Skip to main content
SpringerLink
Log in

Molecular Properties and Electrostatic Interactions of Linear Poly(allylamine hydrochloride) Chains

  • Conference paper
  • First Online:
Analytical Ultracentrifugation VIII

Part of the book series: Progress in Colloid and Polymer Science ((PROGCOLLOID,volume 131))

Abstract

The efficiency of two azoinitiators in the polymerization of allylamine salts in water and organic solvents was studied comparatively. Hydrodynamic and molecular properties of poly(allylamine hydrochloride) in 0.1 M NaCl were investigated in the molecular mass range 18 < MsD × 10−3(g/mol) < 65. Molecular mass relationships were obtained for intrinsic viscosity ([η]), translation diffusion coefficient (D0) and velocity sedimentation coefficient (s0): [η] = 7.65 × 10−3 M0.8u0.1, D0 = 2.41 × 10−4 M−(0.59u0.05), s0 = 2.77 × 10−15 M0.41u0.05. Hydrodynamic data were interpreted by using the concept of electrostatic short- and long-range interactions. The equilibrium rigidity of poly(allylamine hydrochloride) chains in 0.1 M NaCl and structural and electrostatic contributions to it were quantitatively evaluated. It was shown that in pure water the conformation of poly(allylamine hydrochloride) chains is close to rod-like.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Wu G, Wu C (1985) J Biolog Chem 262:4429

    Google Scholar 

  2. Kabanov A, Kabanov V (1995) Bioconjugate Chem 6:7

    CAS  Google Scholar 

  3. Decher G, Schlenoff J (eds) (2003) Multilayer thin films. Wiley, New York

    Google Scholar 

  4. Kim B-S, Lebedeva O, Kim D, Caminade A-M, Majoral J-P, Knoll W, Vinogradova O (2005) Europ Polym Congress Abstracts:194, Moscow

    Google Scholar 

  5. Zubov V, Kumar V, Masterova M, Kabanov V (1979) J Macromol Sci Chem 13:111

    Google Scholar 

  6. Harada S, Hasegawa S (1984) Makromol Chem Rapid Comm 15:27

    Google Scholar 

  7. Masterova M, Andreeva L, Zubov V, Polak L, Kabanov V (1976) Vysokomolekul soedin 18A:1957

    Google Scholar 

  8. Kreindel M, Andreeva L, Kaplan A, Golubev V, Masterova M, Zubov V, Polak L, Kabanov V (1976) Vysokomolekul soedin 18A:2233

    Google Scholar 

  9. Wolfert M, Dash P, Nazarova O, Oupicky D, Seymour L, Smart S, Strohalm J, Ulbrich K (1999) Bioconjugate Chem 10:993

    Article  CAS  Google Scholar 

  10. Kasiyanenko N, Kopyshev A, Obuchova O, Nazarova O, Panarin E (2002) Zh Phys Chem 76:2021

    Google Scholar 

  11. Ochiai H, Handa M, Matsumoto H, Moriga T, Murakami I (1985) Makromolek Chemie 186:2547

    CAS  Google Scholar 

  12. Pavlov G, Panarin E, Korneeva E, Kurochkin E, Baikov V, Uschakova V (1990) Makromolek Chemie 191:2889

    CAS  Google Scholar 

  13. Pavlov G, Ivanova N, Korneeva E, Michailova N, Panarin E (1996) J Carbohydrate Chem 15:417

    Google Scholar 

  14. Solovskij M, Panarin E, Gorbunova O, Korneeva E, Petuhkova N, Michailova N, Pavlov G (2000) Eur Polym J 36:1127

    CAS  Google Scholar 

  15. Pavlov G, Korneeva E, Ebel C, Gavrilova I, Nesterova N, Panarin E (2004) Vysokomolekul Soedin 46A:1732

    Google Scholar 

  16. Tsvetkov V, Eskin V, Frenkel S (1970) Structure of Macromolecules in Solutions. Butterworths, London

    Google Scholar 

  17. Tsvetkov V (1989) Rigid-chain Polymers. Hydrodinamic and optical Properties in Solution. Consultants Bureau, New York, London

