Abstract
The objective of the Oslo and Paris Commission’s (OSPAR) work connected to offshore exploration and production (E&P) chemicals, is to reduce the use and discharge of the chemicals posing an unacceptable risk to the marine environment. Within OSPAR the required test procedure for offshore E&P chemicals have, to a large extent, been harmonized. The standard methods used are generally based on well established OECD Guidelines or proposed guidelines and require that that the tests are conducted according to OECD’s GLP (Good Laboratory Practice) principles. The basic data set includes the following ecotoxicological tests (OSPAR, 1995):
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Toxicity
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Algae: Skeletonema costatum
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Herbivore: Acartia tonsa
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Sediment reworker: Corophium volutator
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Fish: Scopthalmus maximus
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Biodegradation
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A 28-day seawater test
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Bioaccumulation
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n-octanol/water partition coefficient, Pow
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References
Aster/Aquire: Assessment tools for the evaluation of risk. US. EPA. Env. Research Lab., Duluth. MN 55804, Report No. EPA/DF/MT-93/050.
Bakke, S., Vik, E. A., Johnson, D. R., Wright, N. H., 1993: Ranking Criteria for offshore Production chemicals based on environmental hazard assessment. Paper presented at the Fourth International Symposium on Oil Field Chemicals, Geilo, April 18–21.
Bintein, S. J., Devillers, J., Karcher, W., 1993: Non-linear dependence of fish bioconcentration on n-oc- tanol-water partition coefficient. SAR QSAR, Environ. Res. 1, 29–39.
Connel, D. W., Hawker, D. W., 1988: Use of polynomial expressions to describe the bioconcentration of hydrophobic chemicals by fish. Ecotoxicol. Environ. Saf. 16, 242–257.
de Bruijn, J., Busser, F., Seinen, W., Hermens, J., 1989: Determination of octanol/water partition coefficient for hydrophobic organic chemicals with the “slow-stirring” method. Environmental Toxicology Chemical, 8, 499–512.
Ghose et al., 1989: Four additional parameters for hydrophobic and dispersive interactions and their applications for an automated superposition of certain naturally occuring nucleosid antibiotics. Comput. Sci., 27, 163–172.
Hansen, N., Graversen, P., Christensen, F. B., Linde, S. A., 1995: Massbalance of production chemicals — phase II. The Norwegian Oil Operators Association (OLF) Final Report.
Hammers, W. E., Mewis, G. J., de Ligny, C. L., 1982: Correlations between liquid chromatographic capacity ratio data on Lichrosorb RP-18 and partition coefficients in the octanol/water system. J. Chromatogr. 247, 1–13.
Isnard, P., Lambert, S., 1989: Aqueous solubility/n-octanol-water partitioning coefficient correlations. Chemosphere 18: 1837–1853.
Klein, W., Kordel, W., Weiz, M., Poremski, H. J., 1988: Updating of the OECD test guideline 107. “Partition Coefficient n-octanol/water”: OECD Laboratory Intercomparison Test of the HPLC Method. Chemosphere 17, 2, 361–386.
Leo, A. J., Weninger, 1988: Clog Pow. Computer program. Medchem Project. Pomona College, Claremont, CA.
Mackay, D., 1982: Correlation of bioconcentration factors. Environ. Sci. Technol. 16: 274–278.
Meylan, W., Howard, P., 1994: User’s guide for log Kow octanol-water partition coefficient program, January, Syrancuse Research Cooperation Chemicals Hazard Chemistry Center, Syracuse, N.Y. 13210, USA.
Moreau, G.; Broto, P., Vandycke, C., 1984: Molecular structures: perception, auto correlation descriptor and SAR studies. Eur. J. Chem. — Chim. Ter., 19, 71–78
OECD, 1981: Partition Coefficient (N-Octanol/Water) Flask Shaking Method. OECD Guidelines for Testing of Chemicals, OECD 107, May 12.
OECD, 1986: Report of the OECD Workshop on Practical Approaches to the Assessment of Environmental Exposure; Chemicals Division, OECD, Paris, Report No. 9002H/KW/JdK/ 1/8/86.
OECD, 1989: Partition Coefficient (N-Octanol/Water) High Performance Liquid Chromatography (HPLC) Method, OECD Guidelines for testing of Chemicals. OECD 117, March 30.
OECD, 1992: Report of the OECD workshop on effect assessment of chemicals in the sediment. OECD Environment Monographs No. 60. OCDE/6D (92) 170.
Orth, R. G., Powell, R. L., Kutey, G., Kimerle, R. A., 1995: Hazard and Risk Assessment. Impact of sediment partitioning methods on environmental safety assessment of surfactants. Environ.Toxicol, and Chem. 14, 2, 337–343.
OSPAR, 1995: Harmonized offshore chemical notification format. Oslo and Paris Commissions — Summary report of the meeting of the meeting of the programmes and measures committee (PRAM), Annex 10, Oviedo, 20–24 February.
Pedersen, F., Tyle, H., Niemela, J. R., Guttmann, B., Lander, L., Wedebrand, H., 1994: Environmental and hazard classification — Data collection and interpretation guide for substances to be evaluated for classification as dangerous to the environment. Tema Nord 1994, 589. The Nordic Council of Ministers.
Rapaport, R. A., Eisenreich, S. J., 1984: Chromatographic determination of octanol-water partition coefficients (Kow’s) for 58 polychlorinated biphenyl cogeners, Environ. Sci. Technol. 18, 163–170.
Sangster, J., 1989: Octanol-water partition coefficient of simple organic compounds. J. Phys. Chem. Ref. Data, 18,3, 1111–1229.
van Leeuwen, C. J., van der Zandt, P. T. J., Aldenterg, A., Verhoor, H. J. M., Heunen, J. L. M., 1992: Hazard assessment application of QSARs, entrapolation and equilibium partitioning in aquatic effects assessments. I. Narcotic Industrial Pollutants. Environ. Toxicol. Chem. 11: 267–282.
Veith, G. D., DeFoe, D. L., Bergstedt, B. V., 1979: Measuring and estimating the bioconcentration factor of chemicals in fish. J. Fish. Res. Board Can. 36: 1040–1048.
Øfjord, G. D., Vik, E. A., Bakke, S., Johnson, D. R., Edvardsson, T. (1995): CHARM — Chemical Hazard Assessment and Risk Management of offshore E&P Chemicals. Proceedings from the 6th International Symposium Oil Field Chemicals, Geilo, Norway, 19–22 March, No. 5570–7020.
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Vik, E.A., Bakke, S., Johnson, D.R., Verburgh, J. (1996). The N-Octanol/Water Partition Coefficient. In: Reed, M., Johnsen, S. (eds) Produced Water 2. Environmental Science Research, vol 52. Springer, Boston, MA. https://doi.org/10.1007/978-1-4613-0379-4_14
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DOI: https://doi.org/10.1007/978-1-4613-0379-4_14
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