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Ion Exchange Resin Technology in Recovery of Precious and Noble Metals

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Applications of Ion Exchange Materials in Chemical and Food Industries

Abstract

Ion exchange technology has received outstanding attention in a wide variety of industries, including water treatment, pharmaceuticals, petrochemicals and hydrometallurgy due to its fast and high-efficiency operations. In hydrometallurgical applications, ion exchange resins have been used increasingly for the recovery and purification of metal pregnant solutions or for effluent treatment. This chapter devoted to an integrated evaluation of the present uses and future developments of the ion exchange resins in extraction and recovery of precious and noble metals including gold, silver, copper, uranium and iron. A detailed discussion about the recent advances of the ion exchange technique in metal recovery from their pregnant solutions is also presented from the aspects of anion metal adsorption on the resins and metal-loaded resin elution. Besides comprehensive overview about the effectiveness of surface modified resins, the major limitations of the resin adsorption techniques are pointed out.

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Notes

  1. 1.

    Ammine complex of gold, \( {\text{Au}}{{({\text{NH}}_{3} )_{2}}^{ + }} \), displays linear structure, whereas \( {\text{Cu}}{{({\text{NH}}_{3})_{4}}^{2 + }} \) has tetrahedral structural characteristic.

  2. 2.

    A kind of resin network which is composed of poly(vinyl alcohol).

  3. 3.

    In the southeast of Brazil.

Abbreviations

1EDA:

1-ethylenediamine

aAEP:

1-(2-aminoethyl) piperazine

BV:

Bed volume

CMP:

Chemical and mechanical polishing

CPU:

Central processing units

DMA:

Dimethylamine

DVB:

Divinylbenzene

EPA:

U.S. Environmental Protection Agency

EW:

Electrowinning

IEX:

Ion exchange

IEXRs:

Ion exchange resins

MAs:

Mixed amines

PAGs:

Polyamine groups

PIN:

Pin contact elements

PMLS:

Precious metals

QA:

Quaternary ammonium

QABs:

Quaternary amino groups

QAGs:

Quaternary amine groups

RIP:

Resin in pulp

RIS:

Resin in solution

SAGs:

Secondary amino groups

st-DVB:

Polystyrene crosslinked with divinylbenzene

SX-EW:

Solvent extraction-Electrowinning

TAGs:

Tertiary amino groups

TEPA:

Tetraethylenepentamine

VBC:

Vinylbenzylchloride

WB:

Weak base resin

WEEE:

Wasted electronics and electronic equipment

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Mohebbi, A., Abolghasemi Mahani, A., Izadi, A. (2019). Ion Exchange Resin Technology in Recovery of Precious and Noble Metals. In: Inamuddin, Rangreez, T., M. Asiri, A. (eds) Applications of Ion Exchange Materials in Chemical and Food Industries. Springer, Cham. https://doi.org/10.1007/978-3-030-06085-5_9

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