    Google Scholar 

  18. Pavlov G, Korneeva E, Harding S, Vichoreva G (1998) Polymer 39:6951

    CAS  Google Scholar 

  19. Pavlov G, Finet S, Tatarenko K, Korneeva E, Ebel C (2003) Europ Biophysics J 32:437

    Google Scholar 

  20. Mandelkern L, Flory P (1952) J Chem Phys 20:212

    CAS  Google Scholar 

  21. Tsvetkov V, Klenin S (1953) Dokl Akad Nauk SSSR 88:49

    CAS  Google Scholar 

  22. Pavlov G (1997) Europ Biophysics J 25:385

    Google Scholar 

  23. Pavlov G, Harding S, Rowe A (1999) Progr Colloid Polym Sci 113:76

    CAS  Google Scholar 

  24. Pavlov G (2005) Vysokomolekul soedin 47:1872

    CAS  Google Scholar 

  25. Newman S, Loeb L, Conrad C (1953) J Polym Sci 10:463

    CAS  Google Scholar 

  26. Hunt M, Newman S, Scheraga H, Flory P (1956) J Phys Chem 60:1278

    Article  CAS  Google Scholar 

  27. Pavlov G, Kozlov A, Martchenko G, Tsvetkov V (1982) Vysokomolekul soedin 24B:284

    Google Scholar 

  28. Mandel M (1993) Some properties of polyelectrolyte solutions and the scaling approach. In: Hara M (ed) Polyelectrolytes: science and technology. Dekker, New York, p 1–75

    Google Scholar 

  29. Barrat J-L, Joanny J-F (1996) Adv Chem Phys Ed by Prigogine I, Rice S 94:1

    CAS  Google Scholar 

  30. Ptitsyn O, Eizner Yu (1958) Zh Phys Chem 32:2464

    CAS  Google Scholar 

  31. Volkenstein M (1959) Configurational statistics of polymeric chains. Ed Academy Sci, Moscow, Leningrad

    Google Scholar 

  32. Gray G, Bloomfield V, Hearst J (1967) J Chem Phys 46:1493

    CAS  Google Scholar 

  33. Pavlov G (2002) Progr Colloid Polym Sci 119:149

    CAS  Google Scholar 

  34. Pavlov G, Selunin S, Shildiaeva N, Yakopson S, Efros L (1985) Vysokomolekul soedin 27A:1627

    Google Scholar 

  35. Yamakawa H (1971) Modern theory of polymer solutions. Harper and Row, New York

    Google Scholar 

  36. Odijk T (1977) J Polym Sci Polym Phys 15:477

    CAS  Google Scholar 

  37. Fuoss R, Strauss U (1948) J Polym Sci 3:602

    CAS  Google Scholar 

  38. Tanford C (1963) Physical chemistry of macromolecules. Wiley, New York

    Google Scholar 

Download references

Acknowledgments

This work is carried out with partial financial support of the Ministry of industry, science, and technologies of Russian Federation, grant N1823.2003.3.

The authors are sincerely grateful to C. Wandrey for drawing our attention to an excellent experimental work on the study of dilute solution properties of poly(allylammonium chloride) in aqueous sodium chloride solutions [11], which, unfortunately, was not known to the authors.

The authors also thank Gorbunova O. P., and Arpidov Yu. A. for participating in the experimental part of this work.

Author information

Authors and Affiliations

  1. Foke Institute of Physics, St. Petersburg University, Ul'yanovskaya str. 1, 198504, St. Petersburg, Russia

    G.M. Pavlov

  2. Institute of Macromolecular Compounds, Russian Academy of Sciences, Bol'shoi pr. 31, 199004, St. Petersburg, Russia

    E.F. Panarin, E.V. Korneeva, I.I. Gavrilova & N.N. Tarasova

Authors
  1. G.M. Pavlov
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. E.F. Panarin
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. E.V. Korneeva
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. I.I. Gavrilova
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. N.N. Tarasova
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to G.M. Pavlov .

Editor information

Christine Wandrey Helmut Cölfen

Rights and permissions

Reprints and permissions

About this paper

Cite this paper

Pavlov, G., Panarin, E., Korneeva, E., Gavrilova, I., Tarasova, N. Molecular Properties and Electrostatic Interactions of Linear Poly(allylamine hydrochloride) Chains. In: Wandrey, C., Cölfen, H. (eds) Analytical Ultracentrifugation VIII. Progress in Colloid and Polymer Science, vol 131. Springer, Berlin, Heidelberg. https://doi.org/10.1007/2882_014

Download citation

Publish with us

Policies and ethics

Search

Navigation