Abstract
The nuclear portion of the electric quadrupole interaction, along with its application to nuclear physics, was described by Professor Hafemeister in the previous chapter. The importance of the nuclear part, for the purposes of this chapter, is that the extra-nuclear portion, the electric field gradient (EFG) tensor, cannot be extracted from experimental data without prior knowledge of certain nuclear spins and moments. The required information, if known, may be easily located in the Mössbauer Effect Data Index [1], and the use of such information to relate observed splittings to the EFG tensor is illustrated in this chapter. In addition, the following sections describe the prediction of the EFG tensor for an assumed molecular crystal model, special techniques and hints, and the utility of EFG information.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. H. Muir, Jr., K. J. Ando, Helen M. Coogan, Eds., Mössbauer Effect Data Index 1958–1965 (Interscience Publishers, New York, 1966).
R. M. Sternheimer, Phys Rev, 80, 102 (1950); 84, 244 (1951); 130, 1423 (1963);
H. M. Foley, R. M. Sternheimer, and D. Tycko, ibid. 93, 734 (1954);
R. M. Sternheimer and H. M. Foley, ibid. 102, 731 (1956).
R. Ingalls, Phys. Rev. 128, 1155 (1962).
R. M. Sternheimer, Phys. Rev. 130, 1423 (1963).
Michael J. Bielefeld, Semi-empirical Treatment of the Mössbauer Quadrupole Splitting. Research Institute for Natural Sciences, Woodstock College, Woodstock, Maryland, NASA grant NsG-670.
P. R. Edwards, C. E. Johnson, and R. J. P. Williams, Chem. Phys. 47, 2074 (1967).
R. Ingalls, Phys. Rev. 133, A787 (1964).
J. R. Gabriel and S. L. Ruby, Nucl. Instr. Methods 36, 23 (1965).
G. K. Wertheim, Mössbauer Effect (Academic Press, New York, 1964), p. 80.
S. L. Ruby and P. A. Flinn, Rev. Mod. Phys. 36, 351 (1964).
R. L. Collins, J. Chem. Phys. 42, 1072 (1965).
J. C. Travis, Ph.D. thesis. Department of Physics, The University of Texas, Austin, Texas, August, 1967;
R. L. Collins and J. C. Travis, Mössbauer Effect Methodology, Vol. 3, (Plenum Press, New York, 1967), p. 123.
S. V. Karyagin, Dokl Akad. Nauk SSSR 148, 1102 (1963) (in Russian);Proc. Acad. Sci. USSR, Phys. Chem. Sec. 148, 110 (1964) (in English).
P. A. Flinn, S. L. Ruby, and W. L. Kehl, Scientific Paper 63–128–117, p.6, Westing- house Research Laboratories, Beulah Road, Churchill Borough, Pittsburgh, Pennsylvania.
P. Zory, Phys. Rev. 140, A1401 (1965).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1971 Plenum Press, New York
About this chapter
Cite this chapter
Travis, J.C. (1971). The Electric Field Gradient Tensor. In: May, L. (eds) An Introduction to Mössbauer Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8911-8_4
Download citation
DOI: https://doi.org/10.1007/978-1-4684-8911-8_4
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4684-8913-2
Online ISBN: 978-1-4684-8911-8
eBook Packages: Springer Book Archive