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Electroconductive Polymer/Metal Composites

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Metal/Polymer Composites

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Abstract

Electrically conductive nonmetallic materials have been in the forefront of scientific research in recent years. The development of high transition temperatures for superconductivity in ceramics has won high acclaim. Equally important are the achievements in obtaining good electrical conductivity in polymers. This chapter covers the principal techniques for attaining good electrical conductivity in polymers:

  • Synthesis of electroactive polymers and use of dopants and charge transfer salts

  • Deposition of metallic elements in polymers by thermal decomposition of specific metallo-organic compounds

  • Metallic ion implantation techniques

  • Compounding of polymers with conductive metal powders and carbon black

  • Vacuum metallization of polymers is discussed in Chapter 5.

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References

  1. Cowan, D. and Wigul, F., “The Organic Solid State,” C and E News, 64:28, (July 21, 1986).

    Article  Google Scholar 

  2. Edelson, E., “Polymers That Conduct Electricity,” Mosaic, 19:14, (Spring 1988) and 14(2):41, (Spring 1983).

    Google Scholar 

  3. Maugh, T., Science, 222:606, (November 11, 1983).

    Article  Google Scholar 

  4. Anon., Chemical Week, p. 56, (March 9, 1968).

    Google Scholar 

  5. Rembaum, A., CA78-43 986d (February 26, 1973).

    Google Scholar 

  6. Ferrara, J., et. al., Applied Spectroscopy, 41:1377, (August 1987).

    Article  Google Scholar 

  7. Heeger, A., Studies of Charge Transfer Process, Cal Tech Conference, (November 1984).

    Google Scholar 

  8. Duke, C. (Xerox Corp.), Synthetic Metals, 21:5, (1987).

    Article  Google Scholar 

  9. MacDiarmid, A., Synthetic Metals, 21:79, (1987).

    Article  Google Scholar 

  10. Anon., C and E News, p. 29, (April 19, 1982).

    Google Scholar 

  11. Kusy, R., Metal-Filled Polymers, p. 51, New York: M. Dekker, (1986).

    Google Scholar 

  12. Skotheim, T. A., Handbook of Conducting Polymers, Vols. 1 and 2, New York: M. Dekker, (February 1986).

    Google Scholar 

  13. Delmonte, J., Metal Filled Plastics, New York: Reinhold Publishing Co., (1961).

    Google Scholar 

  14. Seymour, R. B., Conductive Polymers, New York: Plenum Press, (1981).

    Book  Google Scholar 

  15. Baughman, R. N., et al., “Conducting Polymers-Synthesis and Properties” — A.C.S. Polymer Preprints, 23:130, (March 1982).

    Google Scholar 

  16. Jenekhe, S. A. (Honeywell), U.S. 4,717,762, (January 5, 1988).

    Google Scholar 

  17. Jenekhe, J., U.S. 4,631,323, (December 23, 1986).

    Google Scholar 

  18. Murakami, M. and Yoshi, S., Synthetic Metals (18), p. 509, (1987).

    Google Scholar 

  19. Klavetter, F. and Grubbs, R., Polymer Material, Science and Engineering, A.C.S., 58:855, (1988) and C and E News, 66:23, (October 31, 1988).

    Google Scholar 

  20. Roberts, W., et al., 4,604,427 (Grace Co.), (August 5, 1986).

    Google Scholar 

  21. Maclnnes, D., Polymer Materials, Science and Engineering, A.C.S., 58:851, (1988).

    Google Scholar 

  22. Papir, Y. to Chevron Research Co., U.S. 4,519,937, (May 28, 1985).

    Google Scholar 

  23. Delannoy, P., et al., Enhancing Conductivity of Doped Polyacetylyene, U.S. 4,502,981, Allied Signal Company, (March 2, 1985).

