Abstract
In this work, ZnO-Ag-Mg layers were developed by thermal evaporation (at high temperature and very low pressure) of powder mixtures of zinc oxide, magnesium and silver with a respective mass percentages (80-10-10)%. The deposited layers on glass substrate were investigated with respect to effect of annealing temperature after deposition on the evolution of structural, optical, electrical and mechanical properties of the layers was investigated. It has been shown that after annealing at 300°C, zinc oxide (ZnO) begins to crystallize with hexagonal wurtzite structure which increases the material’s cristallinity with annealing temperature. The transmittance of the layers increases with temperature to a maximum of 75% while a change of the electrical properties from a conductive layer with 14.29 Ω of resistance value towards a semiconductor layer with resistances around 225 kΩ. Also, it was noticed that the resistance to plastic deformation (Hardness) of the layers does not respect the hall-Petch rule due to very small grain size of less than 100 nm.
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References
Ambacher, O., et al.: Pyroelectric properties of Al(In)GaN/GaN hetero- and quantum well structures. J. Phys.: Condens. Matter 14, 3399 (2002)
Boshta, M., et al.: The photocatalytic activity of sprayed Zn1-xMgxO thin films. Surf. Coat. Technol. 205, 271–274 (2010)
Hartnagel, H.L., et al.: Semiconducting Transparent Thin Films. Institute of Physics Publishing, Bristol and Phadelphia (1995)
Karunakaran, C., et al.: Optical, electrical, photocatalytic, and bactericidal properties of microwave synthesized nanocrystalline Ag-ZnO and ZnO. Solid States Sci. 13, 923–928 (2011)
Lekoui, F., et al.: Effect of annealing temperature on the properties of Ag doped ZnO thin films. Mater. Res. Express. 5, 106406 (2018)
Cao, L., et al.: Enhancement of p-type conduction in Ag-doped ZnO thin films via Mg alloying: The role of oxygen vacancy. J. Phys. Chem. Solids 74, 668–672 (2013)
L’vov, B.V.: The physical approach to the interpretation of the kinetics and mechanisms of thermal decomposition of solids: the state of the art. Thermochim. Acta 373, 97–124 (2001)
L’vov, B.V., et al.: Kinetics and mechanism of free-surface vaporization of groups IIA, IIIA and IVA nitrides analyzed thermogravimetrically by the third-law method. Thermochim. Acta 411, 187–193 (2004)
Morris, J.W.: The influence of grain size on the mechanical properties of steel. In: International Symposium on Ultrafine Grained Steels, pp. 34–41 (2001)
Sankara Reddy, B., et al.: Preparation and structural properties of pure and codoped (Mg, Ag) ZnO nanoparticles. AIP Conf. Proc. 1536, 147–148 (2013)
Teke, A., et al.: Excitonic fine structure and recombination dynamics in single-crystalline ZnO. Phys. Rev. B. 70, 195207 (2004)
Wang, J.B., et al.: Raman study for E2 phonon of ZnO in Zn1-xMnxO nanoparticles. J. Appl. Phys. 97, 086105 (2005)
Wang, L.N., et al.: Studying the Raman spectra of Ag doped ZnO films grown by PLD. Mater. Sci. Semicond. Process. 14, 274–277 (2011)
Weber, W.H., Merlin, R.: Raman Scattering in Materials Science. Weber, Springer, Berlin (2000)
Wyckoff, R.W.G.: Crystal Structures, Inter Science Publishers. INC, New York (1960)
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Lekoui, F. et al. (2020). Structural, Optical, Electrical and Mechanical Properties of ZnO Co-doped Ag, Mg Thin Films: Annealing Temperature Effect. In: Benmounah, A., Abadlia, M.T., Saidi, M., Zerizer, A. (eds) Proceedings of the 4th International Symposium on Materials and Sustainable Development. ISMSD 2019. Springer, Cham. https://doi.org/10.1007/978-3-030-43268-3_16
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