Abstract
Binary and ternary molybdenum oxides have become a subject of many experimental and theoretical studies because most of them are low-dimensional metals and exhibit interesting physical properties associated with their electronic instabilities [1–4]. Red bronzes A0.33MoO3 (A = Li, K, Rb, Cs, T1) are semiconductors, while the blue bronzes A0.3MoO3 (A = K, Rb, T1), the purple bronzes AMo6O17 (A = K, Na, T1) and Li0.9Mo6O17, the Magnéli phases Mo4O11 and Mo8O23, and the rare-earth bronze La2Mo2O7 are all metals at room temperature. A series of tungsten oxides, i.e., the monophosphate tungsten bronzes (MPTB’s) [5], are also metallic and have been recently found to exhibit anomalous transport properties [6–9]. All these oxides contain metal-oxygen (M-O) layers made up of edge- and corner-sharing MO6 octahedra, with large and structurally complex unit cells [5, 10–12].
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Canadell, E., Whangbo, MH. (1996). Fermi Surface Nesting and Electronic Instabilities in Transition Metal Oxides and Bronzes. In: Schlenker, C., Dumas, J., Greenblatt, M., van Smaalen, S. (eds) Physics and Chemistry of Low-Dimensional Inorganic Conductors. NATO ASI Series, vol 354. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-1149-2_16
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DOI: https://doi.org/10.1007/978-1-4613-1149-2_16
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