Abstract
Aluminum alloys have a considerable appeal for mechanical and building designers. This characteristic lies in the mechanical and physicochemical properties of these alloys. Aluminum is often used in the anodized surface condition to impart pleasing aesthetics, higher corrosion resistance, better scratch and wear resistance, and thus an improved value of the product. Anodization is commonly produced by direct current (DC) that offers excellent protection against wear and corrosion. This work focuses on the surface condition of a 2030 aluminum alloy treated with chromium and sulfuric acid. Our goal is to understand what happens at the surface of the Al alloy after each treatment (chromic anodizing, sulfo-chromic anodizing) using a structural characterization (MEB) that will be followed by electrochemical characterization. The results obtained have shown the effectiveness of chromic anodizing, which gives rise to the formation of a thin layer and offers excellent protection against corrosion. Chromic anodic oxidation protects an aluminum part by creating a layer of alumina Al2O3, to give it anti-corrosion, decorative and heat resistance characteristics, as well as, any chromic acid residues do not attack the base material. This is the opposite of sulfuric acid, which makes it an excellent pretreatment for aerospace parts.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
References
Ashtiani, H.R.R., Shahsavari, P.: Strain-dependent constitutive equations to predict high temperature flow behavior of AA2024 aluminum alloy. Mech. Mater. 100, 209–218 (2016)
Bai, F., Li, J.F., Viehland, D.: Domain hierarchy in annealed (001)-oriented Pb (Mg 1/3 Nb 2/3) O 3–x % PbTiO 3 single crystals. Appl. Phys. Lett. 85, 12 (2004)
Costenaro, H., Lanzutti, A., Paint, Y., Fedrizzi, L., Terada, M., de Melo, H.G., Olivier, M.-G.: Corrosion resistance of 2524 Al alloy anodized in tartaric-sulphuric acid at different voltages and protected with a TEOS-GPTMS hybrid sol-gel coating. Surface Coatings Technol. 324, 438–450 (2017)
Datta, J., Samanta, B., Jana, A., Sinha, S., Bhattacharya, C., Bandyopadhyay, S.: Role of Cl- and NO-3 ions on the corrosion behavior of 20% SiC reinforced 6061-Al metal matrix composite: a correlation between electrochemical studies and atomic force microscopy. Corrosion Sci. 50, 2658–2668 (2008)
De Bonfils-Lahovary, M.L., Josse, C., Laffont, L., Blanc, C.: Influence of hYDROGEN ON the propagation of intergranular corrosion defects in 2024 aluminum alloy. Corrosion Sci. 148, 198–205 (2019)
Elabar, D., Němcová, A., Hashimoto, T., Skeldon, P., Thompson, G.E.: Effect of sulphate impurity in chromic acid anodizing of aluminium. Corrosion Sci. 100, 377–385 (2015)
Fadillah, L., Takase, K., Kobayashi, H., Turczyniak-Surdacka, S., Strawski, M., Kowalski, D., Zhu, C., Aoki, Y., Habazaki, H.: The role of tungsten species in the transition of anodic nanopores to nanotubes formed on iron alloyed with tungsten. Electrochim. Acta 309, 274–282 (2019)
García-Rubio, M., Ocón, P., Curioni, M., Thompson, G.E., Skeldon, P., Lavía, A., García, I.: Degradation of the corrosion resistance of anodic oxide films through immersion in the anodising electrolyte. Corrosion Sci. 52, 2219–2227 (2010)
Jensen, F., Kongstad, I., Dirscherl, K., Gudla, V.C., Ambat, R.: High frequency pulse anodising of recycled 5006 aluminium alloy for optimised decorative appearance. Surface Coatings Technol. 368, 42–50 (2019)
Laleh, R.R., Savaloni, H., Abdi, F., Abdi, Y.: Corrosion inhibition enhancement of Al alloy by graphene oxide coating in NaCl solution. Progress Organic Coatings 127, 300–307 (2019)
Le Coz, F., Arurault, L., Datas, L.: Chemical analysis of a single basic cell of porous anodic aluminium oxide templates. Mater. Characterization 61, 283–288 (2010)
Lee, W., Park, S.J.: Porous anodic aluminum oxide: anodization and templated synthesis of functional nanostructures. Chem. Rev. 114, 7487–7556 (2014)
