Abstract
Every student of chemistry today is well aware of the immense power of nuclear magnetic resonance spectroscopy as a structural tool in both organic and inorganic chemistry. In addition, the technique is proving of considerable importance in studies of both rate and equilibrium processes. Among the latter processes, those involving conformational changes and equilibria are perhaps the most important, and in this paper we consider the special case of conformation and isomerism involving partial double bonds. One of the examples is provided by the enolate ion and we briefly consider how NMR can be used to investigate ion pair equilibria in such a system.
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Jackman, L.M. (1970). Studies of Rate and Equilibrium Processes by Nuclear Magnetic Resonance Spectroscopy. In: Coogan, C.K., Ham, N.S., Stuart, S.N., Pilbrow, J.R., Wilson, G.V.H. (eds) Magnetic Resonance. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7373-9_16
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DOI: https://doi.org/10.1007/978-1-4615-7373-9_16
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