nelson, P. V. (1996). A novel Langmuir trough for equilibrium and dynamic measurements oil air-water and oil-water monolayers. Langmuir, 12(25), 5973–5976. https://doi.org/10.1021/la960748o.
Mysels, K. J. (1982). Diffusion-controlled adsorption kinetics. General solution and some applications. The Journal of Physical Chemistry, 86(23), 4648–4651. https://doi.org/10.1021/j100220a036.
Nagata, Y., Ohto, T., Bonn, M., & Kuhne, T. D. (2016). Surface tension of ab initio liquid water at the water-air interface. Journal of Chemical Physics, 144(20), 204705. https://doi.org/10.1063/1.4951710.
Neubauer, M. P., Poehlmann, M., & Fery, A. (2014). Microcapsule mechanics: From stability to function. Advances in Colloid and Interface Science, 207, 65–80. https://doi.org/10.1016/j.cis.2013.11.016.
Noskov, B. A. (1996). Fast adsorption at the liquid-gas interface. Advances in Colloid and Interface Science, 69, 63–129. https://doi.org/10.1016/s0001-8686(96)00308-9.
Ortega, F., Ritacco, H., & Rubio, R. G. (2010). Interfacial microrheology: Particle tracking and related techniques. Current Opinion in Colloid & Interface Science, 15(4), 237–245. https://doi.org/10.1016/j.cocis.2010.03.001.
Pagureva, N., Tcholakova, S., Golemanov, K., Denkov, N., Pelan, E., & Stoyanov, S. D. (2016). Surface properties of adsorption layers formed from triterpenoid and steroid saponins. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 491, 18–28. https://doi.org/10.1016/j.colsurfa.2015.12.001.
Pallas, N. R., & Pethica, B. A. (1987). The liquid vapor transition in monolayers of normal-pentadecanoic acid at the air-water-interface. Journal of the Chemical Society-Faraday Transactions I, 83, 585–590. https://doi.org/10.1039/f19878300585.
Patist, A., Kanicky, J. R., Shukla, P. K., & Shah, D. O. (2002). Importance of micellar kinetics in relation to technological processes. Journal of Colloid and Interface Science, 245(1), 1–15. https://doi.org/10.1006/jcis.2001.7955.
Pauchard, V., Rane, J. P., Zarkar, S., Couzis, A., & Banerjee, S. (2014). Long-term adsorption kinetics of asphaltenes at the oil-water interface: A random sequential adsorption perspective. Langmuir, 30(28), 8381–8390. https://doi.org/10.1021/la500384r.
Peliti, L., & Leibler, S. (1985). Effects of thermal fluctuations on systems with small surface tension. Physical Review Letters, 54(15), 1690–1693.
Petkov, J. T., Gurkov, T. D., Campbell, B. E., & Borwankar, R. P. (2000). Dilatational and shear elasticity of gel-like protein layers on air/water interface. Langmuir, 16(8), 3703–3711.
Pieper, G., Rehage, H., & Barthes-Biesel, D. (1998). Deformation of a capsule in a spinning drop apparatus. Journal of Colloid and Interface Science, 202(2), 293–300. https://doi.org/10.1006/jcis.1998.5438.
Pugh, R. J., Weissenborn, P., & Paulson, O. (1997). Flotation in inorganic electrolytes; the relationship between recover of hydrophobic particles, surface tension, bubble coalescence and gas solubility. International Journal of Mineral Processing, 51(1–4), 125–138. https://doi.org/10.1016/s0301-7516(97)00021-5.
Radke, C. J. (2015). Gibbs adsorption equation for planar fluid-fluid interfaces: Invariant formalism. Advances in Colloid and Interface Science, 222, 600–614. https://doi.org/10.1016/j.cis.2014.01.001.
Reynaert, S., Brooks, C. F., Moldenaers, P., Vermant, J., & Fuller, G. G. (2008). Analysis of the magnetic rod interfacial stress rheometer. Journal of Rheology, 52(1), 261–285. https://doi.org/10.1122/1.2798238.
Ritacco, H., Cagna, A., & Langevin, D. (2006). Oscillating bubble measurements of the compression viscoelasticity of mixed surfactant-polyelectrolyte surface layers. Colloids and Surfaces A-Physicochemical and Engineering Aspects, 282, 203–209. https://doi.org/10.1016/j.colsurfa.2005.11.088.
