Abstract
A number of studies of gaseous free radicals using electron resonance techniques have been reported in the last few years [1]. Work on short-lived species has so far been restricted to diatomic radicals, but in this paper we present an account of the electron resonance spectra of two linear triatomic free radicals, NCO and NCS. Our work is incomplete, but we can describe some of the conclusions and indicate likely developments. Preliminary accounts of both spectra have been published [2,3], and the detailed analysis of the NCO spectrum is discussed elsewhere [4].
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
A. Carrington, Proc. Roy. Soc. A3O2, 291 (1968);
A. Carrington, Molecular Spectroscopy, Institute of Petroleum, 157 (1969).
A. Carrington, A.R. Fabris and N.J.D. Lucas, J. Chem. Phys. 49, 5545 (1968).
A. Carrington, A.R. Fabris and N.J.D. Lucas, Mol. Phys. 16, 195 (1969).
A. Carrington, A.R. Fabris, B.J. Howard and N.J.D. Lucas, Mol. Phys. to be published.
J.H. Van Vleck, Phys. Rev. 33, 467 (1929).
R. Renner, Z. Physik 92, 172 (1934).
H.C. Longuet-Higgins, Advances in Spectroscopy 2, 429 (1961).
A. Messiah, Quantum Mechanics (Amsterdam: North Holland Publishing Co.), Chap. XVI.
J.A. Pople, Mol. Phys. 3, 16 (1960).
J.T. Hougen, J. Chem. Phys. 36, 519 (1962).
R.N. Dixon, Phil. Trans. Roy. Soc. A252, 165 (1960).
R.N. Dixon and D.A. Ramsay, Can. J. Phys. 46, 2619 (1968).
A. Carrington, D.H. Levy and T.A. Miller, Rev. Sci. Instr. 38, 1183 (1967).
A. Carrington, G.N. Currie, D.H. Levy and T.A. Miller, J. Che.,I. Phys. 50, 2726 (1969).
A. Carrington, D.H. Levy and T.A. Miller, Advances in Chemical Physics, to be published.
A. Carrington, D.H. Levy and T.A. Miller, J. Chem. Phys.47 3801 (1967).
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 1970 Plenum Press, New York
About this paper
Cite this paper
Carrington, A., Fabris, A.R., Howard, B.J., Lucas, N.J.D. (1970). Gas-Phase Electron Resonance Spectra of Linear Triatomic Free Radicals. In: Coogan, C.K., Ham, N.S., Stuart, S.N., Pilbrow, J.R., Wilson, G.V.H. (eds) Magnetic Resonance. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-7373-9_15
Download citation
DOI: https://doi.org/10.1007/978-1-4615-7373-9_15
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4615-7375-3
Online ISBN: 978-1-4615-7373-9
eBook Packages: Springer Book Archive