Abstract
The study of bimolecular gas reaction rate coefficients has been one of the primary subjects of kinetics investigations over the last 20 years. Largely as a result of improved reaction systems (static flash photolysis systems, flow reactors, and shock tubes) and sensitive detection methods for atoms and free radicals (atomic and molecular resonance spectrometry, electron paramagnetic resonance and mass spectrometry, laser-induced fluorescence, and laser magnetic resonance), improvements in both the quality and the quantity of kinetic data have been made. Summarizing accounts of our present knowledge of the rate coefficients for reactions important in combustion chemistry are given in Chapters 5 and 6.
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References
Arrhenius, S. (1889). Z. Physik. Chemie 4, 226.
Baulch, D. L. & Drysdale, D. D. (1974). Comb. Flame 23, 215.
Baulch, D. L., Drysdale, D. D., Horne, D. G., & Lloyd, A. C. (1972). Evaluated Data for High Temperature Reactions, Vol. 1, Butterworths, London.
Benson, S. W., (1975). J. Chem. Kin. Symp. Vol. 1, 359.
Benson, S. W., (1976). Thermochemical Kinetics, 2nd Ed., Wiley, New York.
Bernstein, R. B. (1966). In Adv. Chem. Phys. 10, p. 75, J. Ross (Ed.), Interscience Publishers.
Biermann, H. W., Zetzsch, C, & Stuhl, F. (1978). Ber. Bunsenges. Phys. Chem. 82, 633.
Birely, J. H. & Lyman, J. L. (1975). J. Photochem. 4, 269.
Bunker, D. L., (1966). Theory of Elementary Gas Reaction Rates, Pergamon Press, Oxford University Press, New York.
Chan, W. H., Uselman, M., Calvert, J. G., & Shaw, J. H. (1977). Chem. Phys. Lett. 45, 340.
Clark, T. C., Dove, J. E., & Finkelman, M. (1977). Proc. 6th Int. Coll. Gasdynamics of Explosions and Reactive Systems, Stockholm.
Clary, D. C., Connor, J. N. L., & Edge, C. J. (1979). Chem. Phys. Lett. 68, 154.
Douglas, D. J. & Polanyi, J. C., (1976). Chem. Phys. 16, 1.
Dove, J. E. & Teitelbaum, H. (1974). Chem. Phys. 6, 431.
Dreier, T., Wolfrum, J. (1981). 18th Symp. (Int.) on Combustion, The Combustion Institute, Pittsburgh, p. 801.
Dryer, F., Naegeli, D., & Glassman, I. (1971). Comb. Flame 17, 270.
Dubrin, J. (1973). Ann. Rev. Phys. Chem. 74, 97.
Eliason, M. & Hirschfelder, J. O. (1959). J. Chem. Phys. 30, 1426.
Ernst, J., Wagner, H. Gg., & Zellner, R. (1977). Ber. Bunsenges. Phys. Chem. 81, 1270.
Ernst, J., Wagner, H. Gg., & Zellner, R. (1978). Ber. Bunsenges. Phys. Chem. 82, 409.
Eyring, H. (1935). J. Chem. Phys. 3, 107.
Eyring, H. & Lin, S. H. (1974). In Physical Chemistry: An Advanced Treatise, Vol. VI-A, H. Eyring, D. Henderson and W. Jost, Eds., Academic Press, New York.
Felder, W. & Fontijn, A. (1979). Chem. Phys. Lett. 67, 53.
Fowler, R. H. & Guggenheim, E. A. (1949). Statistical Thermodynamics, Cambridge University Press, London.
Fowler, R. H. (1936). Statistical Mechanics, Cambridge University Press, London.
Gardiner, W. C., Jr. (1969). Rates and Mechanisms of Chemical Reactions, Benjamin, New York.
Gardiner, W. C., Jr., Olson, D. B., & White, J. N. (1978). Chem. Phys. Lett. 53, 134.
Garrett, B. C. & Truhlar, D. G. (1979). J. Phys. Chem. 83, 200.
Garrett, B. C., Truhlar, D. G., & Grev, R. S. (1980a). J. Chem. Phys. 73, 231.
Garrett, B. C., Truhlar, D. G., & Grev, R. S. (1980b). J. Phys. Chem. 84, 805.
Gauss, A., Jr. (1978). Chem. Phys. 68, 1689.
Gioumousis, G. & Stevenson, D. P. (1958). J. Chem. Phys. 29, 294.
Glass, G. P. & Chaturvedi, B. K. (1981). J. Chem. Phys. 75, 2749.
