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Exploratory Data Analysis

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Chemometrics in Electroanalysis

Part of the book series: Monographs in Electrochemistry ((MOEC))

Abstract

The main characteristics of multivariate data are discussed, and exploratory tools are provided to extract information from them. Different preprocessing strategies of normalization, smoothing and compression are described and compared for the cases of discrete and continuous variables. Finally, principal component analysis (PCA) is studied as an especially useful strategy for the unsupervised discrimination of samples with examples from the electroanalytical literature.

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References

  1. Sharaf MA, Illman DL, Kowalski BR (1986) Chemometrics. Wiley, New York

    Google Scholar 

  2. Massart DL, Vandeginste BGM, Deming SN, Michotte Y, Kaufman L (1988) Chemometrics: a textbook. Elsevier, Amsterdam

    Google Scholar 

  3. Massart DL, Vandeginste BGM, Buydens LMC, de Jong S, Lewi PJ, Smeyers-Verbeke J (1998) Handbook of chemometrics and qualimetrics. Elsevier, Amsterdam

    Google Scholar 

  4. Esbensen KH, Guyot D, Westad F (2000) Multivariate data analysis in practice: an introduction to multivariate data analysis and experimental design, 4th edn. Camo, Oslo

    Google Scholar 

  5. Brown SD, Tauler R, Walczak B (eds) (2009) Comprehensive chemometrics: chemical and biochemical data analysis. Elsevier, Amsterdam

    Google Scholar 

  6. Brown SD, Bear RS Jr (1993) Crit Rev Anal Chem 24:99

    Article  CAS  Google Scholar 

  7. Richards E, Bessant C, Saini S (2002) Electroanalysis 14:1533

    Article  CAS  Google Scholar 

  8. Esteban M, Ariño C, Díaz-Cruz JM (2006) Trends Anal Chem 25:86

    Article  CAS  Google Scholar 

  9. Savitzky A, Golay MJE (1964) Anal Chem 36:1627

    Article  CAS  Google Scholar 

  10. Cooley JW, Tukey JW (1965) Math Comp 19:297

    Article  Google Scholar 

  11. Smith DE (1976) Anal Chem 48:517A

    Article  Google Scholar 

  12. Duhamel P, Vetterli M (1990) Signal Process 19:259

    Article  Google Scholar 

  13. Grossman A, Morlet J (1984) SIAM J Math Anal 15:723

    Article  Google Scholar 

  14. Daubechies I (1988) Commun Pure Appl Math 41:909

    Article  Google Scholar 

  15. Leung AK, Chau F, Gao J (1998) Chemom Intell Lab Sys 43:165

    Article  CAS  Google Scholar 

  16. Shao XG, Leung AKM, Chau FT (2003) Acc Chem Res 36:276

    Article  CAS  Google Scholar 

  17. Chau FT, Leung AKM (2000) Chapter 10: Application of wavelet transform in electrochemical studies. In: Walczak B (ed) Wavelets in chemistry. Elsevier, Amsterdam, pp 225–239

    Google Scholar 

  18. Moreno-Barón L, Cartas R, Merkoçi A, Alegret S, Gutiérrez JM, Leija L, Hernández PR, Muñoz R, del Valle M (2005) Anal Lett 38:2189

    Article  Google Scholar 

  19. Prikler S, Einax JW (2009) Anal Bioanal Chem 395:1707

    Article  CAS  Google Scholar 

  20. Alonso GA, Marty JL, Gutiérrez JM, Muñoz R (2011) Implementation of the discrete wavelet transform used in the calibration of the enzymatic biosensors. INTECH Open Access Publisher

    Google Scholar 

  21. Cetó X, Céspedes F, del Valle M (2013) Microchim Acta 180:319

    Article  Google Scholar 

  22. Bard AJ, Faulkner LR (2001) Electrochemical methods. Fundamentals and applications, 2nd edn. Wiley, New York

    Google Scholar 

  23. Geladi P, McDougall D, Martens H (1985) Appl Spectrosc 39:491

    Article  Google Scholar 

  24. Zhang Z-M, Chen S, Liang Y-Z (2010) Analyst 135:1138

    Article  CAS  Google Scholar 

  25. Wold H (1966) In: David F (ed) Research papers in statistics. Wiley, New York

    Google Scholar 

  26. Wold H (1966) In: Krishnaiah P (ed) Multivariate analysis. Academic Press, New York, p 391

    Google Scholar 

  27. Vandeginste BGM, Sielhorst C, Gerritsen M (1988) Trends Anal Chem 7:286

    Article  Google Scholar 

  28. Krantz-Rülcker C, Stenberg M, Winquist F, Lundström I (2001) Anal Chim Acta 426:217

    Article  Google Scholar 

  29. Vlasov Y, Legin A, Rudnitskaya A (2002) Anal Bioanal Chem 373:136

    Article  CAS  Google Scholar 

  30. Deisingh AK, Stone DC, Thompson M (2004) Int J Food Sci Technol 39:587

    Article  CAS  Google Scholar 

  31. Ciosek P, Wróblewski W (2007) Analyst 132:963

    Article  CAS  Google Scholar 

  32. Winquist F (2008) Microchim Acta 163:3

    Article  CAS  Google Scholar 

  33. del Valle M (2010) Electroanalysis 22:1539

    Google Scholar 

  34. Escuder-Gilabert L, Peris M (2010) Anal Chim Acta 665:15

    Article  CAS  Google Scholar 

  35. Riul A Jr, Dantas CA, Miyazaki CM, Oliveira ON Jr (2010) Analyst 135:2481

    Article  CAS  Google Scholar 

  36. Ciosek P, Wróblewski W (2011) Sensors 11:4688

    Article  Google Scholar 

  37. Tahara Y, Toko K (2013) IEEE Sens J 13:3001

    Article  Google Scholar 

  38. Martínez-Máñez R, Soto J, Garcia-Breijo E, Gil L, Ibáñez J, Llobet E (2005) Sens Actuators B-Chem 104:302

    Article  Google Scholar 

  39. Lvova L, Martinelli E, Mazzone E, Pede A, Paolesse R, Di Natale C, D’Amico A (2006) Talanta 70:833

    Article  CAS  Google Scholar 

  40. Gallardo J, Alegret S, del Valle M (2005) Talanta 66:1303

    Article  CAS  Google Scholar 

  41. Ciosek P, Wróblewski W (2008) Talanta 76:548

    Article  CAS  Google Scholar 

  42. Hruškar M, Major N, Krpan M (2010) Talanta 81:398

    Article  Google Scholar 

  43. Escriche I, Kadar M, Domenech E, Gil-Sánchez L (2012) J Food Eng 109:449

    Article  CAS  Google Scholar 

  44. Cetó X, Gutiérrez-Capitán M, Calvo D, del Valle M (2013) Food Chem 141:2533

    Article  Google Scholar 

  45. Cuartero M, Carretero A, García MS, Ortuño JA (2015) Electroanalysis 27:782

    Article  CAS  Google Scholar 

  46. Nery EW, Kubota LT (2016) Anal Chim Acta 918:60

    Article  CAS  Google Scholar 

  47. Winquist F, Wide P, Lundström I (1997) Anal Chim Acta 357:21

    Article  CAS  Google Scholar 

  48. Cetó X, Capdevila J, Puig-Pujol A, del Valle M (2014) Electroanalysis 26:1504

    Article  Google Scholar 

  49. Dias LA, Peres AM, Vilas-Boas M, Rocha MA, Estevinho L, Machado AA (2008) Microchim Acta 163:97

    Article  CAS  Google Scholar 

  50. Cetó X, O’Mahony AM, Wang J, del Valle M (2013) Talanta 107:270

    Article  Google Scholar 

  51. Cetó X, Gutiérrez JM, Mimendia A, Céspedes F, del Valle M (2013) Electroanalysis 25:1635

    Article  Google Scholar 

  52. Wei Z, Wang J, Zhang X (2013) Electrochim. Acta 88:231

    Article  CAS  Google Scholar 

  53. Liu N, Liang Y, Bin J, Zhang Z, Huang J, Shu R, Yang K (2014) Food Anal Methods 7:472

    Article  Google Scholar 

  54. Apetrei IM, Apetrei C (2016) Sens Actuat B-Chem 234:371

    Article  CAS  Google Scholar 

  55. Tharwat A, Gaber T, Ibrahim A, Hassanien AE (2017) AI Commun 30:169

    Article  Google Scholar 

  56. Tiwari K, Tudu B, Bandyopadhyay R, Chatterjee A (2013) J Food Eng 117:205

    Article  CAS  Google Scholar 

  57. Domínguez RB, Moreno-Barón L, Muñoz R, Gutiérrez JM (2014) Sensors 14:17770

    Article  Google Scholar 

  58. Cetó X, González-Calabuig A, Capdevila J, Puig-Pujol A, del Valle M (2015) Sens Actuat B-Chem 207:1053

    Article  Google Scholar 

  59. Serrano N, Cetó X, Núñez O, Aragó M, Gámez A, Ariño C, Díaz-Cruz JM (2018) Talanta 189:296

    Article  CAS  Google Scholar 

  60. de Morais TCB, Rodrigues DR, Souto UTDCP, Lemos SG (2019) Food Chem 273:31

    Google Scholar 

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Authors and Affiliations

  1. Faculty of Chemistry, University of Barcelona, Barcelona, Spain

    José Manuel Díaz-Cruz, Miquel Esteban & Cristina Ariño

Authors
  1. José Manuel Díaz-Cruz
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  2. Miquel Esteban
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  3. Cristina Ariño
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Díaz-Cruz, J.M., Esteban, M., Ariño, C. (2019). Exploratory Data Analysis. In: Chemometrics in Electroanalysis. Monographs in Electrochemistry. Springer, Cham. https://doi.org/10.1007/978-3-030-21384-8_3

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