Abstract
Polycrystalline-silicon films formed by chemical vapor deposition are used in a wide variety of ULSI applications requiring very different electrical properties. High-value load resistors for static random-access-memory (RAM) cells utilize the high resistance of lightly doped polysilicon to provide a convenient and stable resistor that limits the current flowing in the cell. At the other extreme, the excellent technological compatibility of polysilicon with high-temperature, integrated-circuit processing allows straightforward fabrication of self-aligned gates and convenient interconnections in ULSI circuits. Although a resistivity of less than about 10-3 Ω-cm — eight orders of magnitude less than for static RAM load resistors — is routinely achieved, the lower bound on the resistivity of polysilicon can limit the performance of silicon-gate integrated circuits that use polysilicon interconnections to conduct signals long distances across a chip [5.1]. As feature sizes become smaller and intrinsic transistor delays decrease on chips of increasing overall dimensions, the resistance of polysilicon interconnections is becoming a more serious limitation on integrated-circuit performance.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
Reference
K Saraswat and F Mohammadi, “Effect of scaling of interconnections on the time delay of VLSI circuits,” IEEE Trans. Electron Devices, ED-29, 645–650 (April 1982).
J D Joseph and T I Kamins, “Resistivity of chemically deposited polycrystalline-silicon films,” Solid-State Electron. 15, 355–358 (March 1972).
N F Mott, “Conduction in glasses containing transition metal ions” J. Non-Cryst. Solids, 1, 1–17 (December 1968).
C A Dimitriadis and P A Coxon, “Hopping conduction in undoped low-pressure chemically vapor deposited polycrystalline silicon films in relation to the film deposition conditions,” J. Appl. Phys. 64, 1601–1604 (1 August 1988).
J D Cressler, W Hwang, and T-C Chen, “On the temperature dependence of majority carrier transport in heavily arsenic-doped polycrystalline silicon thin films,” J. Electrochem. Soc. 136, 794–804 (March 1989).
A L Fripp, “Dependence of resistivity on the doping level of polycrystalline silicon,” J. Appl. Phys. 46, 1240–1244 (March 1975).
T I Kamins, “Hall mobility in chemically deposited polycrystalline silicon,” J. Appl. Phys. 42, 4357–4365 (October 1971).
J Y W Seto, “The electrical properties of polycrystalline silicon films,” J. Appl. Phys. 46, 5247–5254 (December 1975).
M Cao, T King, and K Saraswat, “Determination of the densities of gap states in hydrogenated polycrystalline Si and Si0.8Ge0.2 films,” Appl. Phys. Lett. 61, 672–674 (10 August 1992).
G Baccarani, B Riccó, and G Spadini, “Transport properties of polycrystalline silicon films,” J. Appl. Phys. 49, 5565–5570 (November 1978).
J P Colinge, E Demoulin, F Delannay, M Lobet and J M Temerson, “Grain size and resistivity of LPCVD polycrystalline silicon films,” J. Electrochem. Soc. 128, 2009–2014 (September 1981).
G Baccarani, M Impronta, B Riccó, and P Ferla, “I-V characteristics of polycrystalline silicon resistors,” Revue de Physique Appliqueé, 13, 777–782 (December 1978).
G J Korsh and R S Muller, “Conduction properties of lightly doped, polycrystalline silicon,” Solid-State Electron. 21, 1045–1051 (August 1978).
A K Ghosh, C Fishman, and T Feng, “Theory of the electrical and photovoltaic properties of polycrystalline silicon,” J. Appl. Phys. 51, 446–454 (January 1980).
M M Mandurah, K C Saraswat and T I Kamins, “Phosphorus doping of low pressure chemically vapor-deposited silicon films,” J. Electrochem. Soc. 126, 1019–1023 (June 1979).
A K Ghosh, A Rose, H P Maruska, D J Eustace, and T Feng, “Hall measurements and grain-size effects in polycrystalline silicon,” Appl. Phys. Lett. 37, 544–546 (15 September 1980).
