Abstract
Solution properties of polycarboxybetaines were thoroughly considered by Salamone and co.1–12 especially in the vinylimidazole and vinylpyridine series as well as by other research groups.13–20 One of the features of zwitterion-type polyampholytes is tendency of polymer chains to association. Therefore polymeric betaines are usually insoluble in pure water and have gel characteristics but soluble in salt containing solutions. The loss of water solubility and gel like structure that adopts polybetaines are due to the formation of intragroup, intra- and interchain ion contacts which result in the appearance of a crosslinked networks (Scheme 4.1).
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REFERENCES
J. C. Salamone, C. C. Tsai, A. P. Olson, and A. C. Watterson, Solution properties of polyampholytes from cationic-anionic monomer pairs, Amer.Chem.Soc.Polym.Prepr. 19(2), 261-264 (1978).
J. C. Salamone, C. C. Tsai, A. C. Watterson, and A. P. Olson, Properties of aqueous solutions of poly(vinylimidazolesulfobetaine), Polymer, 19, 1157-1162 (1978).
J. C. Salamone, C. C. Tsai, A. P. Olson, and A. C. Watterson, in: Ionic Polymers, edited by A. Eisenberg, (ACS Series, Washington DC, 1980).
J. C. Salamone, E. L. Rodriguez, K. C. Lin, L. Quach, A. C. Watterson, and I. Ahmed, Aqueous salt absorption by ampholytic polysaccharides, Polymer, 26, 1234-1238 (1985).
J. C. Salamone, A. C. Watterson, T. D. Hsu, C. C. Tsai, and M. U. Mahmud, Polymerization of vinylpyridinium salts. IX. Preparation of monomelic salt pairs, J.Polym.Sci.Polym.Lett.Ed. 15, 487-491 (1977).
J. C. Salamone, A. C. Watterson, T. D. Hsu, C. C. Tsai, M. U. Mahmud, A. W. Wisniewski, and S. C.Israel, Polymerization of vinylpyridinium salts. X. Copolymerization studies of cationic-anionic monomer pairs, J.Polym.Sci.Polym.Symp. 64, 229-243 (1978).
J. C. Salamone, C. C. Tsai, A. C. Watterson, and A. P. Olson, Novel ampholytic polymers. A new class of ionomer, in: Polymeric Amines and Ammonium Salts, edited by E.J.Goethals, (Pergamon Press, Oxford, 1980).
J. C. Salamone, C. C. Tsai, A. P. Olson, and A. C. Watterson, Ampholytic polystyrene ionomers from cationic-anionic monomer pairs, J.Polym.Sci.Polym.Chem.Ed. 18, 2983-2992 (1980).
J. C. Salamone, I. Ahmed, P. Elayaperumal, M. K. Raheja, A. C. Watterson, and A.P. Olson, Behavior of polyampholytes in aqueous-salt solution, Polym.Mater.Sci.Eng. 55, 269-273 (1986).
A. C. Watterson, J. C. Salamone, and P. Elayaperumal, Solution behavior of ampholytic butylmethacrylate ionomers in organic solvents, Polym.Prepr. 27(2), 275-276 (1986).
J. C. Salamone, I. Ahmed, E. L. Rodriguez, L. Quach, and A. C. Watterson, Synthesis and solution properties of ampholytic acrylamide ionomers, J. Macromol. Sei. Chem, 25, 811-837 (1988).
J. C. Salamone and W. C. Rice, in: Encyclopedia of Polymer Science and Engineering (Wiley-Interscience, New York, 1988).
D. J. Liaw, W. F. Lee, and Y. C. Whung, M. C. Lin, Aqueous solution properties of poly[3-dimethyl(methacryloyloxyethyl)ammonium propane sulfonate], J.Appl.Polym.Sci. 34, 999-1011 (1987).
D. J. Liaw, C. C. Huang, and Y. P. Chou, Dilute solution properties of poly(3-trimethylmethacrylamidopropyl ammonium methylsulfate), Eur.Polym.J. 33, 829-836 (1997).
D. J. Liaw and C. C. Huang, Dilute solution properties of poly(3-dimethylacryloyloxyethyl ammonium propiolactone), Polymer, 38, 6355-6362 (1997).
D. J. Liaw, C. C. Huang, W. F. Lee, J. Borbely, and E. T. Kang, Synthesis and characteristics of the poly(carboxybetaine)s and the corresponding cationic polymers, J.Polym.Sci. Part A: Polym.Chem. 35, 3527-3536 (1997).
D. J. Liaw, C. C. Huang, H. C. Sang, and E. T. Kang, Aqueous solution and photophysical properties of cationic poly(trimethyl methacrylamidophenyl ammonium methylsulfate) and zwitterionic poly(N,N-dimethylmethacrylamidophenyl ammonium propane sultone), Polymer, 40, (2000).
