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The Carbon Dioxide Molecule and the Effects of Its Interaction with Electrophiles and Nucleophiles

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Carbon Dioxide and Organometallics

Part of the book series: Topics in Organometallic Chemistry ((TOPORGAN,volume 53))

Abstract

This chapter discusses the CO2 molecule in its ground and excited states, correlating the energy to the molecular geometry. The effect of adding or taking out an electron is illustrated, opening the way to the coordination of CO2 to metal centers. Several modes of bonding of CO2 are presented and the IR and multinuclear NMR spectroscopic data of transition metal complexes or adducts with Lewis acids and bases are commented. The reactivity of the coordinated heterocumulene is presented through several examples. The use of IR and NMR techniques for determining the molecular behavior of transition metal complexes in solution is exemplified.

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  1. Department of Chemical and Biomolecular Engineering, NUS, Singapore, Singapore

    Michele Aresta

  2. CIRCC, via Celso Ulpiani 27, 70126, Bari, Italy

    Michele Aresta & Antonella Angelini

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  1. State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, China

    Xiao-Bing Lu

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Aresta, M., Angelini, A. (2015). The Carbon Dioxide Molecule and the Effects of Its Interaction with Electrophiles and Nucleophiles. In: Lu, XB. (eds) Carbon Dioxide and Organometallics. Topics in Organometallic Chemistry, vol 53. Springer, Cham. https://doi.org/10.1007/3418_2015_93

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