Skip to main content

The Forests as a Source of Natural Adhesives

  • Chapter
Adhesion in Cellulosic and Wood-Based Composites

Part of the book series: NATO Conference Series ((SYSC,volume 3))

Abstract

Natural adhesives are appealing to our present industrial society because they conjure up thoughts of products derived from completely renewable resources, thus offering solutions to the price vulnerability and diminishing availability of the petroleum resource. Sometimes, however, our thought processes are inhibited by the rapid scientific and industrial changes which have occurred over the last few centuries. Going back in history, we soon realize that natural materials have been used as adhesives since at least the time of the Pharaohs. Only in the last hundred years have synthetic-based materials made a significant impact. In fact, it should be remembered that these so-called synthetic materials, which are produced from petroleum or coal feedstocks, in themselves originate from plants and animals. Under the influence of pressure, time and an anaerobic environment, they decomposed to these hydrocarbon sources. This process required tens of thousands of years. Our current energy problems arise because this resource is being depleted in the relative short time period of a few hundred years. By using plant products, the growing cycle can be matched to the time of man’s utilization. If planned carefully, these products then become renewable (in our lifetimes) chemical and energy resources.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 39.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 54.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. R. Houwink and G. Salomon, Adhesion and adhesives. Vol. 1 Elsevier Co., N.Y. (1965).

    Google Scholar 

  2. I. Skeist, Handbook of adhesives, 2nd ed.. Van Nostrand- Reinhold, N.Y. (1975).

    Google Scholar 

  3. K.V. Sarkanen and C.H. Ludwig, ed., Lignins — occurrence, forma tion, structure and reactions, Wiley-Interscience, N.Y. (1971).

    Google Scholar 

  4. W. Schweers, Utilization of lignins isolated under mild conditions from wood or wood waste for the production of useful chemicals and other chemical products. Presented Eighth World Forestry Congress, Jakarta, Indonesia (1978).

    Google Scholar 

  5. G.G. Allan, In: Lignins — occurrence, formation, structure and reactions; K.V. Sarkanen and C.H. Ludwig, ed., Wiley-Interscience, N.Y., P511–573 (1971).

    Google Scholar 

  6. J. Marton, T. Marton, S. Falkehag and E. Alder, In: Lignin structure and reactions; J. Marton, ed.. Advances Chem. Ser. No. 59, Amer. Chem. Soc., Washington, D.C., p.125–144 (1966).

    Chapter  Google Scholar 

  7. K. Kratzl, K. Buchtela, J. Gratzl, J. Zauner and O. Ettings hausen, Lignin and plastics. The reactions of lignin with phenol and isocyanates, Tappi 45(2):113 (1962).

    Google Scholar 

  8. S. Tai, J. Nakano and N. Migita, Studies on utilization of lignin. V. Adhesive from lignin epoxide, Nippon Mokuzai Gakkaishi 13:257 (1967).

    Google Scholar 

  9. S.I. Falkehag, Lignin in materials. Applied Polymer Symp. 28:247 (1975).

    Google Scholar 

  10. D.A. Goring, In: Lignin — occurrence, formation, structure and reactions; K.V. Sarkanen and C.H. Ludwig, ed., Wiley-Interscience, N.Y., p.695–768 (1971).

    Google Scholar 

  11. R.C. Gupta, Adhesives from wood as substitutes for synthetic glues. World Consultation Wood Based Panels, New Delhi, F.A.O. Doc. No. 33, p.7 (1975).

    Google Scholar 

  12. T.A. Johansen, Particleboard bonded with sulphite liquor, Proc. Fifth Particleboard Symp., Wash. State Univ. Pullman, WA p.11–30 (1971).

    Google Scholar 

  13. K.C. Shen, Modified powdered spent sulfite liquor as binder for exterior waferboard. Forest Products J. 24(2):38–44 (1974).

    Google Scholar 

  14. K.C. Shen, Spent sulphite liquor binder for exterior waferboard, Forest Products J. 27(5):32–36 (1977).

    Google Scholar 

  15. J.M. Holderby, H.S. Olsen and W.H. Wegener, Thermosetting adhe sive from electrodialyzed lignosulfonates, Tappi 50(9):92–94A (1967).

    Google Scholar 

  16. K.C. Shen, Ammonium based spent sulfite liquor binder systems for waferboard manufacture, Proc. Thirteenth Particleboard Symp., Wash. State Univ., Pullman, WA. (1979).

