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Applications of the Porous Structures Obtained with the Breath-Figures Self-Assembly

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Breath Figures

Abstract

Applications of the microporous polymer structures obtained with the breath-figures self-assembly are surveyed. Breath-figures self-assembly, being inexpensive, robust, technologically flexible method, enables a broad diversity of the engineering applications, including manufacturing of superhydrophobic surfaces, arrays of microlenses, membranes, and bio-interfaces. Hierarchical honeycomb reliefs manufactured with the breath-figures self-assembly enable manufacturing of interfaces with prescribed wettability varying from omniphobicity to superhydrophilicity. Breath-figures self-assembly enabled inexpensive manufacturing of photonic crystals and arrays of quantum dots. Micropatterned surfaces manufactured with the breath-figures self-assembly are promising for tissue engineering. Pore distribution inherent for the honeycomb breath-figures-inspired relief has a pronounced effect on the living cells’ morphology. Highly efficient antibacterial surfaces based on bacterial/cell size selective microporous supports manufactured with the breath-figures self-assembly were reported. Breath-figures method has been successfully exploited for the fabrication of membranes, sensors, microfluidic reactors, and catalytic surfaces.

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References

  1. Yabu, H. 2018. Fabrication of honeycomb films by the breath figure technique and their applications. Science Technology of Advanced Materials 19 (1): 802–822.

    CAS  Google Scholar 

  2. Bormashenko, E.Y. 2018. Wetting of real surfaces. Vol. 19. Berlin: Walter de Gruyter GmbH & Co KG.

    Google Scholar 

  3. Brown, P.S., et al. 2012. Superhydrophobic hierarchical honeycomb surfaces. Langmuir 28 (38): 13712–13719.

    CAS  Google Scholar 

  4. Yabu, H., et al. 2005. Superhydrophobic and lipophobic properties of self-organized honeycomb and pincushion structures. Langmuir 21 (8): 3235–3237.

    CAS  Google Scholar 

  5. Kamei, J., and H. Yabu. 2015. On-demand liquid transportation using bioinspired omniphobic lubricated surfaces based on self-organized Honeycomb and Pincushion films. Advanced Functional Materials 25 (27): 4195–4201.

    CAS  Google Scholar 

  6. Kim, J., B. Lew, and W.S. Kim. 2011. Facile fabrication of super-hydrophobic nano-needle arrays via breath figures method. Nanoscale Research Letters 6 (1): 616.

    Google Scholar 

  7. Farbod, F., B. Pourabbas, and M. Sharif. 2013. Direct breath figure formation on PMMA and superhydrophobic surface using in situ perfluoro-modified silica nanoparticles. Journal of Polymer Science Part B: Polymer Physics 51 (6): 441–451.

    CAS  Google Scholar 

  8. Bormashenko, E., et al. 2006. Micrometrically scaled textured metallic hydrophobic interfaces validate the Cassie–Baxter wetting hypothesis. Journal of Colloid and Interface Science 302 (1): 308–311.

    CAS  Google Scholar 

  9. Feng, L., et al. 2008. Petal effect: A superhydrophobic state with high adhesive force. Langmuir 24 (8): 4114–4119.

    CAS  Google Scholar 

  10. Bormashenko, E., et al. 2009. “Petal effect” on surfaces based on lycopodium: High-stick surfaces demonstrating high apparent contact angles. The Journal of Physical Chemistry C 113 (14): 5568–5572.

    CAS  Google Scholar 

  11. Bhushan, B., and M. Nosonovsky. 2010. The rose petal effect and the modes of superhydrophobicity. Philosophical Transactions of the Royal Society A: Mathematical, Physical Engineering Sciences 368 (1929): 4713–4728.

    CAS  Google Scholar 

  12. Ishii, D., H. Yabu, and M. Shimomura. 2009. Novel biomimetic surface based on a self-organized metal− polymer hybrid structure. Chemistry of Materials 21 (9): 1799–1801.

    CAS  Google Scholar 

  13. Ishii, D., and M. Shimomura. 2013. Invisible gates for moving water droplets: Adhesive force gradients on a biomimetic superhydrophobic surface. Chemistry of Materials 25 (3): 509–513.

