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Abstract

The nuclear portion of the electric quadrupole interaction, along with its application to nuclear physics, was described by Professor Hafemeister in the previous chapter. The importance of the nuclear part, for the purposes of this chapter, is that the extra-nuclear portion, the electric field gradient (EFG) tensor, cannot be extracted from experimental data without prior knowledge of certain nuclear spins and moments. The required information, if known, may be easily located in the Mössbauer Effect Data Index [1], and the use of such information to relate observed splittings to the EFG tensor is illustrated in this chapter. In addition, the following sections describe the prediction of the EFG tensor for an assumed molecular crystal model, special techniques and hints, and the utility of EFG information.

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References

  1. A. H. Muir, Jr., K. J. Ando, Helen M. Coogan, Eds., Mössbauer Effect Data Index 1958–1965 (Interscience Publishers, New York, 1966).

    Google Scholar 

  2. R. M. Sternheimer, Phys Rev, 80, 102 (1950); 84, 244 (1951); 130, 1423 (1963);

    Article  CAS  Google Scholar 

  3. H. M. Foley, R. M. Sternheimer, and D. Tycko, ibid. 93, 734 (1954);

    CAS  Google Scholar 

  4. R. M. Sternheimer and H. M. Foley, ibid. 102, 731 (1956).

    CAS  Google Scholar 

  5. R. Ingalls, Phys. Rev. 128, 1155 (1962).

    Article  CAS  Google Scholar 

  6. R. M. Sternheimer, Phys. Rev. 130, 1423 (1963).

    Article  CAS  Google Scholar 

  7. Michael J. Bielefeld, Semi-empirical Treatment of the Mössbauer Quadrupole Splitting. Research Institute for Natural Sciences, Woodstock College, Woodstock, Maryland, NASA grant NsG-670.

    Google Scholar 

  8. P. R. Edwards, C. E. Johnson, and R. J. P. Williams, Chem. Phys. 47, 2074 (1967).

    CAS  Google Scholar 

  9. R. Ingalls, Phys. Rev. 133, A787 (1964).

    Article  Google Scholar 

  10. J. R. Gabriel and S. L. Ruby, Nucl. Instr. Methods 36, 23 (1965).

    Article  Google Scholar 

  11. G. K. Wertheim, Mössbauer Effect (Academic Press, New York, 1964), p. 80.

    Google Scholar 

  12. S. L. Ruby and P. A. Flinn, Rev. Mod. Phys. 36, 351 (1964).

    Article  Google Scholar 

  13. R. L. Collins, J. Chem. Phys. 42, 1072 (1965).

    Article  CAS  Google Scholar 

  14. J. C. Travis, Ph.D. thesis. Department of Physics, The University of Texas, Austin, Texas, August, 1967;

    Google Scholar 

  15. R. L. Collins and J. C. Travis, Mössbauer Effect Methodology, Vol. 3, (Plenum Press, New York, 1967), p. 123.

    Google Scholar 

  16. S. V. Karyagin, Dokl Akad. Nauk SSSR 148, 1102 (1963) (in Russian);Proc. Acad. Sci. USSR, Phys. Chem. Sec. 148, 110 (1964) (in English).

    Google Scholar 

  17. P. A. Flinn, S. L. Ruby, and W. L. Kehl, Scientific Paper 63–128–117, p.6, Westing- house Research Laboratories, Beulah Road, Churchill Borough, Pittsburgh, Pennsylvania.

    Google Scholar 

  18. P. Zory, Phys. Rev. 140, A1401 (1965).

    Article  Google Scholar 

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© 1971 Plenum Press, New York

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Travis, J.C. (1971). The Electric Field Gradient Tensor. In: May, L. (eds) An Introduction to Mössbauer Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-8911-8_4

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  • DOI: https://doi.org/10.1007/978-1-4684-8911-8_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-8913-2

  • Online ISBN: 978-1-4684-8911-8

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