    Google Scholar 

  17. K.G. Forss and A. Fuhrmann, Finnish plywood, particleboard, and fiberboard made with a lignin-base adhesive. Forest Products J. 29(7):39–43 (1979).

    Google Scholar 

  18. A.J. Dolenko and M.R. Clarke, Resin binders from kraft lignin. Forest Products J. 28(8):41–46 (1978).

    Google Scholar 

  19. G.E. Troughton, J.F. Manville and S. Chow, Lignin utilization II. Resin properties of 4-alkyl substituted catechol compounds, Forest Products J. 22 (9): 108–110 (1972).

    Google Scholar 

  20. M. Funaoka and I. Abe, The reaction of lignin under the presence of phenol and boron trifluoride. I. On the formation of catechol from MWL, dioxane lignin and kraft lignin, Japan Wood Research Soc. J. 24(4):256–261 (1978).

    Google Scholar 

  21. K.F. Plomley, Tannin-formaldehyde adhesives for wood. II. Wattle tannin adhesives, CSIRO Div. Forest Prod. Technol. Paper No. 39, Melbourne, Australia (1966).

    Google Scholar 

  22. W.E. Hillis and G. Urbach, The reaction of (+)-catechin with formaldehyde, J. Appl. Chem. 9:474–482 (1959).

    Article  Google Scholar 

  23. W.E. Hillis and G. Urbach, Reaction of polyphenols with formal dehyde, J. Appl. Chem. 9:665–673 (1959).

    Article  Google Scholar 

  24. D.G. Roux, D. Ferreira, H.K. Hundt and E. Malan, Structure, stereochemistry, and reactivity of natural condensed tannins as basis for their extended industrial application, Appl. Polym. Symp. No. 28, p.335–353 (1975).

    Google Scholar 

  25. K.D. Sears, R.L. Casebier, H.L. Hergert, G. Stout and L.E. McCandlish, The structure of catechinic acid. A base rearrangement product of catechin, J. Org. Chem. 39:3244–3247 (1975).

    Article  Google Scholar 

  26. R.W. Hemingway, Proc. Complete-tree util. southern pine symp.; C.W. McMillen, ed.. New Orleans, LA., p.443–457 (1978).

    Google Scholar 

  27. R.W. Hemingway, G.W. McGraw and J. Karchesy, Condensation of ortho and para hydroxbenzyl alcohols with catechin as a model for use of methylolphenols as crosslinking agents in conifer bark polyflavonoid adhesive formulations, Symp. Chem. Phenolic Resins, Weyerhaeuser Co., Tacoma, WA. (1979).

    Google Scholar 

  28. R.T. Lin, Behavior of Douglas-fir bark components in compres sion, Wood Sci. 6(2):106–111 (1973).

    Google Scholar 

  29. S. Chow and K. Pickles, Thermal softening and degradation of wood and bark. Wood Fiber 3 (3): 166–178 (1971).

    Google Scholar 

  30. E. Haslam, Symmetry and promiscuity in procyanidin biochemistry, Phytochemistry 16:1625–1640 (1977).

    Article  Google Scholar 

  31. L.J. Porter, Structure of polymeric proanthocyanidins; elucida tion of their structure and their relationship to the condensed tannins of bark, Symp. Extractives: Util. Problem or Fine Chem. Resource? ACS/CSJ Chem. Congress, Honolulu, HI (1979).

    Google Scholar 

  32. C.H. Burrows, Particle board from Douglas-fir bark — without additives. Ore. Forest Res. Center, Inf. Circ. 15, Corvallis, OR, 40p. (1960).

    Google Scholar 

  33. S. Chow, Bark boards without synthetic resins. Forest Products J. 25 (11):32–37 (1975).

    Google Scholar 

  34. A. Pizzi, Tannin-based polyurethane adhesives, J. Appl. Polym. Sci. 23:1889–1891 (1979).

    Article  Google Scholar 

  35. H.M. Saayman and J.A. Oatley, Wood adhesives from wattle bark extract. Forest Products J. 26(12):27–33 (1976).

    Google Scholar 

  36. A. Pizzi, The chemistry and development of tannin-urea-formaldehyde condensates for exterior wood adhesives, J. Appl. Polym. Sci. 23:2777–2792 (1979).

