Skip to main content

Preparation of Silica-Carbon Nanotubes Colloidal Solutions: Application to Kevlar® Reinforcement

  • Conference paper
  • First Online:
Proceedings of the 4th International Symposium on Materials and Sustainable Development (ISMSD 2019)

Included in the following conference series:

Abstract

The reinforcement of materials by nanoparticles has been widely studied and applied in many fields of engineering due to their unique surface effects, chemical activity and their particular physical properties. The aim of this study is to improve the mechanical properties of Kevlar®29, by the impregnation of the later, with various weight percentages of colloidal silica-carbon nanotubes. Firstly, the colloidal solutions of silica/CNTs are prepared using LUDOX HS40 suspension mixed with three weight fractions (50, 60 and 70%) of silica. Herein, 0.02% w of CNTs dispersed in ethylene glycol (50, 40 and 30% respectively) and added to the prepared mixtures. Subsequently, the prepared solutions are used to impregnate the Kevlar using a deep flask. The morphology of the impregnated Kevlar with silica (S) and multiwall carbon nanotubes (MWCNT) are characterized by scanning electron microscopy (SEM) and the mechanical properties are highlighted using uniaxial tensile test. The observed morphology using SEM characterization gives rise to a good dispersion of silica particles at the surface of Kevlar fibers without any significant agglomeration. The tensile test results show a large improvement in mechanical properties of the impregnated Kevlar with colloidal solutions containing less than 60% of silica. Therefore, a sensitive decrease is observed above this ratio. The nanoparticles proportion affect directly the different properties of the studied materials. Hence, the rate of nanomaterials should be optimized in order to ensure optimal properties at low cost.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 169.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 219.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 219.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  • Kanda, M., Puggal, S., Dhall, N., Sharma, A.: recent developments in the fabrication, characterization, and properties enhancement of polymer nanocomposites: a critical review. Mat. Today: Proc. 5(14), 28243–28252 (2018)

    CAS  Google Scholar 

  • Luo, J.J., Daniel, I.M.: Characterization and modeling of mechanical behavior of polymer/clay nanocomposites. Compos. Sci. Technol. 63(11), 1607–1616 (2003)

    Article  CAS  Google Scholar 

  • Mazrouaa, A.M., Mansour, N.A., Abed, M.Y., Youssif, M.A., Shenashen, M.A., Awual, M.R.: Nano-composite multi-wall carbon nanotubes using poly (p-phenyleneterephthalamide) for enhanced electric conductivity. J. Environ. Chem. Eng. 7(2), 103002 (2019)

    Article  Google Scholar 

  • Rebouillat. S.: Aramids, pp. 23–61. Woodhead Publishing Ltd, Cambridge (2001)

    Google Scholar 

  • Bencomo-Cisneros, J.A., Tejeda-Ochoa, A., García-Estrada, J.A., Herrera-Ramírez, C.A., Hurtado-Macías, A., Martínez-Sánchez, R., Herrera-Ramírez, J.M.: Characterization of Kevlar-29 fibers by tensile tests and nanoindentation. J. Alloy. Compd. 536, S456–S459 (2012)

    Article  CAS  Google Scholar 

  • Li, C.S., Zhan, M.S., Huang, X.C., Zhou, H.: The evolution of structure and properties of poly (p-phenyleneterephthalamide) during the hydrothermal aging. J. Appl. Polym. Sci. 126(2), 552–558 (2012)

    Article  CAS  Google Scholar 

  • Yan, H., Li, J., Tian, W., He, L., Tuo, X., Qiu, T.: A new approach to the preparation of poly (p-phenyleneterephthalamide) nanofibers. RSC Adv. 6(32), 26599–26605 (2016)

    Article  CAS  Google Scholar 

  • Tarfaoui, M., Lafdi, K., El Moumen, A.: Mechanical properties of carbon nanotubes based polymer composites. Compos. B Eng. 103, 113–121 (2016)

    Article  CAS  Google Scholar 

  • Varshney, K.: Carbon nanotubes: a review on synthesis, properties and applications. Int. J. Eng. Res. Gener. Sci. 2(4), 660–677 (2014)

    Google Scholar 

  • Ma, P.C., Siddiqui, N.A., Marom, G., Kim, J.K.: Dispersion and functionalization of carbon nanotubes for polymer-based nanocomposites: a review. Compos. A Appl. Sci. Manuf. 41(10), 1345–1367 (2010)

    Article  Google Scholar 

  • Sahoo, N.G., Rana, S., Cho, J.W., Li, L., Chan, S.H.: Polymer nanocomposites based on functionalized carbon nanotubes. Prog. Polym. Sci. 35(7), 837–867 (2010)

    Article  CAS  Google Scholar 

  • Ealias, A.M., Saravanakumar, M.P.: A review on the classification, characterization, synthesis of nanoparticles and their application. In: IOP Conference Series Material Science Engineering Proceedings of the 14th International Conference on Science, Engineering and Technology, vol. 263, p. 032019 (2017)

    Google Scholar 

  • Wang, H., Adeleye, A.S., Huang, Y., Li, F., Keller, A.A.: Hetero aggregation of nanoparticles with biocolloids and geocolloids. Adv. Coll. Interface. Sci. 226, 24–36 (2015)

    Article  CAS  Google Scholar 

  • Mari, R., Seto, R., Morris, J.F., Denn, M.M.: Discontinuous shear thickening in Brownian suspensions by dynamic simulation. Proc. Natl. Acad. Sci. 112(50), 15326–15330 (2015)

    Article  CAS  Google Scholar 

  • Smith, G.N., Finlayson, S.D., Rogers, S.E., Bartlett, P., Eastoe, J.: Electrolyte-induced instability of colloidal dispersions in nonpolar solvents. J. Phys. Chem. Lett. 8(19), 4668–4672 (2017)

    Article  CAS  Google Scholar 

  • Wasan, D.T., Nikolov, A.D., Aimetti, F.: Texture and stability of emulsions and suspensions: role of oscillatory structural forces. Adv. Coll. Interface. Sci. 108, 187–195 (2004)

    Article  Google Scholar 

  • Adams, D.J., Dyson, P.J., Tavener, S.J.: Chemistry in Alternative Reaction Media. Wiley, Chichester (2004)

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to H. Kechit .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 Springer Nature Switzerland AG

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Kechit, H., Belkhiri, S., Bhakta, A.K., Mekhalif, Z. (2020). Preparation of Silica-Carbon Nanotubes Colloidal Solutions: Application to Kevlar® Reinforcement. In: Benmounah, A., Abadlia, M.T., Saidi, M., Zerizer, A. (eds) Proceedings of the 4th International Symposium on Materials and Sustainable Development. ISMSD 2019. Springer, Cham. https://doi.org/10.1007/978-3-030-43268-3_11

Download citation

Publish with us

Policies and ethics