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The Synthesis of Aromatic Polyformals

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New Monomers and Polymers

Abstract

The synthesis of aliphatic polyformals (1) has been known for many years and is relatively straightforwardl. As shown in equation 1, aliphatic diols can be reacted directly with formaldehyde or dialkyl formals (2) to produce these polymers. The principal complication of the reaction occurs when the diol used contains 2, 3 or 4 carbon atoms in which case the formation of the cyclic formal (3) is favored.

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© 1984 Plenum Press, New York

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Williams, F.J. et al. (1984). The Synthesis of Aromatic Polyformals. In: Culbertson, B.M., Pittman, C.U. (eds) New Monomers and Polymers. Polymer Science and Technology, vol 25. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-4619-7_5

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  • DOI: https://doi.org/10.1007/978-1-4684-4619-7_5

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-4621-0

  • Online ISBN: 978-1-4684-4619-7

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