Ritacco, H., Langevin, D., Diamant, D., & Andelman, D. (2011). Dynamic surface tension of aqueous solutions of ionic surfactants: Role of electrostatics. Langmuir, 27, 1009–1014.
Rowlinson, J. S., & Widom, B. (1982). Molecular theory of capillarity. Oxford: Clarendon Press.
Sackmann, E. (1994). Membrane bending energy concept of vesicle-shape and cell-shape and shape-transitions. FEBS Letters, 346(1), 3–16. https://doi.org/10.1016/0014-5793(94)00484-6.
Saint-Jalmes, A., & Gallet, F. (1998). Buckling in a solid Langmuir monolayer: Light scattering measurements and elastic model. European Physical Journal B, 2(4), 489–494. https://doi.org/10.1007/s100510050272.
Samaniuk, J. R., Hermans, E., Verwijlen, T., Pauchard, V., & Vermant, J. (2015). Soft-glassy rheology of asphaltenes at liquid interfaces. Journal of Dispersion Science and Technology, 36(10), 1444–1451. https://doi.org/10.1080/01932691.2015.1022654.
Sasaki, T., Hattori, M., Sasaki, J., & Nukina, K. (1975). Studies of aqueous sodium dodecyl-sulfate solutions by activity measurements. Bulletin of the Chemical Society of Japan, 48(5), 1397–1403. https://doi.org/10.1246/bcsj.48.1397.
Schwartz, D. K., Knobler, C. M., & Bruinsma, R. (1994). Direct observation of Langmuir monolayer flow through a channel. Physical Review Letters, 73(21), 2841–2844.
Schwierz, N., Horinek, D., Sivan, U., & Netz, R. R. (2016). Reversed Hofmeister series – The rule rather than the exception. Current Opinion in Colloid & Interface Science, 23, 10–18. https://doi.org/10.1016/j.cocis.2016.04.003.
Scriven, L. E. (1960). Dynamics of a fluid interface. Equation of motion for newtonian surface fluids. Chemical Engineering Science, 12(2), 98–108. https://doi.org/10.1016/0009-2509(60)87003-0.
Simister, E. A., Thomas, R. K., Penfold, J., Aveyard, R., Binks, B. P., Cooper, P., Fletcher, P., Lu, J. R., & Sokolowski, A. (1992). Comparison of neutron reflection and surface-tension measurements of the surface excess of tetradecyltrimethylammonium bromide layers at the air-water-interface. Journal of Physical Chemistry, 96(3), 1383–1388. https://doi.org/10.1021/j100182a066.
Speight, J. G. (2004). Petroleum asphaltenes – Part 1 – Asphaltenes, resins and the structure of petroleum. Oil & Gas Science and Technology-Revue de l’IFP Energies Nouvelles, 59(5), 467–477. https://doi.org/10.2516/ogst:2004032.
Stocco, A., Garcia-Moreno, F., Manke, I., Banhart, J., & Langevin, D. (2011a). Particle-stabilised foams: Structure and aging. Soft Matter, 7(2), 631–637. https://doi.org/10.1039/c0sm00166j.
Stocco, A., Rio, E., Binks, B. P., & Langevin, D. (2011b). Aqueous foams stabilized solely by particles. Soft Matter, 7(4), 1260–1267. https://doi.org/10.1039/c0sm01290d.
Style, R. W., Jagota, A., Hui, C. Y., & Dufresne, E. R. (2017). Elastocapillarity: Surface tension and the mechanics of soft solids. In M. C. Marchetti & S. Sachdev (Eds.), Annual review of condensed matter physics (Vol. 8, pp. 99–118).
Taylor, C. D., Valkovska, D. S., & Bain, C. D. (2003). A simple and rapid method for the determination of the surface equations of state and adsorption isotherms for efficient surfactants. Physical Chemistry Chemical Physics, 5, 4885–4891.
Tokiwa, Y., Sakamoto, H., Takiue, T., Aratono, M., Matsubara, H., & Bain, C. D. (2018). Effect of surface freezing on stability of oil-in-water emulsions. Langmuir, 34(21), 6205–6209. https://doi.org/10.1021/acs.langmuir.8b01088.
