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Hyperbranched Silicon-Containing Polymers via Bimolecular Non-linear Polymerization

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Silicon-Containing Dendritic Polymers

Part of the book series: Advances in Silicon Science ((ADSS,volume 2))

Bimolecular non-linear polymerization, BMNLP (see Reaction Scheme 16.1), represents ‘the other method’ for preparation of hyperbranched polymers by the step-growth reaction mechanism. In contrast to the monomolecular polymerizations of ABx monomers, discussed for the two most prominent groups of silicon-containing hyperbranched polymers in Chapters 12 and 13, this polymerization type involves, as its name implies, two reactive monomers Ax and By, where A and B denote two types of mutually reactive functional groups while x and y are integers which must both be equal to or larger than 2, while one of them (either x or y) must be equal to or larger than 3 (see Section 16.3). Thus, the most common BMNLP systems include A2 + B3, A2 + B4, and A3 + B4 monomer combinations. General representation of the simplest of these, the A2 + B3 system in which the minor component has completely reacted, is shown in Reaction Scheme 16.1

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  1. Michigan Molecular Institute, W. St. Andrews Rd., 1910, Midland, MI, 48640, USA

    Petar R. Dvornic & Dale J. Meier

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    Petar R. Dvornic  & Michael J. Owen  & 

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Dvornic, P.R., Meier, D.J. (2009). Hyperbranched Silicon-Containing Polymers via Bimolecular Non-linear Polymerization. In: Dvornic, P.R., Owen, M.J. (eds) Silicon-Containing Dendritic Polymers. Advances in Silicon Science, vol 2. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-8174-3_16

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