    CAS  Google Scholar 

  14. Kamei, J., Y. Saito, and H. Yabu. 2014. Biomimetic ultra-bubble-repellent surfaces based on a self-organized honeycomb film. Langmuir 30 (47): 14118–14122.

    CAS  Google Scholar 

  15. Bormashenko, E., et al. 2014. Polysulfone membranes demonstrating asymmetric diode-like water permeability and their applications. Macromolecular Materials and Engineering 299 (1): 27–30.

    CAS  Google Scholar 

  16. Guo, T., et al. 2015. Ordered porous structure hybrid films generated by breath figures for directional water penetration. RSC Advances 5 (107): 88471–88476.

    CAS  Google Scholar 

  17. Yabu, H., and M. Shimomura. 2005. Simple fabrication of micro lens arrays. Langmuir 21 (5): 1709–1711.

    CAS  Google Scholar 

  18. Wu, C.Y., T.H. Chiang, and C.C. Hsu. 2008. Fabrication of microlens array diffuser films with controllable haze distribution by combination of breath figures and replica molding methods. Optics Express 16 (24): 19978–19986.

    CAS  Google Scholar 

  19. Jenekhe, S.A., and X.L. Chen. 1999. Self-assembly of ordered microporous materials from rod-coil block copolymers. Science 283 (5400): 372–375.

    CAS  Google Scholar 

  20. Joannopoulos, J.D., P.R. Villeneuve, and S. Fan. 1997. Photonic crystals. Solid State Communications 102 (2–3): 165–173.

    CAS  Google Scholar 

  21. Haupt, M., et al. 2004. Breath figures: Self-organizing masks for the fabrication of photonic crystals and dichroic filters. Journal of Applied Physics 96 (6): 3065–3069.

    CAS  Google Scholar 

  22. Bormashenko, E., et al. 2005. Self-assembled honeycomb polycarbonate films deposited on polymer piezoelectric substrates and their applications. Polymers for Advanced Technologies 16 (4): 299–304.

    CAS  Google Scholar 

  23. Samanta, S., et al. 2011. Multifunctional porous poly (vinylidene fluoride)-graft-poly (butyl methacrylate) with good Li+ ion conductivity. Macromolecular Chemistry 212 (2): 134–149.

    CAS  Google Scholar 

  24. Vohra, V., et al. 2009. Multilevel organization in hybrid thin films for optoelectronic applications. Langmuir 25 (20): 12019–12023.

    CAS  Google Scholar 

  25. Wang, J., et al. 2012. Multifunctional ionomer-derived honeycomb-patterned architectures and their performance in light enhancement of light-emitting diodes. Journal of Materials Chemistry 22 (9): 4089–4096.

    CAS  Google Scholar 

  26. Fan, D., et al. 2013. Honeycomb-patterned fluorescent films fabricated by self-assembly of surfactant-assisted porphyrin/polymer composites. Journal of Colloid Interface Science 402: 146–150.

    CAS  Google Scholar 

  27. Wang, D.-M., and J.-Y. Lai. 2013. Recent advances in preparation and morphology control of polymeric membranes formed by nonsolvent induced phase separation. Current Opinion in Chemical Engineering 2 (2): 229–237.

    Google Scholar 

  28. Cong, H., et al. 2012. Preparation of a highly permeable ordered porous microfiltration membrane of brominated poly (phenylene oxide) on an ice substrate by the breath figure method. Soft Matter 8 (34): 8835–8839.

    CAS  Google Scholar 

  29. Yu, B., et al. 2015. Fabrication of highly ordered porous membranes of cellulose triacetate on ice substrates using breath figure method. Journal of Polymer Science Part B: Polymer Physics 53 (8): 552–558.

    CAS  Google Scholar 

  30. Sakatani, Y., et al. 2007. Coupling nanobuilding block and breath figures approaches for the designed construction of hierarchically templated porous materials and membranes. Chemistry of Materials 20 (3): 1049–1056.

    Google Scholar 

  31. Gugliuzza, A., V. Pingitore, and E. Drioli. 2016. Relationships between structure and electrical sensing of breathable membranes. Materials Today: Proceedings 3 (2): 308–312.

    Google Scholar 

  32. Tripathi, B.K., and P. Pandey. 2014. Breath figure templating for fabrication of polysulfone microporous membranes with highly ordered monodispersed porosity. Journal of Membrane Science 471: 201–210.