Uematsu, Y., Bonthuis, D. J., & Netz, R. R. (2019). Impurity effects at hydrophobic surfaces. Current Opinion in Electrochemistry, 13, 166–173. https://doi.org/10.1016/j.coelec.2018.09.003.
Vandebril, S., Franck, A., Fuller, G. G., Moldenaers, P., & Vermant, J. (2010). A double wall-ring geometry for interfacial shear rheometry. Rheologica Acta, 49(2), 131–144. https://doi.org/10.1007/s00397-009-0407-3.
Vollhardt, D. (2006). Nucleation in monolayers. Advances in Colloid and Interface Science, 123-126, 173–188. https://doi.org/10.1016/j.cis.2006.05.025.
Vollhardt, D. (2014). Brewster angle microscopy: A preferential method for mesoscopic characterization of monolayers at the air/water interface. Current Opinion in Colloid & Interface Science, 19(3), 183–197. https://doi.org/10.1016/j.cocis.2014.02.001.
Vollhardt, D., & Fainerman, V. B. (2010). Characterisation of phase transition in adsorbed monolayers at the air/water interface. Advances in Colloid and Interface Science, 154(1), 1–19. https://doi.org/10.1016/j.cis.2010.01.003.
Vora, S. R., Bognet, B., Patanwala, H. S., Young, C. D., Chang, S. Y., Daux, V., & Ma, A. W. K. (2018). Global strain field mapping of a particle-laden interface using digital image correlation. Journal of Colloid and Interface Science, 509, 94–101. https://doi.org/10.1016/j.jcis.2017.08.082.
Ward, A. F. H., & Tordai, L. (1946). Time-dependence of boundary tensions of solutions I. The role of diffusion in time-effects. The Journal of Chemical Physics, 14(7), 453–461.
Wyss, H. M., Miyazaki, K., Mattsson, J., Hu, Z. B., Reichman, D. R., & Weitz, D. A. (2007). Strain-rate frequency superposition: A rheological probe of structural relaxation in soft materials. Physical Review Letters, 98(23), 238303. https://doi.org/10.1103/PhysRevLett.98.238303.
Xie, K. L., de Loubens, C., Dubreuil, F., Gunes, D. Z., Jaeger, M., & Leonetti, M. (2017). Interfacial rheological properties of self-assembling biopolymer microcapsules. Soft Matter, 13(36), 6208–6217. https://doi.org/10.1039/c7sm01377a.
Xu, R., Dickinson, E., & Murray, B. S. (2008). Morphological changes in adsorbed protein films at the oil−water interface subjected to compression, expansion, and heat processing. Langmuir, 24(5), 1979–1988. https://doi.org/10.1021/la702806t.
Yan, C., Angus-Smyth, A., & Bain, C. D. (2013). Adsorption kinetics of non-ionic surfactants in micellar solutions: Effects of added charge. Faraday Discussions, 160, 45–61. https://doi.org/10.1039/c2fd20118f.
Zamora, J. M., Marquez, R., Forgiarini, A. M., Langevin, D., & Salager, J.-L. (2018). Interfacial rheology of low interfacial tension systems using a new oscillating spinning drop method. Journal of Colloid and Interface Science, 519, 27–37. https://doi.org/10.1016/j.jcis.2018.02.015.
Zang, D. Y., Rio, E., Langevin, D., Wei, B., & Binks, B. P. (2010). Viscoelastic properties of silica nanoparticle monolayers at the air-water interface. European Physical Journal E, 31(2), 125–134. https://doi.org/10.1140/epje/i2010-10565-7.
Zang, D. Y., Rio, E., Delon, G., Langevin, D., Wei, B., & Binks, B. P. (2011). Influence of the contact angle of silica nanoparticles at the air-water interface on the mechanical properties of the layers composed of these particles. Molecular Physics, 109(7–10), 1057–1066. https://doi.org/10.1080/00268976.2010.542778.
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Langevin, D. (2020). Interfaces Between Two Fluids. In: Emulsions, Microemulsions and Foams. Soft and Biological Matter. Springer, Cham. https://doi.org/10.1007/978-3-030-55681-5_1
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