    Google Scholar 

  24. Thakur, M., Macromolecules, 21:661, (1988).

    Article  Google Scholar 

  25. Naarmann, H and Theophilou, P., New Process for Polyacetylene Films, Synthetic Metals, 22:1, (1987).

    Google Scholar 

  26. Baughman, R. and Shacklette, L. Synthetic Metals, (17), p. 1,733, (1987).

    Google Scholar 

  27. CA 106(20), 166 991f and 167066u, (1987).

    Google Scholar 

  28. Heeger, A., et al., U.S. 4,222,903, (September 16, 1980).

    Google Scholar 

  29. Feldstein, N. (RCA Corp.) U.S. 3697319, (October 10, 1972).

    Google Scholar 

  30. Osterholm, J., et al., Studies of Polythiophene, Synthetic Metals, 18:169, (1987).

    Google Scholar 

  31. Berlin, A., et al. Synthetic Metals, 18:157, (1987).

    Article  Google Scholar 

  32. Ramos, A., et al., SPE Tech. Paper, 23:393, (1977).

    Google Scholar 

  33. Takakura, M. et al., (Nissan Chemical), U.S. 4,666,742, (May 19, 1987).

    Google Scholar 

  34. Porta, G. and Taylor, L., Jl. of Material Research, 3(2):211, (March/April 1988).

    Article  Google Scholar 

  35. Schock, F. and Partco, J., Conductive Polyphenylene Sulphide, ANTEC, 44th Annual Meeting, S.P.E., p. 273, (1986).

    Google Scholar 

  36. Wada, T., et al., Synthetic Metals, 18:585, (1987).

    Article  Google Scholar 

  37. Lagues, M. and Sauterey, C., Jl of Physical Chemistry, 84:3,503, (1980).

    Google Scholar 

  38. Bridge, B., Jl of Material Science Letter, 7:663, (June 1988).

    Article  Google Scholar 

  39. Bigg, D., “Electrical Properties of Metal Filled Polymer Composites,” In Metal-Filled Polymers, Bhattacharya, S.K. (Ed.), New York: M. Dekker, (1986).

    Google Scholar 

  40. Milewski, J., Ind. Eng. Chem. Prod. Res. Dev., 17:363, (1978).

    Article  Google Scholar 

  41. Liu, N. and VanderMeer, R. to General Electric, Electric Conductive Thermoplastics Composites, U.S. 4,566,990, (January 28, 1987), and Eur. P. 185,783, (July 2, 1986).

    Google Scholar 

  42. C.A. 104(20), 170208g, Fukuda Metal Foil and Powder Co., J.P. 60,226,570, (November 11, 1985).

    Google Scholar 

  43. C.A. 107-145725c, Kuramoto, K., J.P. 62,29-007, (February 7, 1987).

    Google Scholar 

  44. Lang, G., et al., Extrusion, West Germany: D. G. Metallkunde, (1981).

    Google Scholar 

  45. C.A. 105-154207w, to Kanebo Ltd., J.P. 61,141,762, (June 28, 1986).

    Google Scholar 

  46. C.A. 105(18) 154371v, Nippon Seisen Co. J.P. 61,127,198, (June 14, 1986).

    Google Scholar 

  47. C.A. 105(18) 154806r, Seisuki Chemical, (1986).

    Google Scholar 

  48. C.A. 106-94529b, to Taiyo Jouden Co., J.P. 61,121,204, (June 9, 1986).

    Google Scholar 

  49. C.A. 106(14) 112171v April 1987, To Toshiba Corp., J.P. 61,107,605, (May 26, 1986).

    Google Scholar 

  50. C.A. 105(14) 103038e, Nippon Petrochemical, J.P. 1,236,841, (October 22, 1986).

    Google Scholar 

  51. C.A. 106(14) 103487a, J.P. 61,253,713, (November 11, 1986).

    Google Scholar 

  52. C.A. 106(14) 103740c, To Mitsubishi, J.P. 61,245,372, (October 31, 1986).

    Google Scholar 

  53. C.A. 106-106554f, April 1987, to IBM, E.P.A. 206,145, (December 30, 1986).

    Google Scholar 

  54. C.A. 106-159631k to Sumitomo Bakelite, J.P. 62,15,762, (January 24, 1987).

    Google Scholar 

  55. C.A. 106-161023g, Showa Elec. Wire Co., J.P. 61,276,952, (December 6, 1986); Furukowa Elec. Co., J.P. 61,279,661, (December 10, 1986); Showa Denko Kiki, J.P. 61,279,662, (December 10, 1986).

