Abstract
Organic-inorganic hybrid nanofibers obtained by electrospinning technology have experienced a growing interest in the last decade thanks to the versatility and the high productivity of the technique, compared to other technologies devoted to the fabrication of nanocomposites, and to the unique and numerous features displayed by the produced nanomaterials. In this review, we classify and highlight recent progress, as well as current issues, in the production of hybrid nanofibers by electrospinning and their related applications. In particular, the scientific literature has been classified by taking into account the different methodologies that have been developed to fabricate hybrid polymeric-inorganic nanofibers by making use of electrospinning technology in combination with additional specific synthetic and processing procedures. The following technological and synthetic strategies have been discussed in detail: (1) electrospinning of inorganic dispersions in polymer solutions, (2) post treatments of electrospun fibers, (3) electrospinning combined with sol–gel processes, (4) electrospinning combined with electrospraying, (5) coaxial electrospinning, and (6) electrospinning of hybrid polymers. The huge number of different fiber morphologies, structures, and properties that can be achieved by electrospinning is impressive. The power of this technology is even more evident if we take into account that innovative hybrid nanofibers can be fabricated with a simple, versatile, extremely cheap, and scalable technology that makes electrospinning the most interesting currently available technique for the production of nanocomposites.
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Abbreviations
- β-TCP:
-
β-Tricalcium phosphate
- 1D:
-
One-dimensional
- Ac:
-
Acetate
- ALD:
-
Atomic layer deposition
- AOT:
-
Dioctyl sulfosuccinate sodium salt
- APTES:
-
(3-Aminopropyl)triethoxysilane
- ATRP:
-
Atom transfer radical polymerization
- BSA:
-
Bovine serum albumine
- BTESPTS:
-
1,4-Bis(triethoxysilyl)propane tetrasulfide
- CA:
-
Cellulose acetate
- Con-A:
-
Concanavalin-A
- COS:
-
Chitosan oligomers
- Ct:
-
Cathecol
- CTAB:
-
Cetyltrimethyl ammonium bromide
- DMF:
-
N,N-Dimethyl formamide
- DSC:
-
Differential scanning calorimetry
- FA:
-
Formic acid
- FESEM:
-
Field emission scanning electron microscopy
- FTIR:
-
Fourier transform infrared spectroscopy
- HA:
-
Hydroxyapatite
- HFIP:
-
1,1,1,3,3,3-Hexafluoro-2-propanol
- HSA:
-
12-Hydroxystearic acid
- LbL:
-
Layer-by-layer
- LPD:
-
Liquid phase deposition
- MPTMS:
-
(3-Mercaptopropyl)trimethoxysilane
- NEC:
-
Neuro-microvascular endothelial cell
- NIR:
-
Near infrared
- NP:
-
Nanoparticle
- P(LA-co-CL):
-
Poly(lactic acid-co-caprolactone)
- P(VDF-co-CTFE):
-
Poly(vinylidene fluoride-co-chlorotrifluoroethylene)
- PAA:
-
Poly(acrylic acid)
- PAN:
-
Polyacrylonitrile
- PANI:
-
Polyaniline
- PCL:
-
Poly(ε-caprolactone)
- PE:
-
Polyethylene
- PEDOT:PSS:
-
Poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate)
- PEG:
-
Poly(ethylene glycol)
- PEO:
-
Poly(ethylene oxide)
- PET:
-
Poly(ethylene terephthalate)
- PHB:
-
Poly(3-hydroxybutyric acid)
- PHEMA:
-
Poly(2-hydroxyethyl methacrylate)
- PI:
-
Polyimide
- PLA:
-
Polylactide
- PLLA:
-
Poly(l-lactic acid)
- PLGA:
-
Poly(lactide-co-glycolide)
- PMMA:
-
Poly(methyl methacrylate)
- POSS-NH3 + :
-
Octa(3-ammoniumpropyl) octasilsesquioxane octachlo ride
- PPhe-GlyP:
-
Polyphosphazenes with phenylalanine ethyl ester and glycine ethyl ester as co-substituents
- PPV:
-
Poly(p-phenylene vinylene)
- PPy:
-
Polypyrrole
- PS:
-
Polystyrene
- PSEI:
-
Poly(dimethylsiloxane-b-etherimide)
- PSU:
-
Polysulfone
- PU:
-
Polyurethane
- PVA:
-
Poly(vinyl alcohol)
- PVAc:
-
Poly(vinyl acetate)
- PVC:
-
Poly(vinyl chloride)
- PVDF:
-
Poly(vinylidene difluoride)
- PVP:
-
Poly(vinyl pyrrolidone)
- QDs:
-
Quantum dots
- Rh-B:
-
Rhodamine-B
- RT:
-
Room temperature
- SEM:
-
Scanning electron microscopy
- SERS:
-
Surface-enhanced Raman scattering
- TEM:
-
Transmission electron microscopy
- TEOS:
-
Tetraethyl orthosilicate
- TESPSA:
-
(3-Triethoxysilylpropyl)succinic anhydride
- Triton X-100:
-
4-(1,1,3,3-Tetramethylbutyl)phenyl-polyethylene glycol
- UV:
-
Ultraviolet
- VA:
-
Vinyl alcohol
- Vis:
-
Visible
- XPS:
-
X-ray photoelectron spectroscopy
References
Crespy D, Friedemann K, Popa AM (2012) Colloid-electrospinning: fabrication of multicompartment nanofibers by the electrospinning of organic or/and inorganic dispersions and emulsions. Macromol Rapid Commun 33:1978–1995
Agarwal S, Greiner A, Wendorff JH (2013) Functional materials by electrospinning of polymers. Progr Polym Sci 38:963–991
Ramakrishna S, Fujihara K, Teo W-E, Lim T, Ma Z (2005) An introduction to electrospinning and nanofibers. World Scientific, Singapore
Zucchelli A, Focarete ML, Gualandi C, Ramakrishna S (2010) Electrospun nanofibers for enhancing structural performance of composite materials. Polym Adv Technol 22:339–349
Bianco A, Bozzo BM, Del Gaudio C, Cacciotti I, Armentano I, Dottori M, D’Angelo F, Martino S, Orlacchio A, Kenny JM (2011) Poly (l-lactic acid)/calcium-deficient nanohydroxyapatite electrospun mats for bone marrow stem cell cultures. J Bioactive Compatible Polym 26:225–241
