Skip to main content

Mechanical Properties of Boron Nitride Nanosheets (BNNSs) Reinforced Si3N4 Composites

  • Conference paper
  • First Online:
Advances in Powder and Ceramic Materials Science

Part of the book series: The Minerals, Metals & Materials Series ((MMMS))

Abstract

The boron nitride nanosheets (BNNSs)/silicon nitride (Si3N4) composite ceramics were prepared by SPS sintering. BNNSs with few layers and transverse size in micron-scale were prepared by ball-milling and ultrasound-assisted liquid-phase stripping. In this work, it was found that the BNNSs prepared by these two methods could enhance the mechanical properties of silicon nitride ceramics, and of BNNSs/Si3N4 composite ceramics exhibit better bending strength when adding the ultrasound-assisted liquid-phase stripping BNNSs. The bending strength and fracture toughness of BNNSs/Si3N4 composite ceramics was increased by 36% and 51%, respectively, when 2 wt% BNNSs prepared by ball-milling method were added. The pullout of BNNSs, the bridging of cracks, and the deflection of cracks are the main factors of improving the toughness.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 129.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 169.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 169.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

References

  1. Rafiee MA, Rafiee J, Wang Z et al (2009) Enhanced mechanical properties of nanocomposites at low graphene content. ACS Nano 3(12):3884

    Article  CAS  Google Scholar 

  2. Liu Y, Wu H, Chen G (2016) Enhanced mechanical properties of nanocomposites at low graphene content based on in situ ball milling. Polym Compos 37(4):1190–1197

    Article  CAS  Google Scholar 

  3. Wang K, Wang Y, Fan Z, Yan J, Wei T (2011) Preparation of graphene nanosheet/alumina composites by spark plasma sintering. Mater Res Bull 46:315–318

    Article  CAS  Google Scholar 

  4. Lee B, Lee D, Lee JH et al (2016) Enhancement of toughness and wear resistance in boron nitride nanoplatelet (BNNP) reinforced Si3N4 nanocomposites. Sci Rep 6:27609

    Article  CAS  Google Scholar 

  5. Sun G, Bi J, Wang W et al (2017) Microstructure and mechanical properties of boron nitride nanosheets-reinforced fused silica composites. J Eur Ceram Soc 37(9):3195–3202

    Article  CAS  Google Scholar 

  6. Shi G, Hanlumyuang Y, Liu Z et al (2014) Boron Nitride-Graphene Nanocapacitor and the origins of anomalous size-dependent increase of capacitance. Nano Lett 14(4):1739–1744

    Article  CAS  Google Scholar 

  7. Li LH, Cervenka J, Watanabe K, Taniguchi T, Chen Y (2014) Strong oxidation resistance of atomically thin boron nitride nanosheets. ACS Nano 8:1457–1462

    Article  CAS  Google Scholar 

  8. Riley FL (2000) Silicon nitride and related materials. J Am Ceram Soc 83:245–265

    Article  CAS  Google Scholar 

  9. Bocanegra-Bernal MH, Matovic B (2010) Mechanical properties of silicon nitride-based ceramics and its use in structural applications at high temperatures. Mater Sci Eng A 527:1314–1338

    Article  Google Scholar 

  10. Wang Z, Jia J, Cao L et al (2019) Microstructure and mechanical properties of spark plasma sintered Si3N4/WC ceramic tools. Materials 12(11):1868

    Article  Google Scholar 

  11. Miranzo P, Jesús González-Julián, María Isabel Osendi et al (2011) Enhanced particle rearrangement during liquid phase spark plasma sintering of silicon nitride-based ceramics. Ceram Int 37(1):159–166

    Google Scholar 

  12. Lei W, Liu D, Chen Y (2015) Highly crumpled boron nitride nanosheets as adsorbents: scalable solvent-less production. Adv Mater Interfaces 2:1400529–1400534

    Article  Google Scholar 

  13. Li LH, Chen Y, Behan G et al (2011) Large-scale mechanical peeling of boron nitride nanosheets by low-energy ball Milling. J Mater Chem 21:11862–11867

    Article  CAS  Google Scholar 

  14. Ma P, Spencer JT (2014) Non-covalent stabilization and functionalization of boron nitride nanosheets (BNNSs) by organic polymers: formation of complex BNNSs-containing structures. J Mater Sci 50:313–323

    Article  Google Scholar 

  15. Gao G, Gao W, Cannuccia E et al (2012) Artificially stacked atomic layers: toward new van der waals solids. Nano Lett 12:3518–3525

    Article  CAS  Google Scholar 

  16. Zhi C, Bando Y, Tang C et al (2009) Large scale fabrication of boron nitride nanosheets and their utilization in polymeric composites with improved thermal and mechanical properties. Adv Mater 21:2889–2893

    Article  CAS  Google Scholar 

  17. Muller F, Hufner S, Sachdev H et al (2010) Epitaxial growth of hexagonal boron nitride on Ag (111). Phys Rev B 82:113406–113409

    Article  Google Scholar 

  18. Zhou KG, Mao NN, Wang HX, Peng Y, Zhang HL (2011) A mixed-solvent strategy for efficient exfoliation of inorganic graphene analogues. Angew Chem Int Ed 50:10839–10842

    Article  CAS  Google Scholar 

  19. Kumar A, Gokhale A, Ghosh S et al (2019) Effect of nano-sized sintering additives on microstructure and mechanical properties of Si3N4 ceramics. Mater Sci Eng A 750:132–140

    Article  CAS  Google Scholar 

  20. Chen YF, Bi JQ, Wang WL et al (2014) Toughening in boron nitride nanotubes/silicon nitride composites. Mater Sci Eng A 590:16–20

    Article  CAS  Google Scholar 

  21. Chen C, Pan L, Li X et al (2017) Mechanical and thermal properties of graphene nanosheets/magnesia composites. Ceram Int 43(13):10377–10385

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to Jianqiang Bi .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2020 The Minerals, Metals & Materials Society

About this paper

Check for updates. Verify currency and authenticity via CrossMark

Cite this paper

Liang, G., Bi, J., Sun, G., Chen, Y., Wang, W. (2020). Mechanical Properties of Boron Nitride Nanosheets (BNNSs) Reinforced Si3N4 Composites. In: Li, B., et al. Advances in Powder and Ceramic Materials Science. The Minerals, Metals & Materials Series. Springer, Cham. https://doi.org/10.1007/978-3-030-36552-3_8

Download citation

Publish with us

Policies and ethics