Skip to main content

Naturally Occurring Polymers

  • Chapter
Principles of Polymer Chemistry

Abstract

There are many naturally occurring polymeric materials. Many are quite complex. It is possible, however, to apply an arbitrary classification and to divide them into six main categories. These are:

  1. 1

    Polysaccharides. This category includes starch, cellulose, chitin, pectin, alginic acid, natural gums, and others.

  2. 2

    Proteins or naturally occurring polyamides found in animal and vegetable sources.

  3. 3

    Polyisoprenes or natural rubbers and similar materials that are isolated from saps of plants.

  4. 4

    Polynucleotides include all the DNA-s and all the RNA-s found in all living organisms.

  5. 5

    Lignin or polymeric materials of coniferyl alcohol and related substances.

  6. 6

    Naturally occurring miscellaneous polymers, like, for instance, shellac, a resin secreted by the lac insect. This is a complex crosslinked polyester of 9,10,16-trihydroxy-exadecanoic acid (aleuritic acid). The structure also includes some unsaturated long chain unsaturated aliphatic acids together with other compounds’.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 74.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. E. Hicks, Shellac, It’s Origins and Applications, Chemical Publishing Co., New York, 1961; S. Maiti and M.D.S. Rahman, J.,MacromoL Sci.,Rev. Macromol. Chem. Phys., C26, 441 (1986);

    Google Scholar 

  2. E. Fischer, Ber., 24, 1836,2683 (1881); 29,1377 (1896);

    Google Scholar 

  3. W.N. Haworth, E.L. Hirst, and HA. Hampton, J. Chem. Soc., 1929,1739

    Google Scholar 

  4. T. Svedberg, J. Phys. Colloid. Chem., 51, 1 (1947)

    Article  CAS  Google Scholar 

  5. K.H. Meyer and H. Mark, Der Aufbau der Hochpolymeren Organischen Naturstoffe. Akademie Verlagagesellschaft, Leipzig, 1930

    Google Scholar 

  6. S. Morell and K.P. Link, J. BioL Chem., 100,385 (1933)

    CAS  Google Scholar 

  7. S. Morell, L. Bauer and K.P. Link, J. Biol. Chem.,105,1(1934)

    CAS  Google Scholar 

  8. P.A. Levene and L.C. Kreider, J. BioL Chem.,129, 591 (1937)

    Google Scholar 

  9. P.A. Levene, G.M. Meyer, and M. Kuna, Science, 89, 370 (1939)

    Article  CAS  Google Scholar 

  10. R.L. Whistler and J.N. BeMiller, eds. Industrial Gums, 2nd ed., Academic Press, New York, 1973

    Google Scholar 

  11. R.L. Whistler and E.F. Paschall, eds. Starch, Chemistry and Technology,vols. I and II, Academic Press, N.Y. 1965

    Google Scholar 

  12. N.M. Bikales and L. Segal, eds. Cellulose and Cellulose Derivatives, Wiley-Interscience, N.Y. 1971; A. Hebeish and J.T. Guthrie, The Chemistry and Technology of Cellulose Derivatives, Springer-Verlag, New York, 1981

    Google Scholar 

  13. E.M. Fetters, ed. Chemical Reactions ofPolymers, Wiley-Interscience, N.Y., 1964

    Google Scholar 

  14. Z.A. Rogovin, VysokomoL soyed., A13 (2), 437 (1971)

    Google Scholar 

  15. J. F. Klebe and H.L. Finkbeiner,J. Polymer Sci., A-17, 1947 (1969)

    Google Scholar 

  16. L.G. Nikologovskaya, L.S. Galbraikh, Y.S. Kozlova, and Z.A. Rogovin, VysokomoL soyed., A12, 2762 (1970)

    Google Scholar 

  17. S. Maiti, S. Das, M. Maiti, and A. Ray, Polymer Applications ofRenewableResourceMaterials, C.E. Carraher Jr. and L.H. Sperling, (eds.), Plenum press, New York, 1983

    Google Scholar 

  18. E.A. MacGregor and C.T. Greenwood, Polymers in Nature, Wiley, New York, 1980

    Google Scholar 

  19. I.A. Pearl, The Chemistry ofLignin, Dekker, New York, 1967

    Google Scholar 

  20. K. Freudenberg, Science, 148, 595 (1965)

    Article  CAS  Google Scholar 

  21. F.R Eirich, ed., Science and Technology of Rubber, Academic Press, New York, 1978; A.D. Roberts, ed., Natural Rubber Science and Technology, Oxford University Press, New York, 1988