A K Ghosh, A Rose, H P Maruska, T Feng, and D J Eustace, “Interpretation of Hall and resistivity measurements in polycrystalline silicon” J. Electronic Mat. 11, 237–260 (March 1982).
R H Bube, “Interpretation of Hall and photo-Hall effects in inhomogeneous materials,” Appl. Phys. Lett. 13, 136–139 (15 August 1968).
M S Bennett, “Relationship between Hall constant and carrier densities in polycrystalline semiconductor film,” J. Appl. Phys. 58, 3470–3475 (1 November 1985).
J W Orton, “Interpretation of Hall mobility in polycrystalline thin films,” Thin Solid Films, 86, 351–357 (December 18, 1981).
G E Pike and C H Seager, “The dc voltage dependence of semiconductor grain-boundary resistance,” J. Appl. Phys. 50, 3414–3422 (May 1979).
J M Andrews, “Electrical conduction in implanted polycrystalline silicon,” J. Electronic Materials, 8, 227–247 (May 1979).
C H Seager and G E Pike, “Grain boundary states and varistor behavior in silicon bicrystals,” Appl. Phys. Lett. 35, 709–711 (1 November 1979).
C H Seager, “Grain boundary recombination: Theory and experiment in silicon,” J. Appl. Phys. 52, 3960–3968 (June 1981).
W B Jackson, N M Johnson, and D K Biegelsen, “Density of gap states of silicon grain boundaries determined by optical absorption,” Appl. Phys. Lett. 43, 195–197 (15 July 1983).
W K Schubert and P M Lenahan, “Spin dependent trapping in a polycrystalline silicon integrated circuit resistor,” Appl. Phys. Lett. 43, 497–499 (1 September 1983).
W E Spear and P G LeComber, “Electronic properties of substitutionally doped amorphous Si and Ge,” Phil. Mag. 33, 935–949 (1976).
G Queirolo, E Servida, L Baldi, G Pignatel, A Armigliato, S Frabboni, and F Corticelli, “Dopant activation, carrier mobility, and TEM studies in polycrystalline silicon films,” J. Electrochem. Soc. 137, 967–971 (March 1990).
V Srikant, D R Clarke, and P V Evans, “Simulation of electron transport across charged grain boundaries,” Appl. Phys. Lett. 69, 1755–1757 (16 September 1996) and Comment H F Mataré, Appl. Phys. Lett. 70, 2055 (14 April 1997).
C-Y Lu, N C-C Lu, and C-S Wang, “Effects of grain-boundary trapping-state energy distribution on the activation energy of resistivity of polycrystalline-silicon films,” Solid-State Electron. 27, 463–466 (May 1984).
N C C Lu, L Gerzberg, C Y Lu, and J D Meindl, “Thermionic field emission in polycrystalline-silicon films,” Fall 1980 Electrochemical Society Meeting (Hollywood FL, October 1980), abstract 483, pp. 1103–1105.
N C-C Lu, L Gerzberg, C-Y Lu, and J D Meindl, “A conduction model for semiconductor-grain-boundary-semiconductor barriers in polycrystalline-silicon films,” IEEE Trans. Electron Devices, ED-30, 137–149 (February 1983).
M M Mandurah, K C Saraswat, and T I Kamins, “A model for conduction in polycrystalline silicon-Part I: Theory,” IEEE Trans. Electron Devices, ED-28, 1163–1171 (October 1981).
E L Murphy and R H Good, Jr., “Thermionic emission, field emission and the transition region,” Phys. Rev. 102, 1464–1473 (June 15, 1956).
M M Mandurah, K C Saraswat, and T I Kamins, “A model for conduction in polycrystalline silicon-Part II: Comparison of theory and experiment,” IEEE Trans. Electron Devices, ED-28, 1171–1176 (October 1981).
D P Joshi and R S Srivastava, “A model of electrical conduction in polycrystalline silicon,” IEEE Trans. Electron Devices, ED-31, 920–927 (July 1984).