Glasstone, S., Laidler, K., & Eyring, H. (1941). The Theory of Rate Processes, McGraw-Hill, New York.
Golden, D. M. (1973). 14th Symp. (Int.) on Combustion, The Combustion Institute, Pittsburgh, p. 121.
Golden, D. M. (1979). J. Phys. Chem. 83, 108.
Haney, M. H. & Franklin, J. L., (1969). Trans. Far. Soc. 65, 1794.
Harding, L. B. (1981). J. Phys. Chem. 85, 10.
Herron, J. T. & Huie, R. E. (1973). J. Phys. Chem. Ref. Data 2, 467.
Herzberg, G. (1950). Molecular Spectra and Molecular Structure. I. Spectra of Diatomic Molecules, Van Nostrand, New York.
Hirschfelder, J. O. & Linnett, J. W. (1950). J. Chem. Phys. 18, 130.
Hirschfelder, J. O., Curtiss, C. F., & Bird, R. B. (1954). Molecular Theory of Gases and Liquids, Wiley, New York.
Huber, K. P. & Herzberg, G. (1979). Molecular Spectra and Molecular Structure. Constants of Diatomic Molecules, Van Nostrand, New York.
Johnson, B. R. & Winter, N. W. (1977). J. Chem. Phys. 66, 4116.
Johnston, H. S. & Parr, C. (1963). J. Am. Chem. Soc. 85, 2544.
Johnston, H. S. (1966). Gas Phase Reaction Rate Theory, Ronald Press, New York.
Kassel, L. S. (1932). The Kinetics of Homogeneous Gas Reactions, Chemical Catalog Company, New York.
Kiefer, J. H. & Lutz, R. W. (1966). J. Phys. Chem. 44, 658, 668.
Klemm, R. B., Tanzawa, T., Skolnik, E. G., & Michael, J. V. (1981) 18th Symp. (Int.) on Combustion, The Combustion Institute, Pittsburgh, p. 785.
Kneba, M. & Wolfrum, J. (1980). Ann. Rev. Phys. Chem. 31, 47.
Kuntz, P. J. (1976). In Dynamics of Molecular Collisions, Part B. W. H. Miller, Ed., Plenum, New York.
Kupperman, A. (1979). J. Phys. Chem. 83, 171.
Lambert, J. D. (1977). Vibrational and Rotational Relaxation in Gases, Clarendon Press, Oxford.
LeRoy, R. L. (1969). J. Chem. Phys. 73, 4338.
Levine, R. D. & Bernstein, R. B. (1974). Molecular Reaction Dynamics, Oxford University Press, New York.
Light, G. C. (1978). J. Chem. Phys. 68, 2831.
Light, G. C. (1979). Presented at 17th Symp. (Int.) on Combustion, The Combustion Institute, Pittsburgh.
Marcus, R. A. (1965). J. Chem. Phys. 43, 1598.
Marcus, R. A. (1974). In Techniques of Chemistry, Vol. 6, E. S. Lewis, Ed., Interscience, New York.
Menzinger, M. & Wolfgang, R. (1969). Angew. Chemie Int. Ed. 8, 438.
Menzinger, M. & Jokozeki, A. (1977). Chem. Phys. 22, 273.
Milligan, D. E. & Jacox, M. E. (1971). J. Chem. Phys. 54, 927.
Moore, C. B. & Smith, I. W. M. (1979). In Kinetics of State Selective Species, Faraday Disc. No. 67, Chemical Society, London.
Morse, P. M. (1929). Phys. Rev. 34, 57.
Mulcahy, M. F. R. (1973). Gas Kinetics, Nelson, London.
O’Neal, H. E. & Benson, S. W. (1973). In Free Radicals, J. K. Kochi, Ed., Wiley, New York.
Pauling, L. (1947). J. Am. Chem. Soc. 69, 542.
Pechukas, P. & Poliak, E. (1979). J. Chem. Phys. 71, 2062.
Pitzer, K. S. (1953). Quantum Chemistry, Prentice-Hall, New York.
Polanyi, J. C. (1972). Acc. Chem. Res. 5, 161.
Polanyi, J. C. & Schreiber, J. L. (1974). In Physical Chemistry: An Advanced Treatise, Vol. VI A, H. Eyring, Ed., Academic Press, New York.
Porter, R. N. (1976). In Dynamics of Molecular Collisions, Part B, W. H. Miller, Ed., Plenum Press, New York.