    Article  Google Scholar 

  37. L.K. Dalton, Tannin-formaldehyde resins as adhesives for wood, Aust. J. Appl. Sci. 1:54–70 (1950).

    ADS  Google Scholar 

  38. A. Pizzi and D.G. Roux, The chemistry and development of tannin-based weather- and boil-proof cold-setting and fast-setting adhesives for wood, J. Appl. Polym. Sci. 22:1945–1954 (1978).

    Article  Google Scholar 

  39. K.F. Plomley, W.E. Hillis and K. Hirst, The influence of wood extractives on the glue-wood bond. I. The effect of kind and amount of commercial tannins and crude wood extracts on phenolic bonding, Holzforschung 30:14–19 (1976).

    Article  Google Scholar 

  40. P.R. Steiner and S. Chow, Some factors influencing the use of western hemlock bark extracts as adhesives, Proc. lUFRO Conf. wood Gluing, Madison, WI p.61–78 (1975).

    Google Scholar 

  41. W.E. Hillis, Natural polyphenols (tannins) as a basis for adhesives, Symp. Chem. Phenolic Resins, Weyerhaeuser Co., Tacoma, WA (1979).

    Google Scholar 

  42. J.L. Keays, Biomass of forest residuals, AIChE Symp. Series 71 (146): 10–21 (1975).

    Google Scholar 

  43. G.M. Barton, J.A. Mcintosh and S. Chow, The present status of foliage utilization, AIChE Symp. Series 74(177):124–131 (1978).

    Google Scholar 

  44. J.L. Keays, Foliage. Part I. Practical utilization of foliage, Appl. Polym. Symp. 28:445–464 (1976).

    Google Scholar 

  45. G.M. Barton, Foliage. Part II. Foliage chemicals, their prop erties and uses, Appl. Polym. Symp. 28:465–484 (1976).

    Google Scholar 

  46. O. Theander, Leaf litter of some forest trees; chemical composi tion and microbiological activity, Tappi 61(4):69–72 (1978).

    Google Scholar 

  47. K.N. Law, S.N. Lo and Z. Koran, Utilization of spruce foliage. Extraction of spruce protein and chlorophyll-carotene. Wood Sci. 11(2):91–96 (1978).

    Google Scholar 

  48. K.N. Law and Z. Koran, Utilization of white spruce foliage. Pulp characteristics. Wood Sei. 12(2):106–112 (1979).

    Google Scholar 

  49. J.L. Keays and G.M. Barton, Recent advances in foliage utiliza tion, Can. Forest. Serv., Western Forest Prod. Lab., Inf. Rep. VP-X-137, Vancouver, B.C. (1975).

    Google Scholar 

  50. J.B. Harborne, Phytochemical methods. Chapman and Hall, London, p.40 (1973).

    Google Scholar 

  51. T-Y Chen and M. Paulitsch, The extractives of needles, bark, and wood of pine and spruce and their effect on particle- board made thereof, Holz als Roh-und Werkstoff 32:397–401 (1974).

    Google Scholar 

  52. P.R. Steiner. Unpublished results.

    Google Scholar 

  53. E.T. Howard, Properties of southern pine needles. Wood Sei. 5(4):281–286 (1973).

    Google Scholar 

  54. S. Chow, Foliage as adhesive extender: a progress report, Proc. Eleventh Particleboard Symp., Wash. State Univ., Pullman, WA p.89–98 (1977).

    Google Scholar 

  55. S. Chow and P.R. Steiner. Unpublished data.

    Google Scholar 

  56. E.T. Howard, Needleboards — an exploratory study. Forest Products J. 24 (5):50–51 (1974).

    Google Scholar 

  57. N.C. Jain and R.C. Gupta, A note on the complete utilisation of trees, Indian Forester 95:841–848 (1969).

    Google Scholar 

  58. S. Chow, L. Rozon and P.R. Steiner, Efficiency of coniferous foliage as extender for powdered phenolic resin, Proc. Thirteenth Particleboard Symp., Wash. State Univ., Pullman, WA (1979).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 1981 Plenum Press, New York

About this chapter

Cite this chapter

Steiner, P.R. (1981). The Forests as a Source of Natural Adhesives. In: Oliver, J.F. (eds) Adhesion in Cellulosic and Wood-Based Composites. NATO Conference Series, vol 3. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8983-5_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-8983-5_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-8985-9

  • Online ISBN: 978-1-4684-8983-5

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics