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Crystal Chemical and Energetic Characterization of Solid Solution

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Thermodynamic Data

Part of the book series: Advances in Physical Geochemistry ((PHYSICAL GEOCHE,volume 10))

Abstract

The golden age of classic crystal chemistry (1920s–30s) yielded many well-known empirical rules and generalizations concerning the formation of solid solutions or isomorphous mixtures (mixed crystals). Among them are Vegard’s rule of additive dependence of lattice spacings on composition, Goldschmidt and Hume-Roseri’s rules of maximal 15% difference of ionic or atomic radii for the existence of wide miscibility, Goldschmidt and Fersman’s rules of substitution polarity (in relation to sizes and charges of the ions replacing each other), and the criteria of proximity of polarizabilities or electronegativities of substituents, etc. In the sections that follow we will return to an analysis of these rules from a more sophisticated and modern point of view.

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Author information

Authors and Affiliations

  1. Department of Crystallography and Crystal Chemistry, Geological Faculty, Moscow State University, 119899, Moscow, Russia

    V. S. Urusov

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  1. V. S. Urusov
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Editors and Affiliations

  1. Planetary Geochemistry Program Institute of Geology, Uppsala University, Box 555, S-75122, Uppsala, Sweden

    Surendra K. Saxena

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© 1992 Springer-Verlag New York Inc.

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Urusov, V.S. (1992). Crystal Chemical and Energetic Characterization of Solid Solution. In: Saxena, S.K. (eds) Thermodynamic Data. Advances in Physical Geochemistry, vol 10. Springer, New York, NY. https://doi.org/10.1007/978-1-4612-2842-4_6

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  • DOI: https://doi.org/10.1007/978-1-4612-2842-4_6

  • Publisher Name: Springer, New York, NY

  • Print ISBN: 978-1-4612-7692-0

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