Lu X, Liu X, Wang L, Zhang W, Wang C (2006) Fabrication of luminescent hybrid fibres based on the encapsulation of polyoxometalate into polymer matrices. Nanotechnology 17:3048–3053
Li Z, Huang H, Wang C (2006) Electrostatic forces induce poly(vinyl alcohol)-protected copper nanoparticles to form copper/poly(vinyl alcohol) nanocables via electrospinning. Macromol Rapid Commun 27:152–155
Li M, Zhang J, Zhang H, Liu Y, Wang C, Xu X, Tang Y, Yang B (2007) Electrospinning: a facile method to disperse fluorescent quantum dots in nanofibers without forster resonance energy transfer. Adv Funct Mater 17:3650–3656
Cho D, Bae WJ, Joo YL, Ober CK, Frey MW (2011) Properties of PVA/HfO2 hybrid electrospun fibers and calcined inorganic HfO2 fibers. J Phys Chem C 115:5535–5544
He D, Hu B, Yao QF, Wang K, Yu SH (2009) Large-scale synthesis of flexible free-standing sers substrates with high sensitivity: electrospun PVA nanofibers embedded with controlled alignment of silver nanoparticles. ACS Nano 3:3993–4002
Zhang CL, Lv KP, Cong HP, Yu SH (2012) Controlled assemblies of gold nanorods in PVA nanofiber matrix as flexible free-standing SERS substrates by electrospinning. Small 8:648–653
Cheng M, Wang H, Zhang Z, Li N, Fang X, Xu S (2014) Gold nanorod-embedded electrospun fibrous membrane as a photothermal therapy platform. ACS Appl Mater Interfaces 6:1569–1575
Wang Y, Li Y, Sun G, Zhang G, Liu H, Du J, Yang S, Bai J, Yang Q (2007) Fabrication of Au/PVP nanofiber composites by electrospinning. J Appl Polym Sci 105:3618–3622
Kriha O, Becker M, Lehmann M, Kriha D, Krieglstein J, Yosef M, Schlecht S, Wehrspohn RB, Wendorff JH, Greiner A (2007) Connection of hippocampal neurons by magnetically controlled movement of short electrospun polymer fibers – a route to magnetic micromanipulators. Adv Mater 19:2483–2485
Wang N, Si Y, Wang N, Sun G, El-Newehy M, Al-Deyab SS, Ding B (2014) Multilevel structured polyacrylonitrile/silica nanofibrous membranes for high-performance air filtration. Separation Purification Technol 126:44–51
Kim YJ, Ahn CH, Lee MB, Choi MS (2011) Characteristics of electrospun PVDF/SiO2 composite nanofiber membranes as polymer electrolyte. Mater Chem Phys 127:137–142
Hsu CY, Liu YL (2010) Rhodamine B-anchored silica nanoparticles displaying white-light photoluminescence and their uses in preparations of photoluminescent polymeric films and nanofibers. J Colloid Interface Sci 350:75–82
Jin Y, Yang D, Kang D, Jiang X (2009) Fabrication of necklace-like structures via electrospinning. Langmuir 26:1186–1190
Wan H, Wang N, Yang J, Si Y, Chen K, Ding B, Sun G, El-Newehy M, Al-Deyab SS, Yu J (2014) Hierarchically structured polysulfone/titania fibrous membranes with enhanced air filtration performance. J Colloid Interface Sci 417:18–26
Cui WW, Tang DY, Gong ZL (2013) Electrospun poly(vinylidene fluoride)/poly(methyl methacrylate) grafted TiO2 composite nanofibrous membrane as polymer electrolyte for lithium-ion batteries. J Power Sources 223:206–213
Gupta KK, Kundan A, Mishra PK, Srivastava P, Mohanty S, Singh NK, Mishra A, Maiti P (2012) Polycaprolactone composites with TiO2 for potential nanobiomaterials: tunable properties using different phases. Phys Chem Chem Phys 14:12844–12853
Ahmadpoor P, Nateri AS, Motaghitalab V (2013) The optical properties of PVA/TiO2 composite nanofibers. J Appl Polym Sci 130:78–85
Xin Y, Huang ZH, Peng L, Wang DJ (2009) Photoelectric performance of poly(p-phenylene vinylene)/Fe3O4 nanofiber array. J Appl Phys 105:086106
Tan ST, Wendorff JH, Pietzonka C, Jia ZH, Wang GQ (2005) Biocompatible and biodegradable polymer nanofibers displaying superparamagnetic properties. ChemPhysChem 6:1461–1465
Gupta P, Asmatulu R, Claus R, Wilkes G (2006) Superparamagnetic flexible substrates based on submicron electrospun Estane® fibers containing MnZnFe-Ni nanoparticles. J Appl Polym Sci 100:4935–4942
Andrew JS, Clarke DR (2008) Enhanced ferroelectric phase content of polyvinylidene difluoride fibers with the addition of magnetic nanoparticles. Langmuir 24:8435–8438
Sui X, Shao C, Liu Y (2007) Photoluminescence of polyethylene oxide-ZnO composite electrospun fibers. Polymer 48:1459–1463
Sui XM, Shao CL, Liu YC (2005) White-light emission of polyvinyl alcohol/ZnO hybrid nanofibers prepared by electrospinning. Appl Phys Lett 87:113115
Lee S (2009) Multifunctionality of layered fabric systems based on electrospun polyurethane/zinc oxide nanocomposite fibers. J Appl Polym Sci 114:3652–3658
Modisha P, Nyokong T (2014) Fabrication of phthalocyanine-magnetic nanoparticles hybrid nanofibers for degradation of Orange-G. J Mol Catal A Chem 381:132–137
Tombe S, Antunes E, Nyokong T (2013) Electrospun fibers functionalized with phthalocyanine-gold nanoparticle conjugates for photocatalytic applications. J Mol Catal A Chem 371:125–134
Sundarrajan S, Ramakrishna S (2007) Fabrication of nanocomposite membranes from nanofibers and nanoparticles for protection against chemical warfare stimulants. J Mater Sci 42:8400–8407
Lee YS, Jeong YB, Kim DW (2010) Cycling performance of lithium-ion batteries assembled with a hybrid composite membrane prepared by an electrospinning method. J Power Sources 195:6197–6201
Padmaraj O, Nageswara Rao B, Jena P, Venkateswarlu M, Satyanarayana N (2014) Electrochemical studies of electrospun organic/inorganic hybrid nanocomposite fibrous polymer electrolyte for lithium battery. Polymer 55:1136–1142
Im JS, Bai BC, Bae TS, In SJ, Lee YS (2011) Improved anti-oxidation properties of electrospun polyurethane nanofibers achieved by oxyfluorinated multi-walled carbon nanotubes and aluminum hydroxide. Mater Chem Phys 126:685–692
Li S, Li Y, Qian K, Ji S, Luo H, Gao Y, Jin P (2013) Functional fiber mats with tunable diffuse reflectance composed of electrospun VO2/PVP composite fibers. ACS Appl Mater Interfaces 6:9–13
Chinnappan A, Kang HC, Kim H (2011) Preparation of PVDF nanofiber composites for hydrogen generation from sodium borohydride. Energy 36:755–759
Abiona AA, Ajao JA, Chigome S, Kana JB, Osinkolu GA, Maaza M (2010) Synthesis and characterization of cobalt chloride/poly(ethylene oxide) electrospun hybrid nanofibers. J Sol Gel Sci Technol 55:235–241
Unnithan AR, Barakat NAM, Abadir MF, Yousef A, Kim HY (2012) Novel CdPdS/PVAc core-shell nanofibers as an effective photocatalyst for organic pollutants degradation. J Mol Catal A Chem 363–364:186–194
Wang Q, Chen Y, Liu R, Liu H, Li Z (2012) Fabrication and characterization of electrospun CdS-OH/polyacrylonitrile hybrid nanofibers. Compos Part A Appl Sci Manuf 43:1869–1876
Dhandayuthapani B, Poulose AC, Nagaoka Y, Hasumura T, Yoshida Y, Maekawa T, Kumar DS (2012) Biomimetic smart nanocomposite: in vitro biological evaluation of zein electrospun fluorescent nanofiber encapsulated CdS quantum dots. Biofabrication 4:025008
Bashouti M, Salalha W, Brumer M, Zussman E, Lifshitz E (2006) Alignment of colloidal cds nanowires embedded in polymer nanofibers by electrospinning. ChemPhysChem 7:102–106
Mthethwa TP, Moloto MJ, De Vries A, Matabola KP (2011) Properties of electrospun CdS and CdSe filled poly(methyl methacrylate) (PMMA) nanofibres. Mater Res Bull 46:569–575
Atabey E, Wei S, Zhang X, Gu H, Yan X, Huang Y, Shao L, He Q, Zhu J, Sun L, Kucknoor AS, Wang A, Guo Z (2013) Fluorescent electrospun polyvinyl alcohol/CdSe@ZnS nanocomposite fibers. J Compos Mater 47:3175–3185
Cho K, Kim M, Choi J, Kim K, Kim S (2010) Synthesis and characterization of electrospun polymer nanofibers incorporated with CdTe nanoparticles. Synthetic Met 160:888–891
Wang S, Sun Z, Yan E, Sun L, Huang N, Zang W, Ni L, Wang Q, Gao Y (2014) Spectrum-control of poly(p-phenylene vinylene) nanofibers fabricated by electrospinning with highly photoluminescent ZnS quantum dots. Int J Electrochem Sci 9:549–561
Schlecht S, Tan S, Yosef M, Dersch R, Wendorff JH, Jia Z, Schaper A (2005) Toward linear arrays of quantum dots via polymer nanofibers and nanorods. Chem Mater 17:809–814
Li M, Zhang Z, Cao T, Sun Y, Liang P, Shao C, Liu Y (2012) Electrospinning preparation and photoluminescence properties of poly(methyl methacrylate)/Eu3+ ions composite nanofibers and nanoribbons. Mater Res Bull 47:321–327
Tang S, Shao C, Liu Y, Mu R (2010) Electrospun nanofibers of poly(acrylonitrile)/Eu3+ and their photoluminescence properties. J Phys Chem Solids 71:273–278
Wang H, Yang Q, Sun L, Zhang C, Li Y, Wang S, Li Y (2009) Improved photoluminescence properties of europium complex/polyacrylonitrile composite fibers prepared by electrospinning. J Alloys Comp 488:414–419
Liu L, Li B, Zhang J, Qin R, Zhao H, Ren X (2009) Electrospinning preparation and characterization of a new kind of composite nanomaterials: one-dimensional composite nanofibers doped with TiO2 nanoparticles and Ru(II) complex. Mater Res Bull 44:2081–2086
Wang H, Li Y, Sun L, Li Y, Wang W, Wang S, Xu S, Yang Q (2010) Electrospun novel bifunctional magnetic-photoluminescent nanofibers based on Fe2O3 nanoparticles and europium complex. J Colloid Interface Sci 350:396–401
Zhang H, Song H, Yu H, Bai X, Li S, Pan G, Dai Q, Wang T, Li W, Lu S, Ren X, Zhao H (2007) Electrospinning preparation and photoluminescence properties of rare-earth complex/polymer composite fibers. J Phys Chem C 111:6524–6527
Hong JH, Jeong EH, Lee HS, Baik DH, Seo SW, Youk JH (2005) Electrospinning of polyurethane/organically modified montmorillonite nanocomposites. J Polym Sci B Polym Phys 43:3171–3177
Marras SI, Kladi KP, Tsivintzelis I, Zuburtikudis I, Panayiotou C (2008) Biodegradable polymer nanocomposites: the role of nanoclays on the thermomechanical characteristics and the electrospun fibrous structure. Acta Biomaterialia 4:756–765
Park J, Lee H, Chae D, Oh W, Yun J, Deng Y, Yeum J (2009) Electrospinning and characterization of poly(vinyl alcohol)/chitosan oligosaccharide/clay nanocomposite nanofibers in aqueous solutions. Colloid Polym Sci 287:943–950
Wang S, Zheng F, Huang Y, Fang Y, Shen M, Zhu M, Shi X (2012) Encapsulation of amoxicillin within laponite-doped poly(lactic-co-glycolic acid) nanofibers: preparation, characterization, and antibacterial activity. ACS Appl Mater Interfaces 4:6393–6401
Deng XL, Sui G, Zhao ML, Chen CQ, Yang XP (2007) Poly(l-lactic acid)/hydroxyapatite hybrid nanofibrous scaffolds prepared by electrospinning. J Biomater Sci Polym Ed 18:117–130