J Martinez, A Criado, and J Piqueras, “Grain boundary potential determination in polycrystalline silicon by the scanning light spot technique,” J. Appl. Phys. 52, 1301–1305 (March 1981).
E Loh, “Interpretation of dc characteristics of phosphorus-doped polycrystalline silicon films: Conduction across low-barrier grain boundaries,” J. Appl. Phys. 54, 4463–4466 (August 1983).
N C-C Lu, and C-Y Lu, “I-V characteristics of polysilicon resistors at high electric field and the non-uniform conduction mechanism,” Solid-State Electron. 27, 797–805 (August/September 1984).
M Taniguchi, M Hirose, Y Osaka, S Hasegawa, and T Shimizu, “Current transport in doped polycrystalline silicon,” Japan. J. Appl. Phys. 19, 665–673 (April 1980).
M J McCarthy, M D Karim, and J A Reimer, “The properties of phosphorus in polycrystalline silicon—A nuclear magnetic resonance study,” Spring 1986 Mat. Res. Soc. Meeting (Palo Alto CA, April 17, 1986), paper F5.19.
D Ballutaud, M Aucouturier, and F Bobonneau, “Electron spin resonance study of hydrogenation effects in polycrystalline silicon,” Appl. Phys. Lett. 49, 1620–1622 (8 December 1986).
N H Nickel, N M Johnson, and W B Jackson, “Hydrogen passivation of grain boundary defects in polycrystalline silicon,” Appl. Phys. Lett. 62, 3285–3287 (21 June 1993).
T Makino and H Nakamura, “The influence of plasma annealing on electrical properties of polycrystalline Si,” Appl. Phys. Lett. 35, 551–552 (1 October 1979).
D L Chen, D W Greve, and A M Guzman, “Influence of hydrogen implantation on the resistivity of polycrystalline silicon,” J. Appl. Phys. 57, 1408–1410 (15 February 1985).
E S Cielaszyk, K H R Kirmse, R A Stewart, and A E Wendt, “Mechanisms for polycrystalline silicon defect passivation by hydrogenation in an electron cyclotron resonance plasma,” Appl. Phys. Lett. 67, 3099–3101 (20 November 1995).
I-W Wu, A G Lewis, T-Y Huang, and A Chiang, “Effects of trap-state density reduction by plasma hydrogenation in low-temperature polysilicon TFT,” IEEE Electron Device Lett. 10, 123–125 (March 1989).
S Ostapenko, L Jastrzebski, J. Lagowski, and R K Smeltzer, “Enhanced hydrogenation in polycrystalline silicon thin films using low-temperature ultrasound treatment,” Appl. Phys. Lett. 68, 2873–2875 (13 May 1996).
J I Pankove, R O Wance, and J E Berkeyheiser, “Neutralization of acceptors in silicon by atomic hydrogen,” Appl. Phys. Lett. 45, 1100–1102 (15 November 1984).
B W Liou, Y H Wu, C L Lee, and T F Lei, “Thickness effect on hydrogen plasma treatment on polycrystalline silicon thin films,” Appl. Phys. Lett. 66, 3013–3014 (29 May 1995).
G P Pollack, W F Richardson, S D S Malhi, T Bonifield, H Shichijo, S Banerjee, M Elahy, A H Shah, R Womack, and P K Chatterjee, “Hydrogen passivation of polysilicon MOSFETs from a plasma nitride source,” IEEE Electron Device Lett. EDL-5, 468–470 (November 1984).
E Puppin, “Hydrogen implanted polycrystalline silicon: Resistivity and grain boundary chemistry,” J. Vac. Sci. Technol. B 5, 606–607 (March/April 1987).
V Suntharalingam and S J Fonash, “Electrically reversible depassivation/passivation mechanism in polycrystalline silicon,” Appl. Phys. Lett. 68, 1400–1402 (4 March 1996).
N M Johnson, D K Biegelsen, and M D Moyer “Deuterium passivation of grain-boundary dangling bonds in silicon thin films,” Appl. Phys. Lett. 40, 882–884 (15 May 1982).
R T Young, M C Lu, R D Westbrook, and G E Jellison, Jr, “Effect of lithium on the electrical properties of grain boundaries in silicon,” Appl. Phys. Lett. 38, 628–630 (15 April 1981).
G L Miller and W A Orr, “Lithium doping of polycrystalline silicon,” Appl. Phys. Lett. 37, 1100–1101 (15 December 1980).
T I Kamins, “MOS transistors in beam-recrystallized polysilicon,” Tech. Digest, 1982 International Electron Devices Meeting (San Francisco, December, 1982), paper 16.1, pp. 420–423.
S D Brotherton, D J McCulloch, J B Clegg, and J P Gowers, “Excimerlaser-annealed poly-Si thin-film transistors,” IEEE Trans. Electron Devices 40, 407–413 (February 1993).
Y Morimoto, Y Jinno, K Hirai, H Ogata, T Yamada, and K Yoneda, “Influence of the grain boundaries and intragrain defects on the performance of poly-Si thin film transistors,” J. Electrochem. Soc. 144, 2495–2501 (July 1997).
G K Giust and T W Sigmon, “Performance improvement obtained for thin-film transistors fabricated in prepatterned laser-recrystallized polysilicon,” IEEE Electron Device Lett. 18, 296–298 (June 1997).
G Yaron, L D Hess, and G L Olsen, “Electrical characteristics of laser-annealed polysilicon resistors for device applications,” Proc. Materials Research Society Symposium (Boston, 1979) (ed. C W White and P S Peercy, Academic Press, 1980), pp. 626–631.
Y Wada and S Nishimatsu, “Resistivity lowering limitations of heavily doped polycrystalline silicon,” Denki Kagaku, 47, 118–123 (1979).
S Solmi, M Severi, R Angelucci, L Baldi, and R Bilenchi, “Electrical properties of thermally and laser annealed polycrystalline silicon films heavily doped with arsenic and phosphorus,” J. Electrochem. Soc. 129, 1811–1818 (August 1982).
N Lifschitz, “Solubility of implanted dopants in polysilicon: Phosphorus and arsenic,” J. Electrochem. Soc. 130, 2464–2467 (December 1983).
R B Fair, “Recent advances in implantation and diffusion modeling for the design and process control of bipolar ICs,” in Semiconductor Silicon 1977 (ed. H R Huff and E Sirtl, The Electrochemical Soc, Princeton NJ, 1977), Proc. Vol. 77-2, pp. 968–987.
R B Fair and J C C Tsai, “A quantitative model for the diffusion of phosphorus in silicon and the emitter dip effect,” J. Electrochem. Soc. 124, 1107–1118 (July 1977).
J Murota and T Sawai, “Electrical characteristics of heavily arsenic and phosphorus doped polycrystalline silicon,” J. Appl. Phys. 53, 3702–3708 (May 1982).
T Makino and H Nakamura, “Resistivity changes of heavily-boron-doped CVD-prepared polycrystalline silicon caused by thermal annealing,” Solid-State Electron. 24, 49–55 (January 1981).
G Masetti, D Nobili, and S Solmi, “Profiles of phosphorus predeposited in silicon and carrier concentration in equilibrium with SiP precipitates,” in Semiconductor Silicon 1977 (ed. H R Huff and E Sirtl, The Electrochemical Soc, Princeton NJ, 1977), Proc. Vol. 77-2, pp. 648–657.
A Lietoila, J F Gibbons, and T W Sigmon, “The solid solubility and thermal behavior of metastable concentrations of As in Si,” Appl. Phys. Lett. 36, 765–768 (1 May 1980).
K Suzuki, N Miyata, and K Kawamura, “Resistivity of heavily doped polycrystalline silicon subjected to furnace annealing,” Japan. J. Appl. Phys. 34, 1748–1752 (April 1995).
T I Kamins, “Resistivity of LPCVD polycrystalline-silicon films,” J. Electrochem. Soc. 126, 833–837 (May 1979).