    CAS  Google Scholar 

  33. Yuan, H., et al. 2016. Preparation of highly permeable BPPO microfiltration membrane with binary porous structures on a colloidal crystal substrate by the breath figure method. Journal of Colloid Interface Science 461: 232–238.

    CAS  Google Scholar 

  34. Ruan, X., et al. 2018. Facile fabrication of reinforced homoporous MF membranes by in situ breath figure and thermal adhesion method on substrates. Journal of Membrane Science 554: 291–299.

    CAS  Google Scholar 

  35. Bormashenko, E., et al. 2013. Electrically controlled membranes exploiting Cassie-Wenzel wetting transitions. Scientific Reports 3: 3028.

    Google Scholar 

  36. Cong, H., et al. 2012. Preparation of a highly permeable ordered porous microfiltration membrane of brominated poly(phenylene oxide) on an ice substrate by the breath figure method. Soft Matter 8 (34): 8835–8839.

    CAS  Google Scholar 

  37. Sakatani, Y., et al. 2008. Coupling nanobuilding block and breath figures approaches for the designed construction of hierarchically templated porous materials and membranes. Chemistry of Materials 20 (3): 1049–1056.

    CAS  Google Scholar 

  38. Li, J., et al. 2011. Preparation of honeycomb porous solid oxide fuel cell cathodes by breath figures method. International Journal of Hydrogen Energy 36 (13): 7641–7648.

    CAS  Google Scholar 

  39. Zhang, N., et al. 2011. Preparation of honeycomb porous La0. 6Sr0. 4Co0. 2Fe0. 8O3− δ–Gd0. 2Ce0. 8O2− δ composite cathodes by breath figures method for solid oxide fuel cells. Applied Surface Science 258 (1): 50–57.

    CAS  Google Scholar 

  40. Bormashenko, E., et al. 2012. Honeycomb structures obtained with breath figures self-assembly allow water/oil separation. Colloids Surfaces A: Physicochemical Engineering Aspects 415: 394–398.

    CAS  Google Scholar 

  41. Miller, S., and Z. Bao. 2015. Fabrication of flexible pressure sensors with microstructured polydimethylsiloxane dielectrics using the breath figures method. Journal of Materials Research 30 (23): 3584–3594.

    CAS  Google Scholar 

  42. Galeotti, F., W. Mróz, and A. Bolognesi. 2011. CdTe nanocrystal assemblies guided by breath figure templates. Soft Matter 7 (8): 3832–3836.

    CAS  Google Scholar 

  43. Böker, A., et al. 2004. Hierarchical nanoparticle assemblies formed by decorating breath figures. Nature Materials 3 (5): 302.

    Google Scholar 

  44. Lee, B.-H., et al. 2015. Direct observation of a carbon filament in water-resistant organic memory. ACS Nano 9 (7): 7306–7313.

    CAS  Google Scholar 

  45. Abbaspour, M., et al. 2017. Solid-state supercapacitor based on breath figured polymethyl methacrylate deposited by graphene: The effect of electrode surface. Journal of Materials Science: Materials in Electronics 28 (19): 14121–14130.

    CAS  Google Scholar 

  46. Kim, Y.W., J.K.R. Modigunta, and U. Male. 2019. Effect of ferrocene on the fabrication of honeycomb-patterned porous polystyrene films and silver functionalization of the film. Polymer 166: 55–62.

    CAS  Google Scholar 

  47. Yu, C., et al. 2008. Water-assisted self-assembly of polyaniline/Fe3O4 composite honeycomb structures film. Thin Solid Films 516 (15): 5107–5110.

    CAS  Google Scholar 

  48. Male, U., and B.K. Shin. 2017. Graphene oxide incorporated poly (ε-caprolactone) honeycomb-patterned porous polymer films by the breath figure method. Macromolecular Research 25 (3): 297–302.

    CAS  Google Scholar 

  49. Zhou, W., et al. 2016. Copper mesh templated by breath-figure polymer films as flexible transparent electrodes for organic photovoltaic devices. ACS Applied Materials & Interfaces 8 (17): 11122–11127.