Jeong SI, Ko EK, Yum J, Jung CH, Lee YM, Shin H (2008) Nanofibrous poly(lactic acid)/hydroxyapatite composite scaffolds for guided tissue regeneration. Macromol Biosci 8:328–338
Sui G, Yang X, Mei F, Hu X, Chen G, Deng X, Ryu S (2007) Poly-l-lactic acid/hydroxyapatite hybrid membrane for bone tissue regeneration. J Biomed Mater Res Part A 82A:445–454
Kutikov AB, Song J (2013) An amphiphilic degradable polymer/hydroxyapatite composite with enhanced handling characteristics promotes osteogenic gene expression in bone marrow stromal cells. Acta Biomaterialia 9:8354–8364
Shen K, Hu Q, Chen L, Shen J (2010) Preparation of chitosan bicomponent nanofibers filled with hydroxyapatite nanoparticles via electrospinning. J Appl Polym Sci 115:2683–2690
Teng SH, Lee EJ, Wang P, Kim HE (2008) Collagen/hydroxyapatite composite nanofibers by electrospinning. Mater Lett 62:3055–3058
Stanishevsky A, Chowdhury S, Chinoda P, Thomas V (2008) Hydroxyapatite nanoparticle loaded collagen fiber composites: microarchitecture and nanoindentation study. J Biomed Mater Res Part A 86A:873–882
Yang D, Jin Y, Ma G, Chen X, Lu F, Nie J (2008) Fabrication and characterization of chitosan/PVA with hydroxyapatite biocomposite nanoscaffolds. J Appl Polym Sci 110:3328–3335
Ba Linh NT, Min YK, Lee BT (2013) Hybrid hydroxyapatite nanoparticles-loaded PCL/GE blend fibers for bone tissue engineering. J Biomater Sci Polym Ed 24:520–538
Bianco A, Di Federico E, Cacciotti I (2011) Electrospun poly(e-caprolactone)-based composites using synthesized b-tricalcium phosphate. Polym Adv Technol 22:1832–1841
Fujihara K, Kotaki M, Ramakrishna S (2005) Guided bone regeneration membrane made of polycaprolactone/calcium carbonate composite nano-fibers. Biomaterials 26:4139–4147
Hang AT, Tae B, Park JS (2010) Non-woven mats of poly(vinyl alcohol)/chitosan blends containing silver nanoparticles: fabrication and characterization. Carbohydr Polym 82:472–479
Abdelgawad AM, Hudson SM, Rojas OJ (2014) Antimicrobial wound dressing nanofiber mats from multicomponent (chitosan/silver-NPs/polyvinyl alcohol) systems. Carbohydr Polym 100:166–178
Jin WJ, Lee HK, Jeong EH, Park WH, Youk JH (2005) Preparation of polymer nanofibers containing silver nanoparticles by using poly(N-vinylpyrrolidone). Macromol Rapid Commun 26:1903–1907
Faridi-Majidi R, Sharifi-Sanjani N (2007) In situ synthesis of iron oxide nanoparticles on poly(ethylene oxide) nanofibers through an electrospinning process. J Appl Polym Sci 105:1351–1355
Wang Y, Li Y, Yang S, Zhang G, An D, Wang C, Yang Q, Chen X, Wei Y (2006) A convenient route to polyvinyl pyrrolidone/silver nanocomposite by electrospinning. Nanotechnology 17:3304–3307
Saquing CD, Manasco JL, Khan SA (2009) Electrospun nanoparticle-nanofiber composites via a one-step synthesis. Small 5:944–951
Tijing LD, Ruelo MT, Amarjargal A, Pant HR, Park CH, Kim CS (2012) One-step fabrication of antibacterial (silver nanoparticles/poly(ethylene oxide))-polyurethane bicomponent hybrid nanofibrous mat by dual-spinneret electrospinning. Mater Chem Phys 134:557–561
An J, Zhang H, Zhang J, Zhao Y, Yuan X (2009) Preparation and antibacterial activity of electrospun chitosan/poly(ethylene oxide) membranes containing silver nanoparticles. Colloid Polym Sci 287:1425–1434
Shi Q, Vitchuli N, Nowak J, Noar J, Caldwell JM, Breidt F, Bourham M, McCord M, Zhang X (2011) One-step synthesis of silver nanoparticle-filled nylon 6 nanofibers and their antibacterial properties. J Mater Chem 21:10330–10335
Penchev H, Paneva D, Manolova N, Rashkov I (2009) Electrospun hybrid nanofibers based on chitosan or N-carboxyethylchitosan and silver nanoparticles. Macromol Biosci 9:884–894
Shi Q, Vitchuli N, Nowak J, Caldwell JM, Breidt F, Bourham M, Zhang X, McCord M (2011) Durable antibacterial Ag/polyacrylonitrile (Ag/PAN) hybrid nanofibers prepared by atmospheric plasma treatment and electrospinning. Eur Polym J 47:1402–1409
Celebioglu A, Aytac Z, Umu OCO, Dana A, Tekinay T, Uyar T (2014) One-step synthesis of size-tunable Ag nanoparticles incorporated in electrospun PVA/cyclodextrin nanofibers. Carbohydr Polym 99:808–816
Lu X, Li L, Zhang W, Wang C (2005) Preparation and characterization of Ag2S nanoparticles embedded in polymer fibre matrices by electrospinning. Nanotechnology 16:2233–2237
Afeesh R, Barakat NAM, Al-Deyab SS, Yousef A, Kim HY (2012) Nematic shaped cadmium sulfide doped electrospun nanofiber mat: highly efficient, reusable, solar light photocatalyst. Colloids Surf A Physicochem Eng Asp 409:21–29
Wang S, Wang C, Zhang B, Sun Z, Li Z, Jiang X, Bai X (2010) Preparation of Fe3O4/PVA nanofibers via combining in-situ composite with electrospinning. Mat Lett 64:9–11
Deniz AE, Vural HA, Ortac B, Uyar T (2011) Gold nanoparticle/polymer nanofibrous composites by laser ablation and electrospinning. Mat Lett 65:2941–2943
Zhuang X, Cheng B, Kang W, Xu X (2010) Electrospun chitosan/gelatin nanofibers containing silver nanoparticles. Carbohydr Polym 82:524–527
Li L, Bellan LM, Craighead HG, Frey MW (2006) Formation and properties of nylon-6 and nylon-6/montmorillonite composite nanofibers. Polymer 47:6208–6217
