The exponential growth in portable electronic devices such as cellular phones and laptop computers during the past decade has created enormous interest in compact, light-weight batteries offering high energy densities. Also, growing environmental concerns around the globe are driving the development of advanced batteries for electric vehicles. Lithium-ion batteries are appealing for these applications as they provide higher energy density compared to the other rechargeable battery systems such as lead-acid, nickel-cadmium, and nickel-metal hydride batteries as shown in Figure l.l.1 The higher volumetric and gravimetric energy densities of the lithium-ion cells in Figure 1.1 are due to the higher cell voltages (~ 4 V) achievable by the use of non-aqueous electrolytes, which also allow a wider temperature of operation. Lithium-ion cells have become a commercial reality after the initial announcement by Sony in the early 1990s because of an intense world-wide activity on lithium insertion compounds (electrode materials) during the past three decades. This chapter provides an overview of the electrode materials aspects of rechargeable lithium batteries. A more detailed discussion of the specific cathode and anode materials systems as well as the electrolytes is presented by various authors in the subsequent chapters.
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References
Lithium Battery Energy Storage (LIBES) Publication, Technological Research Association, Tokyo (1994).
M. S. Whittingham, Science 192 (1976) 1126.
M. K. Aydinol, G. J. Ceder, J. Electrochem. Soc. 144 (1997) 3832.
M. S. Whittingham, A. J. Jacobson, Intercalation Chemistry, Academic Press, New York (1982).
K. Mizushima, P.C. Jones, P.J. Wiseman, J.B. Goodenough, Mat. Res. Bull. 15 (1980) 783.
J.B. Goodenough, K. Mizushima, T. Takeda, Jap. J. Appl. Phys. 19 (1983) 305.
M.M. Thackeray, W.I.F. David, P.G. Bruce, J.B. Goodenough, Mat. Res. Bull. 18 (1983) 461.
J.P. Gabano, (Ed.) Lithium Batteries, Academic Press, London (1983).
H.V. Venkatasetty, (Ed.) Lithium Battery Technology, John Wiley, New York (1984).
G. Pistoia, (Ed.) Lithium Batteries: New Materials, Developments and Perspectives, Industrial Chemistry Library, Vol. 5, Elsevier, Amsterdam (1994).
C. Julien, G.A. Nazri, Solid State Batteries: Materials Design and Optimization, Kluwer, Boston (1994).
D. Linden, (Ed.) Handbook of Batteries, second edition, McGraw Hill, New York (1995).
M. Wakihara, O. Yamamoto, (Eds.) Lithium Ion Batteries: Fundamentals and Performance, Wiley-VCH, Weinheim (1998).
M.M. Thackeray, Prog. Solid State Chem. 25 (1997) 1.
A. Manthiram, J. Kim, Chem. Mat. 10 (1998) 2895.
A. Manthiram, J. Kim, Recent Res. Dev. Electrochem. 2 (1999) 31.
R.J. Gummow, M.M. Thackeray, W.I.F. David, S. Hull, Mat. Res. Bull. 27 (1992) 327.
R.J. Gummow, D.C. Liles, M.M. Thackeray, Mat. Res. Bull. 28 (1993) 235.
R.J. Gummow, D.C. Liles, M.M. Thackeray, Mat. Res. Bull. 28 (1993) 1177.
Y. Shao-Horn, S.A. Hackney, C.S. Johnson, A.J. Kahaian, M.M. Thackeray, J. Solid State Chem. 140(1998)116.
S. Choi, A. Manthiram, J. Electrochem. Soc. 149 (2002) A162.
J.N. Reimers, J.R. Dahn, J. Electrochem. Soc. 139 (1992) 2091.
G.G. Amatucci, J.M. Tarascon, L.C. Klein, Solid State Ionics 83 (1996) 167.
J. Cho, C. Kim, S.I. Yoo, Electrochem. Solid-State Lett. 3 (2000) 362.
J. Cho, Y.I. Kim, B. Park, Chem. Mater. 12 (2000) 3788.
J. Cho, Y.I. Kim, B. Park, J. Electrochem. Soc. 148 (2001) All 10.
J. Cho, Y.I. Kim, T.J. Kim, B. Park, Angew. Chem. Int. Ed. Engl. 40 (2001) 3367.
Z. Liu, H. Wang, L. Fang, J.Y. Lee, L.M. Gan, J. Power Sources 104 (2002) 101.
A.M. Kannan, L. Rabenberg, A. Manthiram, Electrochem. Solid-State Lett. 6 (2003) A16.
Z. Chen, J.R. Dahn, Electrochem. Solid-State Lett. 5 (2002) A213.
T. Ohzuku, A. Ueda, M. Nagayama, J. Electrochem. Soc. 140 (1993) 1862.
G.G. Amatucci, J.M. Tarascon, L.C. Klein, J. Electrochem. Soc. 143 (1996) 1114.
J.M. Tarascon, G. Vaughan, Y. Chabre, L. Seguin, M. Anne, P. Strobel, G.G. Amatucci, J. Solid State Chem. 147 (1999) 410.
X.Q. Yang, X. Sun, J. McBreen, Electrochem. Comm. 2 (2000) 100.
R.V. Chebiam, F. Prado, A. Manthiram, Chem. Mater. 13 (2001) 2951.
R.V. Chebiam, F. Prado, A. Manthiram, J. Solid State Chem. 163 (2002) 5.
S. Venkatraman, A. Manthiram, Chem. Mater. 14 (2002) 3907.
S. Venkatraman, Y. Shin, A. Manthiram, Electrochem. Solid-State Lett. 6 (2003) A9.
A.R. Wizansky, P.E. Rauch, F.J. DiSalvo, J. Solid State Chem. 81 (1989) 203.
A. Manthiram, J.S. Swinnea, Z.T. Sui, H. Steinfink, J.B. Goodenough, J. Amer.Chem. Soc. 109 (1987) 6667.
G. Dutta, A. Manthiram, J.B. Goodenough, J. Solid State Chem. 96 (1992) 123.
A. Hirano, R. Kanno, Y. Kawamoto, Y. Takeda, K. Yamamura, M. Takano, K. Ohyama, M. Ohashi, Y. Yamaguchi, Solid State Ionics 78 (1995) 123.
R. Kanno, H. Kubo, Y. Kawamoto, T. Kamiyama, F. Izumi, Y. Takeda, M. Takano, J. Solid State Chem. 110 (1994) 216.
I. Nakai, T. Nakagome, Electrochem. Solid-State Lett. 1 (1998) 259.
I. Nakai, K. Takahashi, Y. Shiraishi, T. Nakagome, F. Nishikawa, J. Solid State Chem. 140 (1998) 145.
T. Ohzuku, A. Ueda, M. Nagayama, Y. Iwakashi, H. Komori, Electrochim. Acta 38 (1993) 1159.
J.R. Dahn, E.W. Fuller, M. Obrovac, U. von Sacken, Solid State Ionics 69 (1994) 265.
Z. Zhang, D. Fouchard, J.R. Rea, J. Power Sources 70 (1998) 16.
W. Li, J. Curie, J. Electrochem. Soc. 144 (1997) 2773.
G. Nagasubramanian, Proceedings of the 40th Power Sources Conference, Cherry Hill, NJ, June 10–13, 2002, p. 434.
R.V. Chebiam, F. Prado, A. Manthiram, J. Electrochem. Soc. 148 (2001) A49.
A.M. Kannan, A. Manthiram, J. Electrochem. Soc. 150 (2003) A349.
S. Choi, A. Manthiram, J. Electrochem. Soc. 149 (2002) A1157.
J.E. Huheey, Inorganic Chemistry, second edition, Harper and Row, New York, 1978, p. 348.
F. Ronci, B. Scrosati, V.R. Albertini, P. Perfetti, Electrochem. Solid-State Lett. 3 (2000) 174.
R.V. Chebiam, A.M. Kannan, F. Prado, A. Manthiram, Electrochem. Commun. 3 (2001) 624.
L.A. Montoro, M. Abbate, J.M. Rosolen, Electrochem. Solid-State Lett 3 (2000) 410.
A.N. Mansour, X.Q. Yang, X. Sun, J. McBreen, L. Croguennec, C. Delmas, J. Electrochem. Soc. 147 (2000) 2104.
M. Balasubramanian, X. Sun, X.Q. Yang, J. McBreen, J. Electrochem. Soc. 147 (2000) 2903.
G. Ceder, Y.M. Chiang, D.R. Sadoway, M.K. Aydinol, Y.I. Jang, B. Hunny, Nature 392 (1998) 695.
A. Van der Ven, M.K. Aydinol, G. Ceder, G. Kresse, J. Harner, Phys. Rev. B 58 (1998) 2975.
L.A. de Picciotto, M.M. Thackeray, W.I.F. David, P.G. Bruce, J.B. Goodenough, Mat. Res. Bull. 19 (1984) 1497.
A.R. Armstrong, P.G. Bruce, Nature 381 (1996) 499.
F. Capitaine, P. Gravereau, C. Delmas, Solid State Ionics 89 (1996) 197.
B. Fuchs, S. Kemmler-Sack, Solid State Ionics 68 (1994) 279.
I.J. Davidson, R.S. McMillan, J.J. Murray, J. Power Sources 54 (1995) 205.
J. Davidson, R.S. McMillan, H. Slegr, B. Luan, I. Kargina, J.J. Murray, LP. Swainson, J. Power Sources 8182 (1999) 406.
H. Wang, Y.I. Jang, Y.M. Chiang, Electrochem. Solid-State Lett. 2 (1999) 490.
R.J. Gummow, D.C. Liles,.M.M. Thackeray, Mat. Res. Bull. 28 (1993) 1249.
T. Ohzuku, M. Kitagawa, T. Hirai, J. Electrochem. Soc. 137 (1990) 769.
M.M. Thackeray, Y. Shao-Horn, A.J. Kahaian, K.D. Kepler, E. Skinner, J.T. Vaughey, S.A. Hackney, Electrochem. Solid-State Lett. 1 (1998) 7.
D.H. Jang, Y.J. Shin, S.M. Oh, J. Electrochem. Soc. 143 (1996) 2204.
T. Inoue, M. Sano, J. Electrochem. Soc. 145 (1998) 3704.
A. Du Pasquier, A. Blyr, P. Courjal, D. Larcher, G. Amatucci, B. Gerand, J.M. Tarascon, J. Electrochem. Soc. 146 (1999) 428.
Y. Xia, M. Yoshio, J. Electrochem. Soc. 143 (1996) 825.
H. Huang, C.A. Vincent, P.G. Bruce, J. Electrochem. Soc. 146 (1999) 3649.
A.M. Kannan, A. Manthiram, Electrochem. Solid-State Lett. 5 (2002) A167.
Y. Shin, A. Manthiram, Electrochem. Solid-State Lett. 5 (2002) A55.
M.M. Thackeray, A. de Kock, M.H. Rossouw, D.C. Liles, D. Hoge, R. Bittihn, J. Electrochem. Soc. 139 (1992) 363.
R.J. Gummow, A. de Kock, M.M. Thackeray, Solid State Ionics 69 (1994) 59.
S. Choi, A. Manthiram, J. Electrochem. Soc. 147 (2000) 1623.
M.M. Thackeray, M.F. Mansuetto, D.W. Dees, D.R. Vissers, Mater. Res. Bull. 31 (1996) 133.
Y. Gao, J.R. Dahn, J. Electrochem. Soc. 143 (1996) 1783.
M.M. Thackeray, M.F. Mansuetto, C.S. Johnson, J. Solid State Chem. 125 (1996) 274.
J. Kim, A. Manthiram, J. Electrochem. Soc. 145 (1998) L53.
C. Sigala, D. Guyomard, A. Verbaere, Y. Piffard, M. Tournoux, Solid State Ionics 81 (1995) 167.
H. Kawai, M. Nagata, H. Takamoto, A.R. West, Electrochem. Solid-State Lett. 1 (1998) 212.
Q. Zhong, A. Bonakdarpour, M. Zhang, Y. Gao, J.R. Dahn, J. Electrochem. Soc. 144 (1997) 205.
Y. Ein-Eli, W.F. Howard, Jr., S.H. Lu, S. Mukerjee, J. McBreen, J.T. Vaughey, M.M. Thackeray, J. Electrochem. Soc. 145 (1998) 1238.
H. Kawai, M. Tabuchi, M. Nagata, H. Tukamoto, A.R. West, J. Mater. Chem. 8 (1998) 1273.
H. Kawai, M. Nagata, H. Tukamoto, A.R. West, J. Power Sources 81–82 (1999) 67.
Y. Shao-Horn, R. L. Middaugh, Solid State Ionics 139 (2001) 13.
A.R. West, H. Kawai, H. Kageyama, M. Tabuchi, M. Nagata, H. Tukamoto, J. Mater. Chem. 11 (2001) 1662.
Y. Shin, A. Manthiram, Electrochim. Acta (submitted).
S. Park, Y. Han, Y. Kang, P.S. Lee, S. Ahn, H. Lee, J. Lee, J. Electrochem. Soc. 148 (2001) A680.
J. Cho, G.B. Kim, H.S. Lim, C. Kim, S. Yoo, Electrochem. Solid State Lett. 2 (1999) 607.
H. Kweon, G. Kim, D. Park, US Patent No. 6,183,911 (2001).
Y. Shin, A. Manthiram, Electrochem. Solid-State Lett. 6 (2002) A34.
Y. Shin, A. Manthiram, J. Electrochem. Soc. (submitted).
D.W. Murphy, R.J. Cava, S.M. Zahurak, A. Santoro, Solid State Ionics 9&10 (1983) 413.
E. Ferg, R.J. Gummow, A. de Kock, M.M. Thackeray, J. Electrochem. Soc. 141 (1994) L147.
L.A. de Picciotto, M.M. Thackeray, Mat. Res. Bull. 20 (1985) 1409.
A. Manthiram, J.B. Goodenough, Can. J. Phys. 65 (1987) 1309.
S. Choi, A. Manthiram, J. Solid State Chem. 164 (2002) 332.
A. Manthiram, J.B. Goodenough, J. Power Sources 26 (1989) 403.
A. Manthiram, J.B. Goodenough, J. Solid State Chem. 71 (1987) 349.
A.K. Padhi, K.S. Nanjundaswamy, C. Masquelier, S. Okada, J.B. Goodenough, J. Electrochem. Soc. 144 (1997) 1609.
A.K. Padhi, K.S. Nanjundaswamy, C. Masquelier, J.B. Goodenough, J. Electrochem. Soc. 144 (1997) 2581.
A.K. Padhi, K.S. Nanjundaswamy, J.B. Goodenough, J. Electrochem. Soc. 144 (1997) 1188.
A. Yamada, S.C. Chung, K. Hinokuma, J. Electrochem. Soc. 148 (2001) A224.
H. Huang, S-C. Yin, L.F. Nazar, Electrochem. Solid-State Lett. 4 (2001) A170.
P.P. Prosini, M. Carewska, S. Scaccia, P. Wisniewski, S. Passerini, M. Pasquali, J. Electrochem. Soc. 149 (2002) A886.
S.Y. Chung, J.T. Bloking, Y.M. Chiang, Nature Materials 1 (2002) 123.
M.M. Doeff, T.J. Richardson, L. Kepley, J. Electrochem. Soc. 143 (1996) 2507.
Y.U. Jeong, A. Manthiram, Electrochem. Solid-State Lett. 2 (1999) 421.
C. Tsang, A. Manthiram, J. Electrochem. Soc. 144 (1997) 520.
C. Lampe-Onnerud, J.O. Thomas, M. Hardgrave, S. Yde-Andersen, J. Electrochem. Soc. 142 (1995) 3648.
K. Wilhelmi, K. Waltersson, L. Kihlborg, Acta Chem. Scand. 25 (1971) 2675.
F. Theobald, R. Cabala, J. Bernard, J. Solid State Chem. 17 (1976) 431.
A.L. Tipton, S. Passerini, B.B. Owens, W.H. Smyrl, J. Electrochem. Soc. 143 (1996) 3473.
A.M. Kannan, A. Manthiram, J. Electrochem. Soc. (in press).
N. Kumagai, A. Yu, J. Electrochem. Soc. 144 (1997) 830.
Y. Takeda, R. Kanno, Y. Tsuji, O. Yamamoto, J. Power Sources 9 (1983) 325.
B.B. Owens, S. Passerini, W.H. Smyrl, Electrochim. Acta 45 (1999) 215.
A.M. Kannan, A. Manthiram, Solid State Ionics (in press).
O. Yamamoto, Y. Takeda, R. Kanno, Y. Oyabe, Y. Shinya, J. Power Sources 20 (1987) 151.
J. Kim, A. Manthiram, J. Electrochem. Soc. 144 (1997) 3077.
J. Kim, A. Manthiram, Nature 390 (1997) 265.
J.J. Xu, A.J. Kinser, B.B. Owens, W.H. Smyrl, Electrochem. Solid-State Lett. 1 (1998) 1.
J. Kim, A. Manthiram, Electrochem. Solid-State Lett. 2 (1999) 55.
D. Im, A. Manthiram, J. Electrochem. Soc. 149 (2002) A1001.
D. Im, A. Manthiram, J. Electrochem. Soc. (in press).
D. Im, A. Manthiram, Solid State Ionics (in press).
J. Kim, A. Manthiram, J. Electrochem. Soc. 146 (1999) 4371.
S. Choi, A. Manthiram, J. Electrochem. Soc. 149 (2002) A570.
C.R. Home, U. Bergmann, J. Kim, K.A. Streibel, A. Manthiram, S.F. Cramer, E.J. Cairns, J. Electrochem. Soc. 147 (2000) 395.
N. Imanishi, Y. Takeda, O. Yamamoto, in Lithium Ion Batteries: Fundamentals and Performance (M. Wakihara and O. Yamamoto, Eds.), 1998, p. 98, Wiley-VCH, Weinheim.
M. Winter, J.O. Besenhard, in Lithium Ion Batteries: Fundamentals and Performance (M. Wakihara and O. Yamamoto, Eds.), 1998, p. 127, Wiley-VCH, Weinheim.
W. Liu, X. Huang, Z. Wang, H. Li, L. Chen, J. Electrochem. Soc. 145 (1998) 59.
J.J. Auborn, Y.L. Barbeiro, J. Electrochem. Soc. 134 (1987) 638.
K.M. Abraham, D.M. Pasquariello, E.B. Willstaedt, J. Electrochem. Soc. 137 (1990) 743.
S. Morzilli, B. Scrosati, F. Sgarlatta, Electrochim. Acta 30 (1985) 1271.
D.C.S. Souza, V. Pralong, A.J. Jacobson, L.F. Nazar, Science 296 (2002) 2012.
K.D. Kepler, J.T. Vaughey, M.M. Thackeray, Electrochem. Solid-State Lett. 2 (1999) 307.
J.L.C. Rowsell, V. Pralong, L.F. Nazar, J. Amer. Chem. Soc. 123 (2001) 8598.
J.T. Vaughey, K.D. Kepler, R. Benedek, M.M. Thackeray, Electrochem. Comm. 1 (1999) 517.
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Manthiram, A. (2009). Materials Aspects: An Overview. In: Nazri, GA., Pistoia, G. (eds) Lithium Batteries. Springer, Boston, MA. https://doi.org/10.1007/978-0-387-92675-9_1
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