    Google Scholar 

  56. C.A. 106-167271h, Aron Kasei Co., J.P. 61,228,913, (October 13, 1986).

    Google Scholar 

  57. Sorensen, I., Polymer Metal Blends, to Allied Signal Co., U.S. 4,557,857, (December 10, 1985). Re also: Gergen, U.S. 4,088,626.

    Google Scholar 

  58. Coler, M. A., Mfr. of Conductive Plastic, U.S. 2,761,854, (September 4, 1956).

    Google Scholar 

  59. Roberts, W. and Schulz, L., Electrical Conductive Polymer Blends, U.S. 4,604,427, (August 5, 1986).

    Google Scholar 

  60. Janeczek, D. (Raytheon), Conductive Nickel Coated Graphite Fibers, ANTEC, 44th Annual Meeting of S.P.E., p. 226, (1983).

    Google Scholar 

  61. Delmonte, J., “Photodielectric Analysis of Materials,” Modern Plastics, V. 24, p. 163, (February 1947).

    Google Scholar 

  62. Jones, M. to Hercules Corp., U.S. 4,002,595, (January 11, 1977).

    Google Scholar 

  63. Hunter, F. to Acheson Industries, U.S. 3,099,578, (July 3, 1963).

    Google Scholar 

  64. Kaufman, C. and Hall, R. (Shawinigan Chemicals), U.S. 2,453,440, (November 9, 1948).

    Google Scholar 

  65. Giet, C. (Products Chimiques, France), U.S. 4,279,880, (July 21, 1981).

    Google Scholar 

  66. Galli, E., Plastic Compounding, p. 22, (March/April 1982).

    Google Scholar 

  67. Litant, I. to Avco, U.S. 3,406,126, (October 15, 1968).

    Google Scholar 

  68. Sony Corp., U.S. 4,229,328, (October 21, 1980).

    Google Scholar 

  69. Cabot Corp., Conductive Carbon Black, Report S-39, (1988).

    Google Scholar 

  70. Delollis, N. (Sandia), National SAMPE Symposium, Albuquerque, p. 565, (1976).

    Google Scholar 

  71. Meyer, J. V. Texas Instruments Inc., U.S. 3,673,121, (June 27, 1972).

    Google Scholar 

  72. Middelman, J. M. and Doljack, F., Raychem Corp., U.S. 4,475,138, (October 2, 1984).

    Google Scholar 

  73. Liao, S., Microwave Devices and Circuits, Englewood Cliffs, NJ: Prentice Hall Publishing Co., (1980).

    Google Scholar 

  74. Elsenbaumer, R. L., et al. (Allied), “Stablility of Doped Conducting Polymers,” A.C.S. Polymers, Vol. 56, p. 54, (1987).

    Google Scholar 

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Authors and Affiliations

  1. Delsen Testing Laboratories, Glendale, California, USA

    John Delmonte

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  1. John Delmonte
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© 1990 Springer Science+Business Media New York

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Delmonte, J. (1990). Electroconductive Polymer/Metal Composites. In: Metal/Polymer Composites. Springer, Boston, MA. https://doi.org/10.1007/978-1-4684-1446-2_4

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  • DOI: https://doi.org/10.1007/978-1-4684-1446-2_4

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4684-1448-6

  • Online ISBN: 978-1-4684-1446-2

  • eBook Packages: Springer Book Archive

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