    Google Scholar 

  22. M. Joly, A Physico-Chemical Approach to the Denaturation of Proteins, Academic Press, Ney York, 1965

    Google Scholar 

  23. L. Pauling and R.B. Corey, Proc. Natl. Acad. Sci., 37, 729 (1951); ibid., 39, 253 (1953)

    Google Scholar 

  24. L. Pauling, R.B. Corey, and H.R. Branson, Proc. Natl. Acad. Sci., 37, 205 (1951)

    Article  CAS  Google Scholar 

  25. A.M. Liguori, Acta Cryst., 8, 375 (1955)

    Google Scholar 

  26. S. Seifter and P.M. Gallop, in The Proteins, vol. 4, 2nd ed., H. Neurath, ed., Academic Press, New York, 1966; A.G. Walton, Polypeptides and Protein Structure, Elsevier, New York, 1981

    Google Scholar 

  27. D.R. Davis, J. Mol. BioL, 9, 605 (1964)

    Article  Google Scholar 

  28. E.R. Blout in Polyamino Acids, Polypeptides, and Proteins, M.A. Stahmann, (ed.), Univ. Wisconsin Press, Madison, 1962

    Google Scholar 

  29. M.F. Perutz, J.C. Kendrew and H.C. Watson, J. Mol. Biol., 13, 669 (1965)

    Article  CAS  Google Scholar 

  30. R.T. Hatch, Nature,206, 777 (1965)

    Article  CAS  Google Scholar 

  31. R.E. Dickerson and I. Geis, The Structure and Action of Proteins,Harper and Row, New York, 1969

    Google Scholar 

  32. C.H. Bamford and A. Elliott in Fiber Structure, J.W.S. Hearle and R.N. Peters, (eds.), Butterworth and Co. Ltd., London, 1963

    Google Scholar 

  33. B. Jergenson, Optical Rotary Dispersion of Proteins and Other Macromolecules, Springer Verlag, New York, 1969

    Google Scholar 

  34. F.H. Crick, Acta Cryst., 6, 689 (1953)

    CAS  Google Scholar 

  35. R.D.B. Fraser and T.P MacRae, Nature, 195, 1167 (1962)

    Article  CAS  Google Scholar 

  36. C. Cohen and K.C. Hohnes, J. MoL Biol., 6, 423 (1963)

    Article  CAS  Google Scholar 

  37. W.B. Ward and H. P. Lundgren, Adv. in Protein Chem., 9, 243 (1954)

    Article  CAS  Google Scholar 

  38. R.H. Peters, Textile Chemistry,Vol. I, Elsevier Publishing Co., New York, 1963

    Google Scholar 

  39. F. Lucas, J.T.B. Shaw, and S.G. Smith, Biochem. J., 66, 468 (1957)

    CAS  Google Scholar 

  40. R.B.D. Fraser, T.P. MacRae, and G.E. Rogers, Nature,193, 1052 (1962)

    Article  CAS  Google Scholar 

  41. A. Rich and F.H. Crick, J. MoL Biol.,3, 483 (1961)

    Article  CAS  Google Scholar 

  42. R.B.D. Fraser, T.P. MacRae, D.A.D. Parry, and E. Suzuki, Polymer,10 (10), 810 (1969)

    Article  CAS  Google Scholar 

  43. J.C. Kendrew, Science,139, 1259 (1963)

    Article  CAS  Google Scholar 

  44. M.F. Peruz, Science,140, 863 (1964)

    Article  Google Scholar 

  45. G. Buse, Angew. Chem., Intern. Ed., 10 (10), 663 (1971)

    Article  CAS  Google Scholar 

  46. M.F. Penrz, G. Will and A.T.C. North, Nature, 185, 416 (1960)

    Article  Google Scholar 

  47. P. Jolies, Angew. Chem., Intern. Ed., 8 (4), 227 (1969)

    Article  Google Scholar 

  48. E. Katalski and M. Sela, Advan. Protein Chem., 13, 243 (1958)

    Article  Google Scholar 

  49. M. Idelson and E.R. Blout, J. Am. Chem. Soc., 80, 2387 (1958)

    Article  CAS  Google Scholar 

  50. Y. Shalitin and E. Katchalski, J. Am. Chem. Soc.,82, 1630 (1960)

    Article  CAS  Google Scholar 

  51. K. Hofmann, Chem. Eng. News, p.145 (Aug. 7, 1967)

    Google Scholar 

  52. R. Schwyzer amd P. Sieber, Hely. Chim. Acta, 49,134 (1966)

    Article  Google Scholar 

  53. R.B. Merrifield, J. Am. Chem. Soc., 85, 2149 (1963)

    Article  CAS  Google Scholar 

  54. . Chem. Eng. News,p.28 (April 22, 1968)