D. J. Liaw, C. C. Huang, H. C. Chang, and P. L. Wu, Macromolecular microstructure, reactivity ratio and viscometric studies of water-soluble cationic and/or zwitterionic copolymers, Polymer, 41, 6123-6131 (2000).
D. J. Liaw and C. C. Huang, Synthesis and characteristics of the poly(sulfobetaine)s and the corresponding cationic polymers derived from N,N-dialkylamino phenyl methacrylamide, Macromol.Chem.Phys. 201, 1101-1107 (2000).
D. N. Schultz, D. G. Peiffer, P. K. Agarwal, J. Larabee, J. Kaiadas, L. Soni, B. Handwerker, and R.T. Garner, Phase behavior and solution properties of sulphobetaine polymers, Polymer 27, 1734-1742 (1986).
C. Schmuck. Self-folding molecules: A well defined, stable loop formed by a carboxylate-guanidinium zwitterion in DMSO, J.Org.Chem. 65, 2432-2437 (2000).
A. Niu, D. J. Liaw, H. C. Sang, and C. Wu, Light-scattering study of zwitterionic polycarboxybetaine in aqueous solution, Macromolecules, 33, 3492-3494 (2000).
W. F. Lee and C. C. Tsai, Synthesis and solubility of the poly(sulfobetaine)s and the corresponding cationic polymers: 2. Aqueous solution properties of poly[N,N'-dimethyl(acrylamido propyl) ammonium propane sulfonate], Polymer, 25, 357-364 (1995).
W. Jaeger, U. Wendler, A. Lieske, and J. Bohrisch, Novel modified polymers with permanent cationic groups, Langmuir 15, 4026-4032 (1999).
E. E. Kathmann and C. L. McCormick, Water-soluble polymers 71. pH responsive behavior of terpolymers of sodium acrylate, acrylamide, and the zwitterionic monomer 4-(2-acrylamido-2-methylpropanedimethylammonio) butanoate, J.Polym. Sci. Chem. 35, 231-242 (1997).
E. E. Kathmann and C. L. McCormick, Water-soluble polymers 72. Synthesis and solution behavior of responsive copolymers of acrylamide and the zwitterionic monomer 6-(2-acrylamido-2-methylpropyl-dimethylammonio) hexanoate, J. Polym. Sci. Chem. 35, 243-253 (1997).
M. M. Ali, H. P. Perzanowski, and Sk. A Ali, Polymerization of functionalized diallyl quaternary ammonium salt to poly(ampholyte-electrolyte), Polymer 41, 5591- (2000).
R. S. Armentrout and C. L. McCormick, Water-soluble polymers. 76. Electrolyte responsive cyclopolymers with sulfobetaine units exhibiting polyelectrolyte or polyampholyte behavior in aqueous media, Macromolecules 33, 419-424 (2000).
J. J. Kaladas, R. Kastrup and D. N. Schultz, Poly(cyclosulfobetaines): Synthesis, characterization, and solution properties, Polym.Prepr. 39(1), 619-620 (1998).
T. Nakaya, H. Toyoda, and M. Imoto, Polymeric phospholipid analogs. XIII. Synthesis and properties of vinyl polymers containing phosphatidyl choline groups, Polym.J. 18, 881-885 (1986).
Y. Muroga, M. Amano, A. Katagiri, I. Noda, and T. Nakaya, pH and ionic strength dependencies of the intrinsic viscosity of betaine-type polyampholyte, Polym.J. 27, 65-70 (1995).
T. Kato, A. Takahashi, Excluded volume effects of sulphobetaine polymers, Ber.Bunsenges.Phys.Chem. 100(6), 784-787 (1996).
V. M. Monroy Sato and J. C. Galin, Poly(sulfopropylbetaines). 1. Synthesis and characterization, Polymer, 25, 121-128 (1984).
V. M. Monroy Sato and J. C. Galin, Poly(sulfopropylbetaines). 2. Dilute solution properties, Polymer, 25,254-262 (1984).
M. Galin, E. Marchal, A. Mathis, B. Meurer, V. M. Monroy Sato, and J. C. Galin, Poly(sulfopropylbetaines). 3. Bulk properties, Polymer, 28, 1937-1944 (1987).
Y. L. Zheng, R. Knoesel, and J. C. Galin, Poly(sulphopropylbetaines). 4. Binding properties towards reporter anionic probes and local polarity close to the zwitterionic chain in aqueous solution, Polymer, 28,2297-2303 (1987).
