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Encapsulation by Miniemulsion Polymerization

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Modern Techniques for Nano- and Microreactors/-reactions

Part of the book series: Advances in Polymer Science ((POLYMER,volume 229))

Abstract

The miniemulsion technique offers the possibility for the encapsulation of different materials, ranging from liquid to solid, from organic to inorganic, and from molecularly dissolved to aggregated species into polymeric nanoparticles or nanocapsules. Using this technique, a wide variety of novel functional nanomaterials can be generated. This review focuses on the preparation of functional nanostructures by encapsulating organic or inorganic material in polymeric nanoparticles. The examples demonstrate the possibilities to protect the encapsulated material as dyes, pigments, fragrances, photo-initiators, drugs, magnetite, or even DNA, use them as marker systems (dyes, magnetite), or create nanoparticles with completely new properties.

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Abbreviations

AA:

Acrylic acid

ADMET:

Acyclic diene metathesis

AEMH2:

Aminoethyl methacrylate hydrochloride

AGET:

Activator generated by electron transfer

AIBN:

Azo-bis-(isobutyronitrile)

ATRP:

Atom transfer radical polymerization

BODIPY:

Boron-dipyrromethene

CDB:

Phenyl 2-propyl dithiobenzoate

CMTE:

cis-1,2-Bis(2,4,5-trimethyl-3-trienyl)ethane

CTAB:

Cetyltrimethylammonium bromide

CTMA-Cl:

Cetyltrimethylammonium chloride

DMPBA:

1,2-Dimethyl-1-phenyl-butyramide

FACS:

Fluorescent activated cell sorter

HR-SEM:

High resolution scanning electron microscopy

KPS:

Peroxodisulfate

MePEG:

Methoxypoly(ethylene glycol)

MPS:

Methacryloxypropyltrimethoxysilane

MRI:

Magnetic resonance imaging

NMP:

Nitroxide mediated polymerization

NMR:

Nuclear magnetic resonance

PAEMA:

Poly(aminoethyl methacrylate)

PBA:

Polybutylacrylate

PBCA:

Polybutylcyanoacrylate

PCL:

Poly(ε-caprolactone)

PEG:

Poly(ethylene glycol)

P(E/B-EO):

Poly((ethylene-co-butylene)-b-ethylene oxide))

PEI:

Poly(ethylene imine)

PI:

Polyisoprene

PLLA:

Polylactide

PMAA:

Poly(methacrylic acid)

PMI:

N-(2,6-Diisopropylphenyl)perylene-3,4-dicarbonacidimide ()

PMMA:

Poly(methylmethacrylate)

PNIPAM:

Poly(N-isopropylacrylamide)

PPPDTA:

Phenyl 2-propyl phenyl dithioacetate

PS:

Polystyrene

PU:

Polyurethane

PUR:

Polyurea

QD:

Quantum dot

RAFT:

Reversible addition–fragmentation chain transfer

RITC:

Rhodamine isothiocyanate

SDS:

Sodium dodecyl sulfate

SWNT:

Single wall carbon nanotube

TEM:

Transmission electron microscopy

TEOS:

Tetraethylorthosilicate

tmhd:

Tris(2,2,6,6-tetramethyl-3,5-heptanedionato)

TOPO:

Trioctylphosphine oxide

V60:

2,2′-Azobis{2-[1-(2-hydroxyethyl)-2-imidazolin-2-yl]propane}dihydrochloride

References

  1. Aschenbrenner EM, Weiss CK, Landfester K (2009) Enzymatic esterification in aqueous miniemulsions. Chem Eur J 15:2434–2444

    Article  CAS  Google Scholar 

  2. de Barros DPC, Fonseca LP, Cabral JMS, et al. (2009) Synthesis of alkyl esters by cutinase in miniemulsion and organic solvent media. Biotechnol J 4:674–683

    Article  CAS  Google Scholar 

  3. Taden A, Landfester K, Antonietti M (2004) Crystallization of dyes by directed aggregation of colloidal intermediates: a model case. Langmuir 20:957–961

    Article  CAS  Google Scholar 

  4. Taden A, Landfester K (2003) Crystallization of poly(ethylene oxide) confined in miniemulsion droplets. Macromolecules 36:4037–4041

    Article  CAS  Google Scholar 

  5. Montenegro R, Antonietti M, Mastai Y, et al. (2003) Crystallization in miniemulsion droplets. J Phys Chem C 107:5088–5094