Pratt, G. L. (1969). Gas Kinetics, Wiley, London.
Present, R. D. (1959). J. Chem. Phys. 31, 7471.
Prigogine, I. (1961). J. Phys. Coll. Chem. 55, 765.
Pritchard, H. O. (1975). In Reaction Kinetics, Vol. 1, Specialists Periodical Reports, Chem. Soc., London.
Pruett, J. G., Grabiner, F. R., & Brooks, P. R. (1975). J. Chem. Phys. 63, 1173.
Quack, M. & Troe, J. (1977). Ber. Bunsenges. Phys. Chem. 81, 329.
Rosen, B. (1970) (Ed.). Spectroscopic Data Relative to Diatomic Molecules, Pergamon, Oxford.
Roth, P. & Just, Th. (1977). Ber. Bunsenges. Phys. Chem. 82, 572.
Sato, S. (1955). J. Chem. Phys. 23, 592.
Schatz, G. C. & Walch, S. P. (1980). J. Chem. Phys. 72, 776; J. Chem. Phys. 65, 4642, 4648.
Schinke, R. & Lester, W. A. Jr. (1979). J. Chem. Phys. 70, 4893.
Schott, G. L., Getzinger, R. W., & Seitz, W. A. (1974). Int. J. Chem. Kin. 6, 921.
Shaw, R. (1977). Int. J. Chem. Kin. 9, 929.
Shaw, R. (1978). J. Phys. Chem. Ref. Data 7, 1179.
Shizgal, B. & Karplus, M. (1970). J. Chem. Phys. 42, 4262.
Shizgal, B. & Karplus, M. (1971). J. Chem. Phys. 54, 4345, 4357.
Siegbahn, P. & Liu, B. (1978). J. Chem. Phys. 68, 2457.
Smith, I. W. M. (1977) Chem. Phys. Lett. 49, 112.
Smith, I. W. M. (1980). Kinetics and Dynamics of Elementary Gas Reactions, Butter-worths, London.
Smith, I. W. M. & Zellner, R. (1973). J. Chem. Soc. Farad. II. 69, 1617.
Smith, I. W. M. & Zellner, R. (1974). J. Chem. Soc. Farad. II. 70, 1045.
Spencer, J. E., Endo, H., & Glass, G. P. (1977). 16th Symposium (Int.) on Combustion, The Combustion Institute, Pittsburgh, p. 829.
Stevens, B. (1967). Collisional Activation in Gases, Int. Encyclop. Phys. Chem., Vol. 3, Pergamon, London.
Stolte, S., Henry, J. M., & Bernstein, R. B. (1976). J. Chem. Phys. 62, 2506.
Tolman, R. C. (1927). Statistical Mechanics with Applications to Physics and Chemistry, Chapter 27, Chemical Catalog Company, New York.
Troe, J. & Wagner, H. Gg. (1967). Ber. Bunsenges. Phys. Chem. 71, 937.
Truhlar, D. G. (1979). J. Phys. Chem. 83, 188.
Truhlar, D. G. & Wyatt, R. E. (1976). Ann. Rev. Phys. Chem. 27, 1.
Tully, F. B. & Ravishankara, A. R. (1980). J. Phys. Chem. 83, 46.
van’t Hoff, J. H. (1884). Etudes de Thermodynamique Chimique, F. Muller, Amsterdam.
Walch, S. P. & Dunning, Th.H. Jr., (1980). J. Chem. Phys. 72, 1303.
Walch, S. P. et al (1980). J. Chem. Phys. 72, 2894.
Weston, R. E. Jr. & Schwarz, H. A. (1976). Chemical Kinetics, Prentice Hall, New York.
Widom, B. (1971). J. Chem. Phys. 55, 44.
Wigner, E. (1938). Trans. Faraday Soc. 34, 29.
Winter, T. G. & Hill, G. C. (1967). J. Accoust. Soc. Amer. 42, 848.
Zahniser, M. S., Berquist, B. M., & Kaufman, F. (1978). Int. J. Chem. Kin. 10, 15.
Zellner, R. (1979a). J. Phys. Chem. 83, 18.
Zellner, R. (1979b). Habilitationsschrift, University of Gottingen.
Zellner, R. & Steinert, W. (1981). Chem. Phys. Lett. 81, 568.
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Zellner, R. (1984). Bimolecular Reaction Rate Coefficients. In: Gardiner, W.C. (eds) Combustion Chemistry. Springer, New York, NY. https://doi.org/10.1007/978-1-4684-0186-8_3
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