J. C. Galin and M. Galin, Water sorption in poly(ammonium sulfopropylbetaines). I. Differential scanning calorimetry, J.Polym.Sci.Polym.Phys. 30, 1103-1112 (1992).
J. C. Galin and M. Galin, Water sorption in poly(ammonium sulfopropylbetaines). II. Sorption isotherms,J.Polym.Sci.Polym.Phys. 30, 1113-1121 (1992).
M. Galin and J. C. Galin, Hydration of poly(pyridiniumsulfonatopropyl betaines), Makromol.Chem. 194,3479-3491 (1993).
M. Galin, A. Chapoton, and J.C. Galin, Dielectric increments, intercharge distances and conformation of quaternary ammonioalkylsulfonates and alkoxydicyanoethenolates in aqueous and trifluoroethanol solutions, J.Chem.Soc.Perkin Trans. 2, 545-553 (1993).
J. C. Galin and M. Galin, Water sorption in poly(zwitterions) of the ammonioalkoxydicyanoethenolate typt,J Polym. Sci., Part B: Polym. Phys., 33, 2033-2043 (1995).
M. B. Huglin and M. A. Radwan, Unperturbed dimensions of a zwitterionic polymethacrylate, Polymer Intern. 26,97-104 (1991).
L. Chen, Y. Honma, T. Mizutani, D-J. Liaw, J.P. Gong, and Y. Osada, Effect of polyelectrolyte complexation on the UCST of zwitterionic polymer, Polymer 41, 141-147 (2000).
A. Bielge, A. Mathis, B. Meurer, and J.C. Galin, Matrix polarity effects on microphase separation in zwitterionomers, 2. Structural analysis of the model random zwitterionomers, Macromol.Chem.Phys. 201,2401-2407 (2000).
T. Onabe and H. Tanaka, Adsorption of sulfobetaine polyampholyte on silica surfaces from aqueous salt solutions, Langmuir, 15, 4302-4305 (1999).
J. F. Joanny, Adsorption of a polyampholyte chain, J.Phys.II France 4(8), 1281-1288 (1994).
S. A. Rozanski, F. Kremer, P. Koberle, and A. Laschewsky, Relaxation and charge transport in mixtures of zwitterionic polymers and inorganic salts, Makromol. Chem.Phys. 196, 877-890 (1995).
A. Laschewsky and I. Zerbe, Polymerizable and polymeric zwitterionic surfactants. 2. Surface activity and aggregation behaviour in aqueous systems, Polymer 32, 2081-2086 (1991).
P. Anton and A. Laschewsky, Polysoaps via alternating olefin/S02 copolymers, Makromol.Chem.Rapid Commun.12, 189-196 (1991).
P. Koberle, A. Laschewsky, and T. D. Lomax, Interaction of a zwitterionic polysoap and its cationic analog with inorganic salts, Makromol. Chem.Rapid Commun. 12, 427-430 (1991).
A. Laschewsky, Oligoethyleneoxide spacer groups in polymerizable surfactants Colloid.Polym.Sci. 269,785-794 (1991).
P. Anton, P. Koberle, and A. Laschewsky, Recent development in the field of micellar polymers,Makromol.Chem. 194, 1-27 (1993).
P. Anton and A. Laschewsky, Zwitterionic polysoaps with reduced density of surfactant side groups,Makromol.Chem. 194, 601-624 (1993).
P. Favresse and A. Laschewsky, New poly(carbobetaine)s made from zwitterionic diallylammonium monomers, Macromol.Chem.Phys. 200, 887-895 (1999).
P. Favresse, A. Laschewsky, C. Emmerman, L. Gros, and A. Linsner, Synthesis and free radical copolymerization of new zwitterionic monomers; amphiphilic carbobetaines based on isobutylene, Eur.Polym.J. 37, 877-885 (2001).
H. Sawada, M. Umedo, T. Kawaze, T. Tomita, and M. Baba, Synthesis and properties of fluoroalkylated end-capped betaine polymers, Eur.Polym.J. 35, 1611-1617 (1999).
J. Cardoso and O. Manero, Thermal and dilute-solution properties of zwitterionic copolymers, J. Polym.Sei. Part B: Polym. Phys. 29, 639-647 (1991).
N. Hadjichristidis, S. Pispas, and M. Pistikalis, End-functionalized polymers with zwitterionic end-groups, Prog.Polym.Sci. 24, 875-915 (1999).
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Kudaibergenov, S.E. (2002). Properties of Polyampholytes with Betaine Structure. In: Polyampholytes. Springer, Boston, MA. https://doi.org/10.1007/978-1-4615-0627-0_4
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DOI: https://doi.org/10.1007/978-1-4615-0627-0_4
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