    CAS  Google Scholar 

  6. Montenegro R, Landfester K (2003) Metastable and stable morphologies during crystallization of alkanes in miniemulsion droplets. Langmuir 19:5996–6003

    Article  CAS  Google Scholar 

  7. Rossmanith R, Weiss CK, Geserick J, et al. (2008) Porous anatase nanoparticles with high specific surface area prepared by miniemulsion technique. Chem Mater 20:5768–5780

    Article  CAS  Google Scholar 

  8. Asua JM (2002) Miniemulsion polymerization. Prog Polym Sci 27:1283–1346

    Article  CAS  Google Scholar 

  9. Landfester K (2006) Synthesis of colloidal particles in miniemulsions. Annu Rev Mater Res 36:231–279

    Article  CAS  Google Scholar 

  10. Landfester K (2009) Miniemulsion polymerization and the structure of polymer and hybrid nanoparticles. Angew Chem Int Ed 48:4488–4507

    Article  CAS  Google Scholar 

  11. Schork FJ, Luo Y, Smulders W, et al. (2005) Miniemulsion polymerization. Adv Poly Sci 175:129–255

    Article  CAS  Google Scholar 

  12. Crespy D, Landfester K (2005) Anionic polymerization of ε-caprolactam in miniemulsion: synthesis and characterization of polyamide-6 nanoparticles. Macromolecules 38:6882–6887

    Article  CAS  Google Scholar 

  13. Weiss CK, Ziener U, Landfester K (2007) A route to nonfunctionalized and functionalized poly(n-butylcyanoacrylate) nanoparticles: preparation in miniemulsion. Macromolecules 40:928–938

    Article  CAS  Google Scholar 

  14. Cauvin S, Ganachaud F, Moreau M, et al. (2005) High molar mass polymers by cationic polymerisation in emulsion and miniemulsion. Chem Commun 21:2713–2715

    Article  CAS  Google Scholar 

  15. Cauvin S, Ganachaud F (2004) On the preparation and polymerization of p-methoxystyrene miniemulsions in the presence of excess ytterbium triflate. Macromol Symp 215:179–189

    Article  CAS  Google Scholar 

  16. Soula R, Saillard B, Spitz R, et al. (2002) Catalytic copolymerization of ethylene and polar and nonpolar Î ± -olefins in emulsion. Macromolecules 35:1513–1523

    Article  CAS  Google Scholar 

  17. Wehrmann P, Zuideveld M, Thomann R, et al. (2006) Copolymerization of ethylene with 1-butene and norbornene to higher molecular weight copolymers in aqueous emulsion. Macromolecules 39:5995–6002

    Article  CAS  Google Scholar 

  18. Held A, Kolb L, Zuideveld MA, et al. (2002) Aqueous polyketone latices prepared with water-insoluble palladium(II) catalysts. Macromolecules 35:3342–3347

    Article  CAS  Google Scholar 

  19. Quémener D, Héroguez V, Gnanou Y (2005) Latex particles by miniemulsion ring-opening metathesis polymerization. Macromolecules 38:7977–7982

    Article  CAS  Google Scholar 

  20. Quémener D, Héroguez V, Gnanou Y (2006) Design of PEO-based ruthenium carbene for aqueous metathesis polymerization. Synthesis by the “macromonomer method” and application in the miniemulsion metathesis polymerization of norbornene. J Polym Sci Part A Polym Chem 44:2784–2793

    Article  CAS  Google Scholar 

  21. Pecher J, Mecking S (2007) Nanoparticles from step-growth coordination polymerization. Macromolecules 40:7733–7735

    Article  CAS  Google Scholar 

  22. Landfester K, Tiarks F, Hentze HP, et al. (2000) Polyaddition in miniemulsions: a new route to polymer dispersions. Macromol Chem Phys 201:1–5

    Article  CAS  Google Scholar 

  23. Tiarks F, Landfester K, Antonietti M (2001) One-step preparation of polyurethane dispersions by miniemulsion polyaddition. J Polym Sci Part A Polym Chem 39:2520–2524

    Article  CAS  Google Scholar 

  24. Barrere M, Landfester K (2003) High molecular weight polyurethane and polymer hybrid particles in aqueous miniemulsion. Macromolecules 36:5119–5125

    Article  CAS  Google Scholar 

  25. Barrere M, Landfester K (2003) Polyester synthesis in aqueous miniemulsion. Polymer 44:2833–2841

    Article  CAS  Google Scholar 

  26. Taden A, Antonietti M, Landfester K (2003) Enzymatic polymerization towards biodegradable polyester nanoparticles. Macromol Rapid Commun 24:512–516

    Article  CAS  Google Scholar 

  27. Marie E, Rothe R, Antonietti M, et al. (2003) Synthesis of polyaniline particles via inverse and direct miniemulsion. Macromolecules 36:3967–3973

    Article  CAS  Google Scholar 

  28. Bhadra S, Singha NK, Khastgir D (2006) Polyaniline by new miniemulsion polymerization and the effect of reducing agent on conductivity. Synth Met 156:1148–1154

    Article  CAS  Google Scholar 

  29. Alyautdin RN, Reichel A, Löbenberg R, et al. (2001) Interaction of poly(butylcyanoacrylate) nanoparticles with the blood–brain barrier in vivo and in vitro. J Drug Target 9:209–221

    Article  Google Scholar 

  30. Holzapfel V, Musyanovych A, Landfester K, et al. (2005) Preparation of fluorescent carboxyl and amino functionalized polystyrene particles by miniemulsion polymerization as markers for cells. Macromol Chem Phys 206:2440–2449

    Article  CAS  Google Scholar 

  31. Lorenz MR, Holzapfel V, Musyanovych A, et al. (2006) Uptake of functionalized, fluorescent-labeled polymeric particles in different cell lines and stem cells. Biomaterials 27:2820–2828

    Article  CAS  Google Scholar 

  32. Dausend J, Musyanovych A, Dass M, et al. (2008) Uptake mechanism of oppositely charged fluorescent nanoparticles in HeLa cells. Macromol Biosci 8:1135–1143

    Article  CAS  Google Scholar 

  33. Ziegler A, Landfester K, Musyanovych A (2009) Synthesis of phosphonate-functionalized polystyrene and poly(methyl methacrylate) particles and their kinetic behavior in miniemulsion polymerization. Colloid Polym Sci. http://dx.doi.org/10.1007/s00396--009--2087-z

  34. Lorenz MR, Kohnle MV, Dass M, et al. (2008) Synthesis of fluorescent polyisoprene nanoparticles and their uptake into various cells. Macromol Biosci 8:711–727

    Article  CAS  Google Scholar 

  35. Weiss CK, Kohnle M-V, Landfester K, et al. (2008) The first step into the brain: uptake of NIO-PBCA nanoparticles by endothelial cells in vitro and in vivo, and direct evidence for their blood–brain barrier permeation. Chem Med Chem 3:1395–1403

    CAS  Google Scholar 

  36. Weiss CK, Lorenz MR, Landfester K, et al. (2007) Cellular uptake behavior of unfunctionalized and functionalized poly(n-butylcyanoacrylate) particles prepared in a miniemulsion. Macromol Biosci 7:883–896

    Article  CAS  Google Scholar 

  37. Musyanovych A, Schmitz-Wienke J, Mailaender V, et al. (2008) Preparation of biodegradable polymer nanoparticles by miniemulsion technique and their cell interactions. Macromol Biosci 8:127–139

    Article  CAS  Google Scholar 

  38. Holzapfel V, Lorenz M, Weiss CK, et al. (2006) Synthesis and biomedical applications of functionalized fluorescent and magnetic dual reporter nanoparticles as obtained in the miniemulsion process. J Phys Condens Matter 18:S2581–S2594

    Article  CAS  Google Scholar 

  39. Mailander V, Lorenz Myriam R, Holzapfel V, et al. (2008) Carboxylated superparamagnetic iron oxide particles label cells intracellularly without transfection agents. Mol Imaging Biol 10:138–146

    Article  Google Scholar 

  40. Urban M, Musyanovych A, Landfester K (2009) Fluorescent superparamagnetic polylactide nanoparticles by combination of miniemulsion and emulsion/solvent evaporation techniques. Macromol Chem Phys 210:961–970

    Article  CAS  Google Scholar 

  41. Oh JK, Siegwart DJ, Matyjaszewski K (2007) Synthesis and biodegradation of nanogels as delivery carriers for carbohydrate drugs. Biomacromolecules 8:3326–3331

    Article  CAS  Google Scholar 

  42. Oh JK, Siegwart DJ, Lee HI, et al. (2007) Biodegradable nanogels prepared by atom transfer radical polymerization as potential drug delivery carriers: synthesis, biodegradation, in vitro release, and bioconjugation. J Am Chem Soc 129:5939–5945

    Article  CAS  Google Scholar 

  43. Siegwart DJ, Srinivasan A, Bencherif SA, et al. (2009) Cellular uptake of functional nanogels prepared by inverse miniemulsion ATRP with encapsulated proteins, carbohydrates, and gold nanoparticles. Biomacromolecules 10:2300–2309

    Article  CAS  Google Scholar 

  44. Takasu M, Shiroya T, Takeshita K, et al. (2004) Improvement of the storage stability and photostability of colored latex prepared by miniemulsion polymerization. Colloid Polym Sci 282:740–746

    Article  CAS  Google Scholar 

  45. Takasu M, Kawaguchi H (2005) Preparation of colored latex with polyurea shell by miniemulsion polymerization. Colloid Polym Sci 283:805–811

    Article  CAS  Google Scholar 

  46. Takasu M, Shiroya T, Takeshita K, et al. (2003) Preparation of colored latex containing oil-soluble dyes with high dye content by mini-emulsion polymerization. Colloid Polym Sci 282:119–126

    Article  CAS  Google Scholar 

  47. Zhao X, Zhou S, Chen M, et al. (2009) Effective encapsulation of Sudan black B with polystyrene using miniemulsion polymerization. Colloid Polym Sci

    Google Scholar 

  48. Bradley M, Ashokkumar M, Grieser F (2003) Sonochemical production of fluorescent and phosphorescent latex particles. J Am Chem Soc 125:525–529

    Article  CAS  Google Scholar 

  49. Tamai T, Watanabe M, Maeda H, et al. (2008) Fluorescent polymer particles incorporating pyrene derivatives. J Polym Sci Part A Polym Chem 46:1470–1475

    Article  CAS  Google Scholar 

  50. Taniguchi T, Takeuchi N, Kobaru S, et al. (2008) Preparation of highly monodisperse fluorescent polymer particles by miniemulsion polymerization of styrene with a polymerizable surfactant. J Colloid Interface Sci 327:58–62

    Article  CAS  Google Scholar 

  51. Watarai H, Ogawa K, Suzuki N (1993) Formation of fluorescent complexes of Eu(III) and Sm(III) with [beta]-diketones and trioctylphosphine oxide in oil–water microemulsions. Anal Chim Acta 277:73–78

    Article  CAS  Google Scholar 

  52. Ando K, Kawaguchi H (2005) High-performance fluorescent particles prepared via miniemulsion polymerization. J Colloid Interface Sci 285:619–626

    Article  CAS  Google Scholar 

  53. Hu ZK, Xue MZ, Zhang Q, et al. (2007) Controlled preparation of nanocolorants via a modified miniemulsion polymerization process. J Appl Polym Sci 104:3036–3041

    Article  CAS  Google Scholar 

  54. Hu Z, Xue M, Zhang Q, et al. (2008) Nanocolorants: a novel class of colorants, the preparation and performance characterization. Dyes Pigments 76:173–178

    Article  CAS  Google Scholar 

  55. Yuan B, Wicks DA (2007) Thermotropic color changing nanoparticles prepared by encapsulating blue polystyrene particles with a poly-N-isopropylacrylamide gel. J Appl Polym Sci 105:446–452

    Article  CAS  Google Scholar 

  56. Yuan B, States J, Sahagun C, et al. (2008) Effects of three cross-linkers on colored pH-responsive core-shell latexes. J Appl Polym Sci 107:4093–4099

    Article  CAS  Google Scholar 

  57. Han M, Lee E, Kim E (2002) Preparation and optical properties of polystyrene nanocapsules containing photochromophores. Opt Mater 21:579–583

    Article  Google Scholar 

  58. Furukawa H, Misu M, Ando K, et al. (2008) Light-controlled on-off switch of a fluorescent nanoparticle. Macromol Rapid Commun 29:547–551

    Article  CAS  Google Scholar 

  59. Hu Z, Zhang Q, Xue M, et al. (2007) Fluorescent photoswitchable nanohybrids based on photochromism. J Phys Chem Solids 69:206–210

    Article  CAS  Google Scholar 

  60. Hu Z, Zhang Q, Xue M, et al. (2008) Spirobenzopyran-based photochromic nanohybrids with photoswitchable fluorescence. Opt Mater 30:851–856

    Article  CAS  Google Scholar 

  61. Chern CS, Chen TJ, Liou YC (1998) Miniemulsion polymerization of styrene in the presence of a water-insoluble blue dye. Polymer 39:3767–3777

