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Construction and Luminescence Properties of 4f and d-4f Clusters with Salen-Type Schiff Base Ligands

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Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials

Part of the book series: Structure and Bonding ((STRUCTURE,volume 173))

Abstract

The synthesis, crystal structures, and photophysical properties of twenty-three 4f and d-4f clusters based on eight salen-type Schiff base ligands are described in this chapter. Most of these lanthanide-based clusters exhibit interesting “enclosed” structures, such as multi-decker, “twisted,” and drum-like structures. In these polynuclear complexes, the multidentate salen-type ligands can efficiently sensitize lanthanide emissions by serving as antennas that absorb excitation light and transfer the energy to the lanthanide centers. With the lanthanide ions encapsulated by chromophoric salen-type ligands and shielded from solvent molecules which can quench the emissions from lanthanide ions, those lanthanide-based clusters with “enclosed” structures show impressive luminescence properties.

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Acknowledgements

We thank the National Natural Science Foundation of China (No. 51025207, SMH) and the Welch Foundation (Grant F-816, RAJ) for financial support. Single crystal X-ray data were collected using instrumentation purchased with funds provided by the National Science Foundation (CHE-0741973), USA.

Overview

The synthesis, structures and luminescence properties of twenty-three 4f and d-4f clusters which are formed from eight salen-type Schiff base ligands are described in this chapter.

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Authors and Affiliations

  1. College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, 325035, China

    Xiaoping Yang, Shiqing Wang, Chengri Wang & Shaoming Huang

  2. Department of Chemistry and Biochemistry, The University of Texas at Austin, 1 University Station A5300, Austin, TX, 78712, USA

    Richard A. Jones

Authors
  1. Xiaoping Yang
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  2. Shiqing Wang
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  3. Chengri Wang
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  4. Shaoming Huang
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  5. Richard A. Jones
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Corresponding authors

Correspondence to Xiaoping Yang , Shaoming Huang or Richard A. Jones .

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Editors and Affiliations

  1. Department of Chemistry and Biochemistry, University of Arizona, Tucson, Arizona, USA

    Zhiping Zheng

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Yang, X., Wang, S., Wang, C., Huang, S., Jones, R.A. (2016). Construction and Luminescence Properties of 4f and d-4f Clusters with Salen-Type Schiff Base Ligands. In: Zheng, Z. (eds) Recent Development in Clusters of Rare Earths and Actinides: Chemistry and Materials. Structure and Bonding, vol 173. Springer, Berlin, Heidelberg. https://doi.org/10.1007/430_2016_10

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