Abstract
Boyd and England (1963) studied melting of diopside under dry conditions up to pressures of 50 kbar. Boettcher et al. (1982) corrected these data below 30 kbar. Eggler (1973) was the first to study the system diopside-water up to a temperature of 1430°C at a pressure of 20 kbar. Hodges (1974) published data at the same pressure up to 1500°C. Rosenhauer and Eggler (1975) repeated Hodges’s runs at 20 kbar and discovered a large difference in composition of the system at the univariant point (see Table 1). These authors did not discard their own data three years later (Rosenhauer and Eggler, 1978). Eggler and Burnham (1984) reported data on the liquidus of the system diopside-water studied in a gas vessel at a pressure of 2 kbar. Table 1 compiles the present day data on the water-saturated liquidus.
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References
Boettcher, A.L., Burnham, C.W., Windom, K.E., and Bohlen, S.R. (1982) Liquids, glasses, and the melting of silicates at high pressures. J. Geol., 90, 127–138.
Boyd, R.F., and England, J.L. (1963) Effect of pressure on the melting of diopside, CaMgSi2O6, and albite, NaAlSi3O8, in the range up to 50 kilobars. J. Geophys. Res., 68, 311–323.
Burnham, C.W., and Davis, N.F. (1974) The role of H2O in silicate melts: Part. II. Thermodynamics and phase relations in the system NaAlSi3O8-H2O to 10 kb, 750°C to 1,100°C. Amer. J. Sci., 274, 902–940.
Burnham, C.W., and Davis, N.F. (1970) Thermodynamic properties of water-bearing magmas. Phys. Earth Planet Int., 3, 332–348.
Carmichael, I.S., Nicholls, J., Spera, F.J., Wood, B.J., and Nelson, S.A. (1977) High temperature properties of silicate liquids: applications to the equilibration and ascent of basic magma. Philos. Trans. Roy. Soc. Lond. [A], 286, 373–431.
Eggler, D.H., and Burnham, C.W. (1984) Solution of H2O in diopside melts: a thermo-dynamic model. Contrib. Mineral. Petrol., 85, 58–66.
Eggler, D.H. (1973) Role of C02 in melting processes in the mantle. Carnegie Inst. Wash., 72, 457–467.
Eggler, D.H., and Rosenhauer, M. (1978) Carbon dioxide in silicate melts: II. Solubilities of CO2 and H2O in CaMgSi2O6 (diopside) liquids and vapors at pressures to 40 kb. Amer. J. Sci., 278, 64–94.
Epel’baum, M.B. (1985) The structures and properties of hydrous granitic melts. Geol. Zbornik—Geol. Carpathica, 36, 491–498.
Epel’baum, M.B., Persikov, E.S., and Zhigun, I.G. (1984) Relations of the different water species in the hydrous albite glass. Contrib. Phys. Chem. Petrol., 12, 72–78.
Ferrier, A. (1968) Chimie pyroxene—Mesure de l’enthalpe du diopside sinthetique entre 298 et i 885, K. Comp. Rend. Acad. Sci. Paris. Ser. C., 267, 101–106.
Ferrier, A. (1971) Etude experimentale de l’enthalpie de cristallisation du diopside et de l’anorthite sinthetique. Rev. Int. Hautes Temp. Refract. 8, 31–36.
Flory, P.J. (1942) The thermodynamics of high polymers. J. Chem. Phys., 10, 51–61.
Goranson, (1936) The solubility of H2O in albite melts. Amer. Geoph. Union Trans. 17, 257–268.
Kadik, A. A. (1965) State of the water and silicate components in the melts (magmas) of acid composition at high pressure of H2O vapor. In: Geochemical Studies at High Temperatures and Pressures, edited by N. I. Khitarov, pp. 5–15. Nauka, Moscow.
Kestin, J., Sengers, J.V., Kandar-Parsi, B., and Levelt Sengars, J. M. H. Thermophysical properties of fluid H2O. J. Phys. Chem. Ref. Data, 3, 175–183.
Kracek, F.C. (1953) Contributions of thermochemical and X-ray data to the problem of mineral stability. Carnegie Inst. Wash., 52, 69–75.
Kushiro, I. (1976) Changes in viscosity and structure of melts of NaAlSi3O8 composition at high pressure. J. Geophys. Res., 81, 6347–6350.
Kurkjian, C.R., and Russel, L.E. (1958) Solubility of water in molten alkali silicates. J. Soc. Glass. Technol., 42,130–144.
Langmuir, C.H., and Hanson, G.N. (1981) Calculating mineral-melt equilibria with stoi-chiometry, mass balance, and single-component distribution coefficients. In: Advances in Physical Geochemistry, Vol. 1, edited by S.K. Saxena, pp. 247–271. Springer-Verlag, New York.
Hodges, F.N. (1973) Solubility of H2O in forsterite melt at 20 kb. Carnegie Inst. Wash., 72, 495–497.
Hodges, F.N. (1974) The solubility of H2O in silicate melts. Carnegie Inst. Wash., 73, 251–255.
Moelwyn-Hughes, E.A. (1961) Physical Chemistry. Pergamon Press, London and New York.
Meyer, K.N., and Lunderman, R. (1935) Ü ber das Verhalten hoher molekularer Verbin-dung in Lösung. Helvet. Chim. Acta, 18, 307–325.
Navrotsky, A. (1980) Thermodynamics of mixing in silicate glasses and melts. In Advances in Physical Geochemistry, Vol. 1, edited by S.K. Saxena, pp. 189–206. Springer-Verlag, New York.
Navrotsky, A., and Coons, W.E. (1976) Thermochemistry of some pyroxenes and related compounds. Geochim. Cosmochim. Acta, 40, 1281–1288.
Navrotsky, A., Hon, R., Weil, D.F., and Henry, D. (1980) Thermochemistry of glasses and liquids in the systems CaMgSi2O6-CaAl2Si2O8-NaAlSi3O8, Si02-CaAl2Si2O8-NaAlSi3O8 and SiO2-Al2O3-CaO-Na2O. Geochim. Cosmochim. Acta, 44,1409–1423.
Persikov, E.C. Experimental study of H2O solubility in granitic melt and kinetics of equilibria of granitic melt-H2O at high pressures. Geology Geophys., 9, 3–9.
Perchuk, L.L. (1973) Thermodynamic Regime of Depth Petrogenesis. Nauka Press, Moscow, 316 pp.
Perchuk, L.L. (1983) System alkali basalt—water: I. Analyses of run products near the liquidus at pressure 15 kbar. Contrib. Phys.-Chem. Petrol. 11, 103–120.
Perchuk, L.L. (1985) System alkaline basalt—water. II. Liquidus surface at pressures 1–20,000 bar. Contrib. Phys.-Chem. Petrol., 13, 66–80.
Perchuk, L.L., and Vaganov, V.I. (1978) Temperature regime of crystallization and differentiation of basic and ultrabasic magmas. Contrib. Phys.-Chem. Petrol., 6, 142–174.
Perchuk, L.L., and Kushiro, I. (1985) Experimental study of the system alkali basalt-water up to pressure 20 kbar in respect of estimation of H2O content in the original magmas beneath the island arcs. Geol. Zbornik.—Geol. Carpathica, 36, 3, 359–368.
Perchuk L.L., Kushiro, I., and Kosyakov, A.V. (1988). Experimental determination of the liquidus surface in the system diopside-water. Geokhimia, 7, 942–955.
Robie, R.A., Hemingway, B.S., and Fisher, J.R. (1978) Thermodynamic properties of minerals and related substances at 298,15, K and 1 bar pressure and at higher temperatures. US Government Printing Office, 1452,456.
Rosenhauer, M, and Eggler, D.H. (1975) Solution of H2O and CO2 in diopside melt. Carnegie Inst. Wash., 74, 474–479.
Ryabchikov, I.D. (1975) Thermodynamics of Fluid Phase of Granitic Magmas. Nauka, Moscow, 320 pp.
Ryabchikov, I.D., Solovova, I.P., Dmitriyev, Yu.I., and Muravitskaya, G.N. (1984) Water in parental magma of oceanic Fe-basalts. Geokhimia, 2, 209–216.
Show, H.R. (1964) Theoretical solubility of H2O in silicate melts: quasi-crystalline models. J. Geol., 72, 601–617.
Silver, L., and Stolper, E.A. (1985) Thermodynamic model for hydrous silicate melts. J. Geol., 93,161–177.
Stolper, E. (1982,a) Water in silicate melts: an infrared spectroscopic study. Contrib. Mineral. Petrol., 81, 1–17.
Stolper, E. (1982,b) The specification of water in silicate melts. Geochim. Cosmochim. Acta, 46, 2609–2620.
Yoder, H.S. (1965) Diopside-anorthite-water at 5–10 kbar and its bearing on explosive volcanism. Carnegie Inst. Wash., 64, 82–89.
Yoder, H.S. (1975) Heat of melting of simple systems related to basalts and eclogites. Carnegie Inst. Wash., 74, 515–519.
Wasserburg, G.J. (1957) Effect H2O in silicate systems. J. Geol., 65, 15–23.
Weil, D.F., Hon, R., and Navrotsky, A. (1980) The igneous system CaMgSi2O6-CaAl2Si2O8-NaAlSi3O8: variations on a classic theme by Bowen. In Physics of Magmatic Processes, edited by R.B. Hargraves, pp. 49–92. Princeton University Press, Princeton, NJ.
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Perchuk, L.L., Kushiro, I. (1991). Thermodynamics of the Liquidus in the System Diopside—Water: A Review. In: Perchuk, L.L., Kushiro, I. (eds) Physical Chemistry of Magmas. Advances in Physical Geochemistry, vol 9. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-3128-8_9
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