Bis(3-methylbutantio) maleonitril has been obtained from the reaction of disodium salt, 1-bromo-3 methylb ü tan in acetone under nitrogen for 11 hours. MgPz has been synthesized through the cyclotetramerization reaction of magnesium and n-butanol with bis(3-methylbutantio) maleonitril. The metal free pophyrazine derivative was obtained by its treatment with trifluroacetic acid and further reaction of this product with cobalt(II) acetate, nickel(II) acetate and zinc(II) acetate led to the metal porphyrazine (MPz, M = Co, Ni ve Zn). These new compounds have been investigated and characterized by U V, FT-IR, 1H NMR, GC-MS and elemental analysis methods.
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Erdoğmuş, A., Keser Karaoğlan, G., Avciata, U., Gül, A. (2009). Synthesis and Characterization of New Type Soluble Porphyrazine Containing 1-Bromo-3-Methylbutan Group and Investigation of Its Complexes. In: Şener, B. (eds) Innovations in Chemical Biology. Springer, Dordrecht. https://doi.org/10.1007/978-1-4020-6955-0_44
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