Skip to main content

The Problem of the Cold Brittleness of Refractory Metals and Alloys

  • Chapter
Physical Metallurgy of Refractory Metals and Alloys

Abstract

In addition to the oxidizability and poor weldability of refractory metals, their cold brittleness forms the principal obstacle to their utilization in the new technology. Transition from the ductile to the brittle state occurs in refractory metals in a certain temperature range. Group Va metals and particularly group VIa metals having a bcc lattice show a tendency to lose ductility on cooling (Fig. 73). Group VIa metals and primarily tungsten have the highest ductile—brittle transition temperature. Iron is the classic example of a cold-brittle metal.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

eBook
USD 16.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

Literature Cited

  1. N. N. Davidenkov and G. N. Chuchman, in: Research on Refractory Metals [in Russian], Vol. 2, Izd. Akad. Nauk SSSR, p. 9 (1957).

    Google Scholar 

  2. N. N. Davidenkov, in: Research on Refractory Metals [in Russian], Vol. 4, Izd. Akad. Nauk SSSR, p. 13 (1959).

    Google Scholar 

  3. V. S. Ivanova and Yu. I. Ragozin, Izv. Akad. Nauk SSSR, Neorganicheskie Materialy, 1(10):1684 (1965).

    CAS  Google Scholar 

  4. I. A. Oding, Theory of Dislocations in Metals and Its Application [in Russian], Izd. Akad. Nauk SSSR (1959).

    Google Scholar 

  5. V. I. Trefilov, in: Physical Nature of the Brittle Fracture of Metals [in Russian], Kiev, Izd. “Naukova Dumka,” p. 22 (1965).

    Google Scholar 

  6. E. M. Savitskii, Influence of Temperature on the Mechanical Properties of Metals and Alloys [in Russian], Izd. Akad. Nauk SSSR (1957)

    Google Scholar 

  7. E. M. Savitskii, Izv. Akad. Nauk SSSR, Metally, No, 5, p. 3 (1965).

    Google Scholar 

  8. E. M. Savitskii, Izv. Akad. Nauk SSSR, OTN, Metallurgiya i Toplivo, No. 5, p. 52 (1960).

    Google Scholar 

  9. E. M. Savitskii and G. P. Tsarev, Izv. Akad. Nauk SSSR, Metally, No. 2, p. 84 (1965).

    Google Scholar 

  10. G. T. Hahn, A. Gilbert, and R. I. Jaffee, Proc. Refractory Metals Sympos., Chicago, p. 23 (April 1962).

    Google Scholar 

  11. M. V. Lomonosov, Complete Works [in Russian], Vol. 1, Izd. Akad. Nauk SSSR (1950).

    Google Scholar 

  12. N. V. Ageev, Nature of the Chemical Bond in Alloys [in Russian], Izd. Akad. Nauk SSSR (1947).

    Google Scholar 

  13. M. I. Korsunskii and Ya. E. Genkin, Izv. Akad. Nauk SSSR, Seriya Fizicheskaya, 28(5):832 (1964).

    CAS  Google Scholar 

  14. Collection: Ultrasonic Metals [in Russian], Izd. “Metallurgiya” (1966).

    Google Scholar 

  15. J. M. Ziman, Theory of Solids, Cambridge University Press, New York (1965).

    Google Scholar 

  16. Collection: Electronic Structure of Transition Metals and the Chemistry of Their Alloys [in Russian], Izd. “Metallurgiya” (1966).

    Google Scholar 

  17. Express Information, Metallovedenie i Termoobrabotka [in Russian], VINITI, No. 4, p. 1 (Abstr. 12) (1965).

    Google Scholar 

  18. J. G. Bechtold and E. T. Bessel, in: Molybdenum [Russian translation], IL, p. 159 (1962).

    Google Scholar 

  19. D. L. Wood and J. H. Westbrook, Reprint from Proceedings ASTM, 63:759 (1963).

    Google Scholar 

  20. E. M. Shvetsova, Zavod. Lab., 4(6):694 (1935).

    Google Scholar 

  21. G. I. Pogodin-Alekseev, Properties of Metals under Impact Stress [in Russian], Metal-lurgizdat (1953).

    Google Scholar 

  22. R. I. Jaffee, Problemy Sovremennoi Metallurgii, No. 6, p. 115 (1960).

    Google Scholar 

  23. M. Semchyshen and R. Q. Barr, in: Refractory Metals and Alloys [in Russian], Izd. “Metallurgiya,” p. 149 (1966).

    Google Scholar 

  24. E. M. Savitskii and V. A. Trapeznikov, in: Research on Heat-Resistant Alloys, Vol. II, Izd. Akad. Nauk SSSR, p. 141 (1957).