Liu, H., Gu, T., Zhang, G., Cheng, Y., Wang, H., Liu, H.: The effect of magneticfield on biomineralization and corrosion behavior of carbon steel induced by iron-oxidizing bacteria. Corros. Sci. 102, 93–102 (2016)
Ma, Y., Wen, Y., Li, J., Feng, C., Zhang, Z., Gou, T., Huang, J., Lu, J., Cui, Z., Sun, R.: Fabrication of alumina with ordered tapered-nanopore nested in micro-bowl hierarchical structure by a combined anodization. Mater. Chem. Phys. 239, 122023 (2020)
Moon, S., Nam, Y., Yang, C., Jeong, Y.: Growth of anodic oxide films on AC2A alloy in sulphuric acid solution. Corros. Sci. 53, 1547–1553 (2011)
Nettikaden, V.C., Liu, H., Skeldon, P., Thompson, G.E.: Porous anodic film formation on Al–Ti alloys in sulphuric acid. Corros. Sci. 57, 49–55 (2012)
Ono, S., Saito, M., Asoh, H.: Self-ordering of anodic porous alumina formed in organic acid electrolytes. Electrochim. Acta 51, 827–833 (2005)
Palagonia, M.S., Erinmwingbovo, C., Brogioli, D., Mantia, F.L.: Comparison between cyclic voltammetry and differential charge plots from galvanostatic cycling. J. Electroanal. Chem. 847, 113170 (2019)
Saeedikhani, M., Javidi, M., Vafakhah, S.: Anodising of 2024-T3 aluminium alloy in electrolyte of sulphuric–boric–phosphoric mixed acid containing cerium salt as corrosion inhibitor. Trans. Nonferrous Met. Soc. China 27(3), 711–721 (2017)
Sousa, C.T., Leitao, D.C., Proenca, M.P., Ventura, J., Pereira, A.M., Araujo, J.P.: Nanoporous alumina as templates for multifunctional applications. Appl. Phys. Rev. 1, 3 (2014)
Tao, Y., Xiong, T., Sun, C., Jin, H., Du, H., Li, T.: Effect of α-Al2O3 on the properties of cold sprayed Al/α-Al2O3 composite coatings on AZ91D magnesium alloy. Appl. Surf. Sci. 256, 261–266 (2009)
Tao, Y., Xiong, T., Sun, C., Kong, L., Cui, X., Li, T., Song, G.L.: Microstructure and corrosion performance of a cold sprayed aluminum coating on AZ91D magnesium alloy. Corros. Sci. 52, 3191–3197 (2010)
Wang, J., Xiong, F., Liu, H., Zhang, T., Li, Y., Li, C., Xia, W., Wang, H., Liu, H.: Study of the corrosion behavior of Aspergillus niger on 7075-T6 aluminum alloy in a high salinity environment. Bioelectrochemistry 129, 10–17 (2019)
Zhang, P., Zu, Y.: Effects of pore parameters on performance of anodic film on 2024 aluminum alloy. Mater. Chem. Phys. 231, 9–20 (2019)
Zhang, S., Zhang, T., He, Y., Feng, Y., Du, X., Ma, B., Zhang, T.: Effect of coastal atmospheric corrosion on fatigue properties of 2024-T4 aluminum alloy structures. J. Alloy. Compd. 802, 511–521 (2019a)
Zhang, Z., Liu, F., Han, E.H., Xu, L., Uzoma, P.C.: Effects of Al2O3 on the microstructures and corrosion behavior of low-pressure cold gas sprayed Al 2024-Al2O3 composite coatings on AA 2024-T3 substrate. Surf. Coat. Technol. 370, 53–68 (2019b)
Zhou, X., Luo, C., Hashimoto, T., Hughes, A.E., Thompson, G.E.: Study of localized corrosion in AA2024 aluminium alloy using electron tomography. Corros. Sci. 58, 299–306 (2012)
Zhou, X., Thompson, G., Skeldon, P., Wood, G.C., Shimizu, K., Habazaki, H.: Film formation and detachment during anodizing of Al–Mg alloys. Corros. Sci. 41(8), 1599–1613 (1999)
Author information
Authors and Affiliations
Corresponding author
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2020 Springer Nature Switzerland AG
About this paper
Cite this paper
Benmohamed, M., Benmounah, A., Haddad, A. (2020). Effect of Different Anodizing Bath on Improving the Corrosion Resistance of a 2030 Aluminum Alloy. In: Benmounah, A., Abadlia, M.T., Saidi, M., Zerizer, A. (eds) Proceedings of the 4th International Symposium on Materials and Sustainable Development. ISMSD 2019. Springer, Cham. https://doi.org/10.1007/978-3-030-43268-3_2
Download citation
DOI: https://doi.org/10.1007/978-3-030-43268-3_2
Published:
Publisher Name: Springer, Cham
Print ISBN: 978-3-030-43267-6
Online ISBN: 978-3-030-43268-3
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)