Fong H, Liu W, Wang CS, Vaia RA (2002) Generation of electrospun fibers of nylon 6 and nylon 6-montmorillonite nanocomposite. Polymer 43:775–780
Zhang Y, Venugopal JR, El-Turki A, Ramakrishna S, Su B, Lim CT (2008) Electrospun biomimetic nanocomposite nanofibers of hydroxyapatite/chitosan for bone tissue engineering. Biomaterials 29:4314–4322
Song JH, Kim HE, Kim HW (2008) Electrospun fibrous web of collagen-apatite precipitated nanocomposite for bone regeneration. J Mater Sci Mater Med 19:2925–2932
Kim HW, Song JH, Kim HE (2005) Nanofiber generation of gelatin-hydroxyapatite biomimetics for guided tissue regeneration. Adv Funct Mater 15:1988–1994
Kim GM, Wutzler A, Radusch HJ, Michler GH, Simon P, Sperling RA, Parak WJ (2005) One-dimensional arrangement of gold nanoparticles by electrospinning. Chem Mater 17:4949–4957
Drew C, Liu X, Ziegler D, Wang X, Bruno FF, Whitten J, Samuelson LA, Kumar J (2003) Metal oxide-coated polymer nanofibers. Nano Lett 3:143–147
Niesen TP, De Guire MR (2002) Review: deposition of ceramic thin films at low temperatures from aqueous solutions. Solid State Ionics 151:61–68
George SM, Ott AW, Klaus JW (1996) Surface chemistry for atomic layer growth. J Phys Chem 100:13121–13131
Oldham CJ, Gong B, Spagnola JC, Jur JS, Senecal KJ, Godfrey TA, Parsons GN (2011) Encapsulation and chemical resistance of electrospun nylon nanofibers coated using integrated atomic and molecular layer deposition. J Electrochem Soc 158:D549–D556
Kayaci F, Ozgit-Akgun C, Donmez I, Biyikli N, Uyar T (2012) Polymer–inorganic core–shell nanofibers by electrospinning and atomic layer deposition: flexible Nylon–ZnO core–shell nanofiber mats and their photocatalytic activity. ACS Appl Mater Interfaces 4:6185–6194
Shi W, Song S, Zhang H (2013) Hydrothermal synthetic strategies of inorganic semiconducting nanostructures. Chem Soc Rev 42:5714–5743
He T, Zhou Z, Xu W, Ren F, Ma H, Wang J (2009) Preparation and photocatalysis of TiO2-fluoropolymer electrospun fiber nanocomposites. Polymer 50:3031–3036
Chang Z (2011) “Firecracker-shaped” ZnO/polyimide hybrid nanofibers viaelectrospinning and hydrothermal process. Chem Commun 47:4427–4429
Kim HJ, Pant HR, Amarjargal A, Kim CS (2013) Incorporation of silver-loaded ZnO rods into electrospun nylon-6 spider-web-like nanofibrous mat using hydrothermal process. Colloids Surf A Physicochem Eng Asp 434:49–55
Xiao S, Shen M, Guo R, Wang S, Shi X (2009) Immobilization of zerovalent iron nanoparticles into electrospun polymer nanofibers: synthesis, characterization, and potential environmental applications. J Phys Chem C 113:18062–18068
Xiao S, Shen M, Guo R, Huang Q, Wang S, Shi X (2010) Fabrication of multiwalled carbon nanotube-reinforced electrospun polymer nanofibers containing zero-valent iron nanoparticles for environmental applications. J Mater Chem 20:5700–5708
Xiao S, Xu W, Ma H, Fang X (2012) Size-tunable Ag nanoparticles immobilized in electrospun nanofibers: synthesis, characterization, and application for catalytic reduction of 4-nitrophenol. RSC Adv 2:319–327
Dong H, Fey E, Gandelman A, Jones WE (2006) Synthesis and assembly of metal nanoparticles on electrospun poly(4-vinylpyridine) fibers and poly(4-vinylpyridine) composite fibers. Chem Mater 18:2008–2011
Fang X, Ma H, Xiao S, Shen M, Guo R, Cao X, Shi X (2011) Facile immobilization of gold nanoparticles into electrospun polyethyleneimine/polyvinyl alcohol nanofibers for catalytic applications. J Mater Chem 21:4493–4501
Gardella L, Basso A, Prato M, Monticelli O (2013) PLA/POSS nanofibers: a novel system for the immobilization of metal nanoparticles. ACS Appl Mater Interfaces 5:7688–7692
Liu Z, Zhou C, Zheng B, Qian L, Mo Y, Luo F, Shi Y, Choi MMF, Xiao D (2011) In situ synthesis of gold nanoparticles on porous polyacrylonitrile nanofibers for sensing applications. Analyst 136:4545–4551
Son HY, Ryu JH, Lee H, Nam YS (2013) Bioinspired templating synthesis of metal–polymer hybrid nanostructures within 3D electrospun nanofibers. ACS Appl Mater Interfaces 5:6381–6390
Demir MM, Gulgun MA, Menceloglu YZ, Erman B, Abramchuk SS, Makhaeva EE, Khokhlov AR, Matveeva VG, Sulman MG (2004) Palladium nanoparticles by electrospinning from poly(acrylonitrile-co-acrylic acid)-PdCl2 solutions. Relations between preparation conditions, particle size, and catalytic activity. Macromolecules 37:1787–1792
Han GY, Guo B, Zhang LW, Yang BS (2006) Conductive gold films assembled on electrospun poly(methyl methacrylate) fibrous mats. Adv Mater 18:1709–1712
Son WK, Youk JH, Lee TS, Park WH (2004) Preparation of antimicrobial ultrafine cellulose acetate fibers with silver nanoparticles. Macromol Rapid Commun 25:1632–1637
Li Z, Huang H, Shang T, Yang F, Zheng W, Wang C, Manohar S (2006) Facile synthesis of single-crystal and controllable sized silver nanoparticles on the surfaces of polyacrylonitrile nanofibres. Nanotechnology 17:917
Lu X, Zhao Y, Wang C, Wei Y (2005) Fabrication of CdS nanorods in PVP fiber matrices by electrospinning. Macromol Rapid Commun 26:1325–1329
Lu X, Zhao Y, Wang C (2005) Fabrication of PbS nanoparticles in polymer-fiber matrices by electrospinning. Adv Mater 17:2485–2488
Dong F, Li Z, Huang H, Yang F, Zheng W, Wang C (2007) Fabrication of semiconductor nanostructures on the outer surfaces of polyacrylonitrile nanofibers by in-situ electrospinning. Mater Lett 61:2556–2559
Wang H, Lu X, Zhao Y, Wang C (2006) Preparation and characterization of ZnS:Cu/PVA composite nanofibers via electrospinning. Mater Lett 60:2480–2484
Wang C, Yan E, Sun Z, Jiang Z, Tong Y, Xin Y, Huang Z (2007) Mass ratio of CdS/poly(ethylene oxide) controlled photoluminescence of one-dimensional hybrid fibers by electrospinning. Macromol Mater Eng 292:949–955
Ye J, Chen Y, Zhou W, Wang X, Guo Z, Hu Y (2009) Preparation of polymer@PbS hybrid nanofibers by surface-initiated atom transfer radical polymerization and acidolysis by H2S. Mater Lett 63:1425–1427
Ariga K, Hill JP, Ji Q (2007) Layer-by-layer assembly as a versatile bottom-up nanofabrication technique for exploratory research and realistic application. Phys Chem Chem Phys 9:2319–2340
Ding B, Kim J, Kimura E, Shiratori S (2004) Layer-by-layer structured films of TiO2 nanoparticles and poly(acrylic acid) on electrospun nanofibres. Nanotechnology 15:913
Muller K, Quinn JF, Johnston APR, Becker M, Greiner A, Caruso F (2006) Polyelectrolyte functionalization of electrospun fibers. Chem Mater 18:2397–2403
Lee JA, Krogman KC, Ma M, Hill RM, Hammond PT, Rutledge GC (2009) Highly reactive multilayer-assembled TiO2 coating on electrospun polymer nanofibers. Adv Mater 21:1252–1256
Xiao S, Wu S, Shen M, Guo R, Huang Q, Wang S, Shi X (2009) Polyelectrolyte multilayer-assisted immobilization of zero-valent iron nanoparticles onto polymer nanofibers for potential environmental applications. ACS Appl Mater Interfaces 1:2848–2855
Lu X, Zhao Q, Liu X, Wang D, Zhang W, Wang C, Wei Y (2006) Preparation and characterization of polypyrrole/TiO2 coaxial nanocables. Macromol Rapid Commun 27:430–434
Li Y, Gong J, He G, Deng Y (2011) Fabrication of polyaniline/titanium dioxide composite nanofibers for gas sensing application. Mater Chem Phys 129:477–482
Zampetti E, Macagnano A, Pantalei S, Bearzotti A (2013) PEDOT:PSS coated titania nanofibers for NO2 detection: study of humidity effects. Sensor Actuator B Chem 179:69–73
Kickelbick G (2003) Concepts for the incorporation of inorganic building blocks into organic polymers on a nanoscale. Progr Polym Sci 28:83–114
Sanchez C, Julian B, Belleville P, Popall M (2005) Applications of hybrid organic–inorganic nanocomposites. J Mater Chem 15:3559–3592
Wen J, Wilkes GL (1996) Organic/inorganic hybrid network materials by the sol–gel approach. Chem Mater 8:1667–1681
Hench LL, West JK (1990) The sol–gel process. Chem Rev 90:33–72
Larsen G, Velarde-Ortiz R, Minchow K, Barrero A, Loscertales IG (2003) A method for making inorganic and hybrid (organic/inorganic) fibers and vesicles with diameters in the submicrometer and micrometer range via sol–gel chemistry and electrically forced liquid jets. J Am Chem Soc 125:1154–1155
Kim ID, Rothschild A (2011) Nanostructured metal oxide gas sensors prepared by electrospinning. Polym Adv Technol 22:318–325
Lu X, Wang C, Wei Y (2009) One-dimensional composite nanomaterials: synthesis by electrospinning and their applications. Small 5:2349–2370
Wu H, Pan W, Lin D, Li H (2012) Electrospinning of ceramic nanofibers: fabrication, assembly and applications. J Adv Ceram 1:2–23
Pirzada T, Arvidson SA, Saquing CD, Shah SS, Khan SA (2012) Hybrid silica-PVA nanofibers via sol–gel electrospinning. Langmuir 28:5834–5844
Jang TS, Lee EJ, Jo JH, Jeon JM, Kim MY, Kim HE, Koh YH (2012) Fibrous membrane of nano-hybrid poly-l-lactic acid/silica xerogel for guided bone regeneration. J Biomed Mater Res 100B:321–330
Lee EJ, Teng SH, Jang TS, Wang P, Yook SW, Kim HE, Koh YH (2010) Nanostructured poly(e-caprolactone)-silica xerogel fibrous membrane for guided bone regeneration. Acta Biomaterialia 6:3557–3565
Shao C, Kim HY, Gong J, Ding B, Lee DR, Park SJ (2003) Fiber mats of poly(vinyl alcohol)/silica composite via electrospinning. Mater Lett 57:1579–1584
Tong HW, Mutlu BR, Wackett LP, Aksan A (2013) Silica/PVA biocatalytic nanofibers. Mater Lett 111:234–237
Allo BA, Rizkalla AS, Mequanint K (2010) Synthesis and electrospinning of e-polycaprolactone-bioactive glass hybrid biomaterials via a sol–gel process. Langmuir 26:18340–18348
Rawolle M, Niedermeier MA, Kaune G, Perlich J, Lellig P, Memesa M, Cheng YJ, Gutmann JS, Muller-Buschbaum P (2012) Fabrication and characterization of nanostructured titania films with integrated function from inorganic–organic hybrid materials. Chem Soc Rev 41:5131–5142
Gaya UI, Abdullah AH (2008) Heterogeneous photocatalytic degradation of organic contaminants over titanium dioxide: a review of fundamentals, progress and problems. J Photochem Photobiol C Photochem Rev 9:1–12
Wu N, Shao D, Wei Q, Cai Y, Gao W (2009) Characterization of PVAc/TiO2 hybrid nanofibers: from fibrous morphologies to molecular structures. J Appl Polym Sci 112:1481–1485
Larsen G, Skotak M (2008) Co-solvent mediated fiber diameter and fiber morphology control in electrospinning of sol–gel formulations. J Non Crystal Solids 354:5547–5554
Skotak M, Larsen G (2006) Solution chemistry control to make well defined submicron continuous fibres by electrospinning: the (CH3CH2CH2O)4Ti/AcOH/poly(N-vinylpyrrolidone) system. J Mater Chem 16:3031–3039
Wu N, Chen L, Wei Q, Liu Q, Li J (2011) Nanoscale three-point bending of single polymer/inorganic composite nanofiber. J Text Inst 103:154–158
Hong Y, Li D, Zheng J, Zou G (2006) Sol–gel growth of titania from electrospun polyacrylonitrile nanofibres. Nanotechnology 17:1986
Meng X, Luo N, Cao S, Zhang S, Yang M, Hu X (2009) In-situ growth of titania nanoparticles in electrospun polymer nanofibers at low temperature. Mater Lett 63:1401–1403
Su C, Tong Y, Zhang M, Zhang Y, Shao C (2013) TiO2 nanoparticles immobilized on polyacrylonitrile nanofibers mats: a flexible and recyclable photocatalyst for phenol degradation. RSC Adv 3:7503–7512
Arafat MM, Dinan B, Akbar SA, Haseeb SMA (2012) Gas sensors based on one dimensional nanostructured metal-oxides: a review. Sensors 12:7207–7258
Udom I, Ram MK, Stefanakos EK, Hepp AF, Goswami DY (2013) One dimensional-ZnO nanostructures: synthesis, properties and environmental applications. Mater Sci Semicond Process 16:2070–2083
Znaidi L (2010) Sol–gel-deposited ZnO thin films: a review. Mater Sci Eng B 174:18–30
Liu H, Yang J, Liang J, Huang Y, Tang C (2008) ZnO nanofiber and nanoparticle synthesized through electrospinning and their photocatalytic activity under visible light. J Am Ceram Soc 91:1287–1291
Yang X, Shao C, Guan H, Li X, Gong J (2004) Preparation and characterization of ZnO nanofibers by using electrospun PVA/zinc acetate composite fiber as precursor. Inorg Chem Commun 7:176–178
Wu H, Pan W (2006) Preparation of zinc oxide nanofibers by electrospinning. J Am Ceram Soc 89:699–701
Hong Y, Li D, Zheng J, Zou G (2006) In situ growth of ZnO nanocrystals from solid electrospun nanofiber matrixes. Langmuir 22:7331–7334
Ye S, Zhang D, Liu H, Zhou J (2011) ZnO nanocrystallites/cellulose hybrid nanofibers fabricated by electrospinning and solvothermal techniques and their photocatalytic activity. J Appl Polym Sci 121:1757–1764
Zhang J, Wen B, Wang F, Ding Y, Zhang S, Yang M (2011) In situ synthesis of ZnO nanocrystal/PET hybrid nanofibers via electrospinning. J Polym Sci B Polym Phys 49:1360–1368
Park SH, Lee SM, Lim HS, Han JT, Lee DR, Shin HS, Jeong Y, Kim J, Cho JH (2010) Robust superhydrophobic mats based on electrospun crystalline nanofibers combined with a silane precursor. ACS Appl Mater Interfaces 2:658–662
Song JH, Yoon BH, Kim HE, Kim HW (2008) Bioactive and degradable hybridized nanofibers of gelatin-siloxane for bone regeneration. J Biomed Mater Res Part A 84A:875–884
Ren L, Wang J, Yang FY, Wang L, Wang D, Wang TX, Tian MM (2010) Fabrication of gelatin-siloxane fibrous mats via sol–gel and electrospinning procedure and its application for bone tissue engineering. Mat Sci Eng C 30:437–444
Gao C, Gao Q, Li Y, Rahaman MN, Teramoto A, Abe K (2013) In vitro evaluation of electrospun gelatin-bioactive glass hybrid scaffolds for bone regeneration. J Appl Polym Sci 127:2588–2599
Toskas G, Cherif C, Hund RD, Laourine E, Mahltig B, Fahmi A, Heinemann C, Hanke T (2013) Chitosan(PEO)/silica hybrid nanofibers as a potential biomaterial for bone regeneration. Carbohydr Polym 94:713–722
Allo BA, Lin S, Mequanint K, Rizkalla AS (2013) Role of bioactive 3D hybrid fibrous scaffolds on mechanical behavior and spatiotemporal osteoblast gene expression. ACS Appl Mater Interfaces 5:7574–7583
Poologasundarampillai G, Yu B, Jones JR, Kasuga T (2011) Electrospun silica/PLLA hybrid materials for skeletal regeneration. Soft Matter 7:10241–10251
Taha AA, Yn W, Wang H, Li F (2012) Preparation and application of functionalized cellulose acetate/silica composite nanofibrous membrane via electrospinning for Cr(VI) ion removal from aqueous solution. J Environ Manag 112:10–16
Xu R, Jia M, Zhang Y, Li F (2012) Sorption of malachite green on vinyl-modified mesoporous poly(acrylic acid)/SiO2 composite nanofiber membranes. Microporous Mesoporous Mater 149:111–118
Xu R, Jia M, Li F, Wang H, Zhang B, Qiao J (2012) Preparation of mesoporous poly (acrylic acid)/SiO2 composite nanofiber membranes having adsorption capacity for indigo carmine dye. Appl Phys A 106:747–755
Teng M, Wang H, Li F, Zhang B (2011) Thioether-functionalized mesoporous fiber membranes: sol–gel combined electrospun fabrication and their applications for Hg2+ removal. J Colloid Interface Sci 355:23–28
Teng M, Li F, Zhang B, Taha AA (2011) Electrospun cyclodextrin-functionalized mesoporous polyvinyl alcohol/SiO2 nanofiber membranes as a highly efficient adsorbent for indigo carmine dye. Colloids Surf A Physicochem Eng Asp 385:229–234
Wu S, Li F, Wu Y, Xu R, Li G (2010) Preparation of novel poly(vinyl alcohol)/SiO2 composite nanofiber membranes with mesostructure and their application for removal of Cu2+ from waste water. Chem Commun 46:1694–1696
Yan L, Si S, Chen Y, Yuan T, Fan H, Yao Y, Zhang Q (2011) Electrospun in-situ hybrid polyurethane/nano-TiO2 as wound dressings. Fibers Polym 12:207–213
Gupta KK, Mishra PK, Srivastava P, Gangwar M, Nath G, Maiti P (2013) Hydrothermal in situ preparation of TiO2 particles onto poly(lactic acid) electrospun nanofibres. Appl Surface Sci 264:375–382