    Google Scholar 

  25. A. P. Gulyaev and V. N. Nikitin, Zavod. Lab., 30(7):885 (1964).

    Google Scholar 

  26. Express Information, Metallovedenie i Termoobrabotka, VINITI, No. 4 (Abstr. 13) (1965).

    Google Scholar 

  27. E. M. Savitskii, G. S. Burkhanov, and Ch. V. Kopetskii, Izv. Akad. Nauk SSSR, Metallurgiya i Gornoe Delo, No. 6, p. 12 (1963).

    Google Scholar 

  28. I. A. Gindin and Ya. D. Starodybov, Fiz. Metallov i Metallovedenie, 15(5):736 (1963).

    CAS  Google Scholar 

  29. E. M. Savitskii and G. E. Chuprikov, Izv. Akad. Nauk SSSR, OTN, Metallurgiya i Toplivo, No. 4, p. 137 (1962).

    Google Scholar 

  30. A. L. Eustice and O. N. Carlson, Trans. AIME, 221:238 (1961).

    CAS  Google Scholar 

  31. J. H. Bechtold, Acta Metallurgica, 3:249 (1955).

    Article  CAS  Google Scholar 

  32. A. G. Imgram, F. C. Holden, H. R. Ogden, and R. I. Jaffee, Trans. AIME, 221:517 (1961).

    CAS  Google Scholar 

  33. V. N. Platt, in: Molybdenum [Russian translation], IL, p. 246 (1949).

    Google Scholar 

  34. H. L. Vane, F. Henderson, S. T. Johnstown, and N. J. Luat, Problemy Sovremennoi Metallurgii, No. 6, p. 115 (1958).

    Google Scholar 

  35. E. M. Savitskii and G. L. Tsarev, Izv. Akad. Nauk Belorussian SSR, Seriya Fiz.-Tekhn. Nauk, No. 2, p. 84 (1965).

    Google Scholar 

  36. E. M. Savitskii and G. L. Tsarev, in: Growth and Imperfections of Metal Crystals [in Russian], Izd. “Naukova Dumka,” p. 290 (1966).

    Google Scholar 

  37. G. T. Hahn, A. Gilbert, and R. I. Jaffee, Refractory Metals and Alloys, II (Metallurgical Society Conferences, Vol. 17), New York, pp. 23–63 (1963).

    Google Scholar 

  38. N. K. Popov, E. M. Savitskii, and G. L. Tsarev, Dokl. Akad. Nauk SSSR, 162(1):64 (1965).

    CAS  Google Scholar 

  39. G. V. Samsonov and K. I. Portnoi, Alloys Based on Refractory Compounds [in Russian], Oborongiz (1961).

    Google Scholar 

  40. O. Kubaschewski and E. L. Evans, Metallurgical Thermochemistry, Pergamon, New York, 3rd ed. (1958).

    Google Scholar 

  41. E. B. Bas, L. Preuss, and W. Epprecht, Z. Metallkunde, 48(12):516 (1957).

    CAS  Google Scholar 

  42. R. I. Jaffee, J. Metals, 410 (May 1960).

    Google Scholar 

  43. H. Braun, M. Samchyshen, and R. Q. Barr, Metallwerk Plansee A. G. Reutte/Tyrol, 35 (1965).

    Google Scholar 

  44. A. Gilbert, W. R. Warke, and B. A. Wilcox, J. Less-Common Metals, No. 7, p. 222 (1964).

    Google Scholar 

  45. E. M. Savitskii, G. S. Burkhanov, Ch. V. Kopetskii, and G. E. Chuprikov, in: “Growth of Crystals” [in Russian], Izd. “Nauka,” p. 308 (1965).

    Google Scholar 

  46. E. Rudy, F. Benesovsky, and L. Toth, Z. Metallkunde, 54(6):345 (1963).

    CAS  Google Scholar 

  47. G. S. Bazinskii and É. Slisvik, Problemy Sovremennoi Metallurgiya, No. 4, p. 109 (1957).

    Google Scholar 

  48. E. M. Savitskii, Metall, i. Term. Obrabotka, No. 7, p. 3 (1965).

    Google Scholar 

  49. G. S. Speisel and J. Wulf, in: Molybdenum [Russian translation], IL (1962).

    Google Scholar 

  50. R. C. Koo, Trans. Met. Soc. AIME, 227(1):280 (1963).

    CAS  Google Scholar 

  51. D. J. Maykuth and R. I. Jaffee, Problemy Sovremennoi Metallurgii, No. 1, p. 83 (1958).

    Google Scholar 

  52. D. A. Robins, J. Less-Common Metals, 1:396 (1959).

    Article  CAS  Google Scholar 

  53. E. M. Savitskii, Rare Metals and Alloys [in Russian], Moscow, Izd. Doma Tekhniki (1959).

    Google Scholar 

  54. L. L. Seigle and M. D. Dickinson, Proc. Refractory Metals Sympos., Chicago (April 1962).

    Google Scholar 

  55. N. J. Petch, Atomic Mechanism of Fracture [Russian translation], Metallurgizdat (1965).

    Google Scholar 

  56. R. C. Koo, J. Less-Common Metals, 3(5) (1961).

    Google Scholar 

  57. A. J. Opinsky et al., Proc. Refractory Metals Sympos., Chicago (April 1962).

    Google Scholar 

  58. A. H. Cottrell, Dislocations and Plastic Flow in Crystals, Oxford University Press, New Jersey (1953).

    Google Scholar 

  59. A. H. Cottrell and B. A. Bilby, Proc. Roy. Soc. A, 62:49 (1949).

    Google Scholar 

  60. E. T. Wessel, J. Metals, 9:930 (1957).

    CAS  Google Scholar 

  61. N. Mott, The Rutherford Memorial Lecture, Atomic Physics and the Strength of Metals (1962).

    Google Scholar 

  62. G. A. Verbraak, Z. Metallkunde, 55(12):723 (1964).

    Google Scholar 

  63. G. Schoeck, Acta Metallurgica, 9:382 (1961).

    Article  CAS  Google Scholar 

  64. A. H. Cottrell, Trans. ASME, 46A:13 (1964).

    Google Scholar 

  65. J. W. Pugh, J. Metals, 10(5):335 (1958).

    Google Scholar 

  66. J. W. Pugh, J. Metals, 9(10):1243 (1957).

    Google Scholar 

  67. U. R. Hibbard, in: Mechanism of the Strengthening of Solids [in Russian], Izd. Metallurgiya, p. 9 (1965).

    Google Scholar 

  68. W. G. Johnston and P. S. Gilman, J. Appl. Phys., 30:129 (1959).

    Article  CAS  Google Scholar 

  69. L. L. Seigle and Dickinson, Refractory Metals and Alloys, Vol. 17, p. 65, Chicago (April 1962).

    Google Scholar 

  70. A. Seeger, Phil. Mag., No. 46, p. 1194 (1955).

    Google Scholar 

  71. E. M. Savitskii, V. V. Baron, Yu. V. Efimov, and V. A. Frolov, in: Questions of the Theory and Application of Rare-Earth Metals [in Russian], Izd. “Nauka” (1964).

    Google Scholar 

  72. E. M. Savitskii, Metallovedenie i Termoobrabotka Metallov, No. 9, p. 19 (1961).

    Google Scholar 

  73. R. T. Begley and J. H. Bechtold, J. Less-Common Metals, 3(1):1 (1961).

    Article  CAS  Google Scholar 

  74. F. Schmidt, W. Klopp, D. Maykuth, H. Ogden, and R. I. Jaffee, WADD TR 61–106 (1961).

    Google Scholar 

  75. E. M. Savitskii, Izv. Akad. Nauk SSSR, OTN, Metallurgiya i Toplivo, No. 5, p. 52 (1960).

    Google Scholar 

  76. R. Smith and A. Hendrickson, in: Superpure Metals [Russian translation], Izd. “Metallurgiya,” p. 78 (1966).

    Google Scholar 

  77. E. P. Abrahamson and N. J. Grant, Trans. ASME, 50:705 (1958).

    Google Scholar 

  78. R. I. Jaffee, D. J. Maykuth, and R. U. Douglass, Rhenium and Refractory Metals of the Platinum Group [Russian translation], IL (1963).

    Google Scholar 

  79. E. M. Savitskii and Tao Chu-Chun, Fizika Metallov i Metallovedenie, 14(1):148 (1962).

    CAS  Google Scholar 

  80. E. M. Savitskii, M. A. Tylkina, and K. B. Povarova, Rhenium Alloys [in Russian], Izd. Akad. Nauk SSSR (1965).

    Google Scholar 

  81. P. A. Flinn, in: Mechanism of the Strengthening of Solids [in Russian], Izd. “Metallurgiya,” p. 25 (1965).

    Google Scholar 

  82. E. M. Savitskii, M. A. Tylkina, and K. B. Povarova, Dokl. Akad. Nauk SSSR, 119(2):274 (1958).

    CAS  Google Scholar 

  83. M. A. Tylkina, K. B. Povarova, and E. M. Savitskii, Zh. Neorgan. Khimii, 5(11):2458 (1960).

    CAS  Google Scholar 

  84. D. J. Maykuth, F. C. Holden, and K. J. Jaffee, Rhenium, Amsterdam, p. 114 (1962).

    Google Scholar 

  85. T. G. Booth, R. I. Jaffee, and E. L. Salkovitz, Metallwerk Plansee, A. G. Reutte/Tyrol (1965).

    Google Scholar 

  86. A. Gilbert, C. N. Reid, and G. T. Gahn, AIME Meeting, New York (February 1964).

    Google Scholar 

  87. R. Kieffer, K. Seldachek, and H. Braun, Problemy Sovremennoi Metallurgii, No. 4, p. 164 (1959).

    Google Scholar 

  88. C. S. Wukusick, Evaluation of Chromium—Ruthenium Alloys, General Electric (June 25, 1965).

    Google Scholar 

  89. R. Orava, Trans. Met. Soc. AIME, 230(7):1614 (1964).

    Google Scholar 

  90. J. H. Bechtold, J. Metals, 5:1969 (1953).

    Google Scholar 

  91. J. H. Bechtold, E. T. Wessel, and L. L. France, Refractory Metals and Alloys, Inter-science, New York, p. 25 (1961).

    Google Scholar 

  92. L. D. Sokolov, Resistance of Metals to Plastic Deformation [in Russian], Metallurgizdat (1963).

    Google Scholar 

  93. N. N. Davidenkov, The Impact Problem in Physical Metallurgy [in Russian], Izd. Akad. Nauk SSSR (1938).

    Google Scholar 

  94. S. I. Gubkin, Theory of the Working of Metals by Pressure [in Russian], Metallurgizdat (1947).

    Google Scholar 

  95. S. I. Gubkin and E. M. Savitskii, Izv. Sektora Fiz.-Khim. Analiza, 14:235 (1941).

    Google Scholar 

  96. E. S. Atroshchenko, P. O. Pashkov, and I. M. Rodinskaya, Fizika Metall, i Metalloved., 19(4):619 (1965).

    Google Scholar 

  97. P. W. Bridgman, Studies in Large Plastic Flow and Fracture, McGraw-Hill, New York (1952).

    Google Scholar 

  98. E. J. Imgram, F. S. Holden, H. R. Ogden, and R. I. Jaffee, Problemy Sovremennoi Metallurgii, No. 6, p. 80 (1961).

    Google Scholar 

  99. E. M. Savitskii, Dokl. Akad. Nauk SSSR, 89(1):85 (1963).

    Google Scholar 

  100. J. Stephens, Some Problems of Refractory Metals and Alloys [Russian translation], IL, p. 89 (1963).

    Google Scholar 

  101. G. S. Zhdanov, Solid State Physics [in Russian], Izd. MGU (1962).

    Google Scholar 

  102. N. S. Kurnakov, Collected Works [in Russian], Vols. I and II, Izd. Akad. Nauk SSSR (1960–61).

    Google Scholar 

  103. S. I. Gubkin, Plastic Deformation [in Russian], Vol. 2, Metallurgizdat (1960).

    Google Scholar 

  104. E. M. Savitskii, V. F. Terekhova, I. V. Burov, I. A. Markova, and O. P. Naumkin, Alloys of the Rare-Earth Metals [in Russian], Izd. Akad. Nauk SSSR (1962).

    Google Scholar 

  105. Yu. V. Mil’man, A. P. Rachek, and V. I. Trefilov, in: Scientific Transactions of the Metal Institute of the Academy of Sciences, Ukrainian SSR [in Russian], Kiev, No. 20, p. 3 (1960).

    Google Scholar 

  106. E. M. Savitskii, V. V. Baron, and Tao Chu-Chun, Izv. Akad. Nauk SSSR, OTN, Metal-lurgiya i Toplivo, No. 1, p. 151 (1962).

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 1970 Consultants Bureau, New York

About this chapter

Cite this chapter

Savitskii, E.M., Burkhanov, G.S. (1970). The Problem of the Cold Brittleness of Refractory Metals and Alloys. In: Physical Metallurgy of Refractory Metals and Alloys. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1572-8_4

Download citation

  • DOI: https://doi.org/10.1007/978-1-4684-1572-8_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-1574-2

  • Online ISBN: 978-1-4684-1572-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics