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Daytime Atmospheric Chemistry of C 4–C 7 Saturated and Unsaturated Carbonyl Compounds

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Environment, Energy and Climate Change I

Part of the book series: The Handbook of Environmental Chemistry ((HEC,volume 32))

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Abstract

This chapter aims to review the daytime atmospheric chemistry of some carbonyl compounds, crucial intermediates in the autocatalytic production of the main atmospheric oxidant, the hydroxyl radical (OH•). Carbonyl compounds are very important trace gases for the physico-chemistry of the troposphere mainly because they are directly emitted into the atmosphere or formed in situ in the photooxidation of almost all organic compounds. Particularly aldehydes (RCHO, R=alkyl chain) and ketones (RC(O)R′) are important key species in many atmospheric processes, because they undergo a wide variety of reactions, both chemical and photolytic. This chapter presents a synthesis of the studies on the chemistry of C 4–C 7 saturated and unsaturated aldehydes and ketones in the troposphere. A comprehensive revision of the gas-phase rate coefficients for the reactions of these carbonyls with the major diurnal oxidants, photolysis frequencies and chemical mechanisms is also presented. The impact of these species on urban air pollution is also discussed. These kinetic and photochemical data can be included in the chemical modules of atmospheric models which are used by policymakers in formulating and deciding strategies for the improvement of air quality.

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Abbreviations

CL:

Chemiluminescence

DF:

Discharge flow tube

FID:

Flame ionisation detection

FP:

Flash photolysis

FT:

Flow tube

FTIR:

Fourier transform infrared

GC:

Gas chromatography

LIF:

Laser-induced fluorescence

MCM:

Master chemical mechanism

MIR:

Maximum incremental reactivity

MS:

Mass spectrometry

n.m.:

Not measured

OVOC:

Oxygenated volatile organic compound

PAN:

Peroxyacetyl nitrate

PANs:

Peroxyacyl nitrates

PLP:

Pulsed laser photolysis

POCP:

Photochemical ozone creation potential

ppmv:

Parts per million based on volume

RF:

Resonance fluorescence

ROG:

Reactive organic gas

RR:

Relative rate

SAR:

Structure activity relationship

SOA:

Secondary organic aerosol

UV:

Ultraviolet

VOC:

Volatile organic compound

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Authors and Affiliations

  1. Departamento de Química Física, Facultad de Ciencias y Tecnologías Químicas, Universidad de Castilla-La Mancha, Avda. Camilo José Cela s/n, 13071, Ciudad Real, Spain

    Elena Jiménez

  2. Instituto de Investigación en Combustión y Contaminación Atmosférica (ICCA), Universidad de Castilla-La Mancha, Camino de Moledores s/n, 13071, Ciudad Real, Spain

    Elena Jiménez

  3. Fachbereich C – Physikalische Chemie, Bergische Universität Wuppertal, Gauss Strasse 20., 42119, Wuppertal, Germany

    Ian Barnes

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  1. Elena Jiménez
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Correspondence to Elena Jiménez .

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  1. Department of Physical Chemistry, University of Castilla-La Mancha (UCLM), Ciudad Real, Spain

    Elena Jiménez

  2. Department of Physical Chemistry, University of Castilla-La Mancha (UCLM), Ciudad Real, Spain

    Beatriz Cabañas

  3. CERTES-IUT, The University Paris-Est Créteil, Paris Créteil, France

    Gilles Lefebvre

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Jiménez, E., Barnes, I. (2014). Daytime Atmospheric Chemistry of C 4–C 7 Saturated and Unsaturated Carbonyl Compounds. In: Jiménez, E., Cabañas, B., Lefebvre, G. (eds) Environment, Energy and Climate Change I. The Handbook of Environmental Chemistry, vol 32. Springer, Cham. https://doi.org/10.1007/698_2014_286

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