    CAS  Google Scholar 

  50. Mir, S.H., and B. Ochiai. 2018. Conductive polymer-Ag Honeycomb thin film: The factors affecting the complexity of the microstructure. Journal of the Electrochemical Society 165 (8): B3030–B3034.

    CAS  Google Scholar 

  51. Martínez-Campos, E., et al. 2016. Toward cell selective surfaces: Cell adhesion and proliferation on breath figures with antifouling surface chemistry. ACS Applied Materials & Interfaces 8 (10): 6344–6353.

    Google Scholar 

  52. Kawano, T., et al. 2014. Honeycomb-shaped surface topography induces differentiation of human mesenchymal stem cells (hMSCs): Uniform porous polymer scaffolds prepared by the breath figure technique. Biomaterials Science 2 (1): 52–56.

    CAS  Google Scholar 

  53. Tsukiyama, S., et al. 2008. Enhanced cell survival and yield of rat small hepatocytes by honeycomb-patterned films. Japanese Journal of Applied Physics 47 (2S): 1429.

    CAS  Google Scholar 

  54. Tsuruma, A., et al. 2008. Control of neural stem cell differentiation on honeycomb films. Colloids Surfaces A: Physicochemical Engineering Aspects 313: 536–540.

    Google Scholar 

  55. Carlomagno, C., et al. 2019. Breath figures decorated silicon oxinitride ceramic surfaces with controlled Si ions release for enhanced osteoinduction. Journal of Biomedical Materials Research Part B: Applied Biomaterials 107 (4): 1284–1294.

    CAS  Google Scholar 

  56. Calejo, M.T., et al. 2018. Breath figures in tissue engineering and drug delivery: State-of-the-art and future perspectives. Acta Biomaterialia 66: 44–66.

    CAS  Google Scholar 

  57. Manabe, K., S. Nishizawa, and S. Shiratori. 2013. Porous surface structure fabricated by breath figures that suppresses Pseudomonas aeruginosa biofilm formation. ACS Applied Materials & Interfaces 5 (22): 11900–11905.

    CAS  Google Scholar 

  58. Zhao, Y., et al. 2015. Nanostructured 2D diporphyrin honeycomb film: Photoelectrochemistry, photodegradation, and antibacterial activity. ACS Applied Materials Interfaces 7 (22): 11783–11791.

    CAS  Google Scholar 

  59. Muñoz-Bonilla, A., et al. 2018. Antimicrobial porous surfaces prepared by breath figures approach. Materials 11 (8): 1266.

    Google Scholar 

  60. Vargas-Alfredo, N., et al. 2017. Highly efficient antibacterial surfaces based on bacterial/cell size selective microporous supports. ACS Applied Materials & Interfaces 9 (51): 44270–44280.

    CAS  Google Scholar 

  61. Huang, C., et al. 2019. Hybrid breath figure method: A new insight in Petri dishes for cell culture. Journal of Colloid Interface Science 541: 114–122.

    CAS  Google Scholar 

  62. Connal, L.A., G.V. Franks, and G.G. Qiao. 2010. Photochromic, metal-absorbing honeycomb structures. Langmuir 26 (13): 10397–10400.

    CAS  Google Scholar 

  63. Kojima, M., et al. 2010. Photo-patterning of honeycomb films prepared from amphiphilic copolymer containing photochromic spiropyran. Chemical Communications 46 (22): 3970–3972.

    CAS  Google Scholar 

  64. Wan, L.-S., et al. 2012. Patterned biocatalytic films via one-step self-assembly. Chemical Communications 48 (37): 4417–4419.

    CAS  Google Scholar 

  65. De León, A.S., et al. 2015. Enzymatic catalysis combining the breath figures and layer-by-layer techniques: Toward the design of microreactors. ACS Applied Materials & Interfaces 7 (22): 12210–12219.

    Google Scholar 

  66. ———. 2017. Microfluidic reactors based on rechargeable catalytic porous supports: Heterogeneous enzymatic catalysis via reversible host–guest interactions. ACS Applied Materials & Interfaces 9 (4): 4184–4191.

    Google Scholar 

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Rodríguez-Hernández, J., Bormashenko, E. (2020). Applications of the Porous Structures Obtained with the Breath-Figures Self-Assembly. In: Breath Figures . Springer, Cham. https://doi.org/10.1007/978-3-030-51136-4_8

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