Vitchuli N, Shi Q, Nowak J, Kay K, Caldwell JM, Breidt F, Bourham M, McCord M, Zhang X (2011) Multifunctional ZnO/Nylon-6 nanofiber mats by an electrospinning-electrospraying hybrid process for use in protective applications. Sci Technol Adv Mater 12:055004
Korina E, Stoilova O, Manolova N, Rashkov I (2014) Poly(3-hydroxybutyrate)-based hybrid materials with photocatalytic and magnetic properties prepared by electrospinning and electrospraying. J Mater Sci 49:2144–2153
Lee MW, An S, Joshi B, Latthe SS, Yoon SS (2013) Highly efficient wettability control via three-dimensional (3D) suspension of titania nanoparticles in polystyrene nanofibers. ACS Appl Mater Interfaces 5:1232–1239
Gupta D, Venugopal J, Mitra S, Giri Dev VR, Ramakrishna S (2009) Nanostructured biocomposite substrates by electrospinning and electrospraying for the mineralization of osteoblasts. Biomaterials 30:2085–2094
Francis L, Venugopal J, Prabhakaran MP, Thavasi V, Marsano E, Ramakrishna S (2010) Simultaneous electrospin-electrosprayed biocomposite nanofibrous scaffolds for bone tissue regeneration. Acta Biomaterialia 6:4100–4109
Loscertales IG, Barrero A, Guerrero I, Cortijo R, Marquez M, Ganan-Calvo AM (2002) Micro/nano encapsulation via electrified coaxial liquid jets. Science 295:1695–1698
Li D, Xia Y (2004) Direct fabrication of composite and ceramic hollow nanofibers by electrospinning. Nano Lett 4:933–938
Kalra V, Mendez S, Lee JH, Nguyen H, Marquez M, Joo YG (2006) Confined assembly in coaxially electrospun block copolymer fibers. Adv Mater 18:3299–3303
Kalra V, Lee J, Lee JH, Lee SG, Marquez M, Wiesner U, Joo YL (2008) Controlling nanoparticle location via confined assembly in electrospun block copolymer nanofibers. Small 4:2067–2073
Song T, Zhang Y, Zhou T, Lim CT, Ramakrishna S, Liu B (2005) Encapsulation of self-assembled FePt magnetic nanoparticles in PCL nanofibers by coaxial electrospinning. Chem Phys Letts 415:317–322
Kim MS, Shin KM, Kim SI, Spinks GM, Kim SJ (2008) Controlled array of ferritin in tubular nanostructure. Macromol Rapid Commun 29:552–556
Sharma N, Hassnain Jaffari G, Ismat Shah S, Pochan DJ (2010) Orientation-dependent magnetic behavior in aligned nanoparticle arrays constructed by coaxial electrospinning. Nanotechnology 21:085707
Sung YK, Ahn BW, Kang TJ (2012) Magnetic nanofibers with core (Fe3O4 nanoparticle suspension)/sheath (poly ethylene terephthalate) structure fabricated by coaxial electrospinning. J Magn Magn Mater 324:916–922
Medina-Castillo AL, Fernandez-Sanchez JF, Fernandez-Gutierrez A (2011) One-step fabrication of multifunctional core-shell fibres by co-electrospinning. Adv Funct Mater 21:3488–3495
Ma Q, Wang J, Dong X, Yu W, Liu G, Xu J (2012) Electrospinning preparation and properties of magnetic-photoluminescent bifunctional coaxial nanofibers. J Mater Chem 22:14438–14442
Bedford NM, Steckl AJ (2010) Photocatalytic self cleaning textile fibers by coaxial electrospinning. ACS Appl Mater Interfaces 2:2448–2455
Yu DG, Zhou J, Chatterton NP, Li Y, Huang J, Wang X (2012) Polyacrylonitrile nanofibers coated with silver nanoparticles using a modified coaxial electrospinning process. Int J Nanomed 7:5725–5732
Allcock HR (2002) Chemistry and applications of polyphosphazenes. Wiley, Hoboken
Nair LS, Bhattacharyya S, Bender JD, Greish YE, Brown PW, Allcock HR, Laurencin CT (2004) Fabrication and optimization of methylphenoxy substituted polyphosphazene nanofibers for biomedical applications. Biomacromolecules 5:2212–2220
Lin YJ, Cai Q, Li L, Li QF, Yang XP, Jin RG (2010) Co-electrospun composite nanofibers of blends of poly[(amino acid ester)phosphazene] and gelatin. Polym Int 59:610–616
Carampin P, Conconi MT, Lora S, Menti AM, Baiguera S, Bellini S, Grandi C, Parnigotto PP (2007) Electrospun polyphosphazene nanofibers for in vitro rat endothelial cells proliferation. J Biomed Mater Res Part A 80A:661–668
Deng M, Kumbar SG, Nair LS, Weikel AL, Allcock HR, Laurencin CT (2011) Biomimetic structures: biological implications of dipeptide-substituted polyphosphazene-polyester blend nanofiber matrices for load-bearing bone regeneration. Adv Funct Mater 21:2641–2651
Qian YC, Ren N, Huang XJ, Chen C, Yu AG, Xu ZK (2013) Glycosylation of polyphosphazene nanofibrous membrane by click chemistry for protein recognition. Macromol Chem Phys 214:1852–1858
Singh A, Steely L, Allcock HR (2005) Poly[bis(2,2,2-trifluoroethoxy)phosphazene] superhydrophobic nanofibers. Langmuir 21:11604–11607
Xu Y, Wen Y, Yn W, Lin C, Li G (2012) Hybrid nanofibrous mats with remarkable solvent and temperature resistance produced by electrospinning technique. Mater Lett 78:139–142
Schramm C, Rinderer B, Tessadri R (2013) Synthesis and characterization of novel ultrathin polyimide fibers via sol–gel process and electrospinning. J Appl Polym Sci 128:1274–1281
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Gualandi, C., Celli, A., Zucchelli, A., Focarete, M.L. (2014). Nanohybrid Materials by Electrospinning. In: Kalia, S., Haldorai, Y. (eds) Organic-Inorganic Hybrid Nanomaterials. Advances in Polymer Science, vol 267. Springer, Cham. https://doi.org/10.1007/12_2014_281
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