Abstract
The two functional properties of tire tread rubbers of prime importance today are low rolling resistance and high wet traction during braking. Rolling resistance and wet traction are related to low tan δ and Tg, respectively. In most of the conventional synthetic rubbers, high Tg is accompanied with high tan δ. Studies on polybutadiene rubbers prepared with anionic catalysts showed that the rubbers containing a high percent of vinyl structure provide exceptions to this general rule. This work demonstrates that vinyl groups in vinyl BR’s do not contribute significantly to tan δ in the frequency/temperature regime corresponding to the rubber plateau region. Guided by our results, a number of experimental rubber compositions were developed for tire treads. These compositions have the desirable combination of high traction and low rolling resistance.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
K. H. Nordsiek, Kautsch. Gummi Kunstst., 38, 178 (1983).
R. Bond, Proc. Royal Soc., London, A399, 1 (1985).
N. Yoshimura, M. Okuyama, and K. Yamagishi: Tire Rolling Resistance, D. J. Schuring, ed., Rubber Division Meeting, Am. Chem. Soc., 1983.
A. Schallamach, Int. Polym. Sci. Techni., 6, T44, T63 (1975).
E. Southern and A. G. Thomas, Rubber Chem. Technol., 52, 1008 (1979).
A. N. Gent and C. T. R. Pulford, J. Appl. Polym. Sci., 28, 943 (1983).
J. D. Ferry, Viscoelastic Properties of Polymers, 2nd ed., Wiley, New York, 1970.
H. L. Hsieh, R. C. Farrar, and K. Udipi, in Anionic Polymerization, J. E. McGrath, ed., Symposium Series No. 166, Am. Chem. Soc., Washington, D.C., 1981.
I. G. Hargis, R. A. Livigni, and S. L. Aggarwal, in Elastomers and Rubber Elasticity, J. E. Mark and J. Lal, eds., Symposium Series No. 193, Am. Chem. Soc., Washington, D. C., 1982.
T. Antkowiak, A. E. Oberster, A. F. Halasa, and D. P. Tate, J. Polym. Sci., Part A-10, 10, 1319 (1972).
D. D. Werstler, Rubber Chem. Technol., 53(5) 1114 (1980).
V. D. Mochel and B. L. Johnson, Rubber Chem. Technol., 43(5) 1138 (1970).
MTS 830 Elastomer Test System by MTS System Corp., Box 24012, Minneapolis, MN 55424.
F. L. Yerzley, Rubber Age, 104, 27 (1972).
D. J. Schuring, Rubber Chem. Technol., 53, 600 (1980).
British Standards Institution, British Standard No. 903; 1950, part 22, Methods of Testing Vulcanized Rubber, London (1950).
J. M. Giustino and R. J. Emerson, Instrumentation of the British Portable Skid Tester, Paper No. 76, 123rd Meeting Rubber Division, Inc., Am. Chem. Soc., May 10–12 (1983).
E. W. Duck and J. M. Locke, J. Inst. Rubber Ind., 2(5), 223 (1968).
K. H. Nordsiek and K. M. Kiepert, Kautsch. Gummi Kunstst., 33, 251 (1980).
R. E. Railsback and N. A. Stumpe, Jr., Rubber Age, 107, 27 (1975).
R. G. Mancke and J. D. Ferry, Trans. Soc. Rheol., 12, 335 (1968).
J. M. Carella, W. W. Graessley, and L. J. Fetters, Macromolecules, 17, 2775 (1984).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1986 Springer Science+Business Media New York
About this chapter
Cite this chapter
Aggarwal, S.L., Hargis, I.G., Livigni, R.A., Fabris, H.J., Marker, L.F. (1986). Structure and Properties of Tire Rubbers Prepared by Anionic Polymerization. In: Lal, J., Mark, J.E. (eds) Advances in Elastomers and Rubber Elasticity. Springer, Boston, MA. https://doi.org/10.1007/978-1-4757-1436-4_2
Download citation
DOI: https://doi.org/10.1007/978-1-4757-1436-4_2
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4757-1438-8
Online ISBN: 978-1-4757-1436-4
eBook Packages: Springer Book Archive