    Google Scholar 

  55. B. Gurte and RB. Merrifield, J. Am. Chem. Soc., 91, 501 (1961)

    Google Scholar 

  56. J.N. Davidson, The Biochemistry ofNucleic Acids, 7th ed., Academic Press, New York, 1972

    Google Scholar 

  57. N.K. Kochetkov and E.I. Budovskii, (eds.),Organic Chemistry ofNucleic Acids, Plenum Press, London, Part A - 1971, Part. B -1972; L.B. Townsend and R.S. Tipson, (eds.), Nucleic Acid Chemistry,WileyInterscience, New York, 1986

    Google Scholar 

  58. J.D. Watson and F.H. Crick, Nature, 171, 734, 964 (1953

    Article  CAS  Google Scholar 

  59. G. Felsenfeld and H.T. Miles, Ann. Rev. Biochem., 36, 407 (1967)

    Article  CAS  Google Scholar 

  60. J.L. Fox, Chem. End. News, p. 14 (Dec. 14, 1979)

    Google Scholar 

  61. G. Kolata, Science, 214, 1108 (1981)

    Article  CAS  Google Scholar 

  62. L.B. Townsend and R.S. nRipson, (ed.), Nucleic Acid Chemistry,Wiley-Interscience, New York, 1986

    Google Scholar 

  63. F.L. Suddath, G.J. Quigley, A. McPherson, J.L. Sussman, A.H.J. Wang, N.C. Seeman and A. Rich, Science,185, 435 (1974)

    Article  Google Scholar 

  64. S.E. Chang and D. Ish-Horowicz, J. Mol. BioL, 84, 375 (1974)

    Article  CAS  Google Scholar 

  65. K.L. Agarwal, A. Yamazaki, P.J. Cashion, and H.G. Khorana, Angew. Chem.,Intern. Ed, 11(6), 451 (1972)

    Article  CAS  Google Scholar 

  66. J.M. Frechet and Schurch, J. Am. Chem. Soc., 93, 492 (1971)

    Article  Google Scholar 

  67. M. Lemoigne, C.R. Acad Sci., 180, 1539 (1925); Bull. Soc. Chim. Biol., 8, 1291 (1926)

    Google Scholar 

  68. J. Cornibert, R.H. Marchessault, H. Benoit, and G. Weil, Macromolecules, 3, 741 (1970)

    Article  Google Scholar 

  69. R.H. Marchessault, Am.Chem. Soc. Polymer Preprints, 29 (1), 584 (1988)

    CAS  Google Scholar 

  70. K. Rose, J. Am. Chem. Soc.,116, 30 (1994)

    Article  CAS  Google Scholar 

  71. K.G. Gagnon, R.W. Lenz, R.J. Farris, and RC. Fuller, Rubber Chem. Tech., 65, 761 (1992)

    Article  CAS  Google Scholar 

  72. K. Griebenow and A.M. Klibanov, J. Am. Chem. Soc.,118, 11695 (1996)

    Article  CAS  Google Scholar 

  73. F. Shi, R.A. Gross and D.R. Rutheford, Macromolecules, 29, 10, (1996)

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Rights and permissions

Reprints and permissions

Copyright information

© 2000 Springer Science+Business Media New York

About this chapter

Cite this chapter

Ravve, A. (2000). Naturally Occurring Polymers. In: Principles of Polymer Chemistry. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-4227-8_7

Download citation

  • DOI: https://doi.org/10.1007/978-1-4615-4227-8_7

  • Publisher Name: Springer, Boston, MA

  • Print ISBN: 978-1-4613-6898-4

  • Online ISBN: 978-1-4615-4227-8

  • eBook Packages: Springer Book Archive

Publish with us

Policies and ethics