G Kawachi, T Aoyama, K Miyata, Y Ohno, A Mimura, N Konishi, and Y Mochizuki, “Large-area ion doping technique with bucket-type ion source for polycrystalline silicon films,” J. Electrochem. Soc. 137, 3522–3526 (November 1990).
Y Mishima and M Takei, “Non-mass-separated ion shower doping of polycrystalline silicon,” J. Appl. Phys. 75, 4933–4938 (15 May 1994).
R Bashir, S Venkatesan, H Yen, G W Neudeck and E P Kvam, “Doping of polycrystalline silicon films using an arsenic spin-on-glass source and surface smoothness,” J. Vac. Sci. Technol. B, 11, 1903–1905 (September/October 1993).
B S Meyerson, F K LeGoues, T N Nguyen, and D L Harame, “Nonequilibrium boron doping effects in low-temperature epitaxial silicon films,” Appl. Phys. Lett. 50, 113–115 (12 January 1987).
R Chow and R A Powell, “Activation and redistribution of implants in polysi by RTP,” Semiconductor International (May 1985), pp. 108–113.
W Shockley, Electrons and Holes in Semiconductors (John Wiley and Sons, New York 1959), pp. 318–325.
P Panayotatos, E S Yang, and W Hwang, “Determination of the grain boundary recombination velocity in polycrystalline silicon as a function of illumination from photoconductance measurements,” Solid-State Electron. 25, 417–422 (May 1982).
H C Card and E Yang, “Electronic processes at grain boundaries in polycrystalline semiconductors under optical illumination,” IEEE Trans. Electron Devices, ED-24, 397–402 (April 1977).
M A Green, “Bounds upon grain boundary effects in minority carrier semiconductor devices: A rigorous “perturbation” approach with application to silicon solar cells,” J. Appl. Phys. 80, 1515–1521 (1 August 1996).
J E Mahan, “Threshold and memory switching in polycrystalline silicon,” Appl. Phys. Lett. 41, 479–481 (1 September 1982).
P T Landsberg and M S Abrahams, “Effects of surface states and of excitation on barrier heights in a simple model of a grain boundary or a surface,” J. Appl. Phys. 55, 4284–4293 (15 June 1984).
P Kenyon and H Dressel, “Negative resistance switching in near-perfect crystalline silicon film resistors,” J. Vac. Sci. Technol. A 2, 1486–1490 (October-December 1984).
C-Y Lu, N C-C Lu, and C-C Shih, “Resistance switching characteristics in polycrystalline silicon film resistors,” J. Electrochem. Soc. 132, 1193–1196 (May 1985).
C H Seager and G E Pike, “Anomalous low-frequency grain-boundary capacitance in silicon,” Appl. Phys. Lett. 37, 747–749 (15 October 1980).
M Darwish and K Board, “Theory of switching in polysilicon n-p + structures,” Solid-State Electron. 27, 775–783 (August/September 1984).
Y Amemiya, T Ono, and K Kato, “Electrical trimming of heavily doped polycrystalline silicon resistors,” IEEE Trans. Electron Devices, ED-26, 1738–1742 (November 1979).
M Tanimoto, J Murota, Y Ohmori, and N Ieda, “A Novel MOS PROM using a highly resistive poly-Si resistor,” IEEE Trans. Electron Devices, ED-27, 517–520, (March 1980).
O-H Kim and C-K Kim, “Effects of high-current pulses on polycrystalline silicon diode with n-type region heavily doped with both boron and phosphorus,” J. Appl. Phys. 53, 5359–5360 (July 1982).
Author information
Authors and Affiliations
Rights and permissions
Copyright information
© 1998 Springer Science+Business Media New York
About this chapter
Cite this chapter
Kamins, T. (1998). Electrical Properties. In: Polycrystalline Silicon for Integrated Circuits and Displays. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-5577-3_5
Download citation
DOI: https://doi.org/10.1007/978-1-4615-5577-3_5
Publisher Name: Springer, Boston, MA
Print ISBN: 978-1-4613-7551-7
Online ISBN: 978-1-4615-5577-3
eBook Packages: Springer Book Archive