    Article  CAS  Google Scholar 

  62. Chern CS, Liou YC, Chen TJ (1998) Particle nucleation loci in styrene miniemulsion polymerization using alkyl methacrylates as the reactive cosurfactant. Macromol Chem Phys 199:1315–1322

    Article  CAS  Google Scholar 

  63. Chern C-S, Chang H-T (2002) Particle nucleation and growth mechanisms in miniemulsion polymerization of styrene. Polym Int 51:1428–1438

    Article  CAS  Google Scholar 

  64. Chern C-S, Liou Y-C (1998) Effects of mixed surfactants on the styrene miniemulsion polymerization in the presence of an alkyl methacrylate. Macromol Chem Phys 199:2051–2061

    Article  CAS  Google Scholar 

  65. Chern C-S, Liou Y-C (1999) Kinetics of styrene miniemulsion polymerization stabilized by nonionic surfactant/alkyl methacrylate. Polymer 40:3763–3772

    Article  CAS  Google Scholar 

  66. Chern C-S, Liou Y-C (1999) Styrene miniemulsion polymerization initiated by 2,2′-azobisisobutyronitrile. J Polym Sci Part A Polym Chem 37:2537–2550

    Article  CAS  Google Scholar 

  67. Musyanovych A, Rossmanith R, Tontsch C, et al. (2007) Effect of hydrophilic comonomer and surfactant type on the colloidal stability and size distribution of carboxyl- and amino-functionalized polystyrene particles prepared by miniemulsion polymerization. Langmuir 23:5367–5376

    Article  CAS  Google Scholar 

  68. Manzke A, Pfahler C, Dubbers O, et al. (2007) Etching masks based on miniemulsions: a novel route towards ordered arrays of surface nanostructures. Adv Mater 19:1337–1341

    Article  CAS  Google Scholar 

  69. Schreiber E, Ziener U, Manzke A, et al. (2009) Preparation of narrowly size distributed metal-containing polymer latexes by miniemulsion and other emulsion techniques: applications for nanolithography. Chem Mater 21:1750–1760

    Article  CAS  Google Scholar 

  70. Vancaeyzeele C, Ornatsky O, Baranov V, et al. (2007) Lanthanide-containing polymer nanoparticles for biological tagging applications: nonspecific endocytosis and cell adhesion. J Am Chem Soc 129:13653–13660

    Article  CAS  Google Scholar 

  71. Ramírez LP, Antonietti M, Landfester K (2006) Formation of novel layered nanostructures from lanthanide-complexes by secondary interactions with ligating monomers in miniemulsion droplets. Macromol Chem Phys 207:160–165

    Article  CAS  Google Scholar 

  72. Bechthold N, Tiarks F, Willert M, et al. (2000) Miniemulsion polymerization: applications and new materials. Macromol Symp 151:549–555

    Article  CAS  Google Scholar 

  73. Lelu S, Novat C, Graillat C, et al. (2003) Encapsulation of an organic phthalocyanine blue pigment into polystyrene latex particles using a miniemulsion polymerization. Polym Int 52:542–547

    Article  CAS  Google Scholar 

  74. Steiert N, Landfester K (2007) Encapsulation of organic pigment particles via miniemulsion polymerization. Macromol Mater Eng 292:1111–1125

    Article  CAS  Google Scholar 

  75. Tiarks F, Landfester K, Antonietti M (2001) Encapsulation of carbon black by miniemulsion polymerization. Macromol Chem Phys 202:51–60

    Article  CAS  Google Scholar 

  76. Barraza HJ, Pompeo F, O’Rear EA, et al. (2002) SWNT-filled thermoplastic and elastomeric composites prepared by miniemulsion polymerization. Nano Lett 2:797–802

    Article  CAS  Google Scholar 

  77. Ha MLP, Grady BP, Lolli G, et al. (2007) Composites of single-walled carbon nanotubes and styrene-isoprene copolymer latices. Macromol Chem Phys 208:446–456

    Article  CAS  Google Scholar 

  78. Ham HT, Choi YS, Chee MG, et al. (2006) Singlewall carbon nanotubes covered with polystyrene nanoparticies by in-situ miniemulsion polymerization. J Polym Sci Part A Polym Chem 44:573–584

    Article  CAS  Google Scholar 

  79. Lu HF, Xin JH, Fei B, et al. (2007) Synthesis and lubricating performance of a carbon nanotube seeded miniemulsion. Carbon 45:936–942

    Article  CAS  Google Scholar 

  80. Ham HT, Choi YS, Jeong N, et al. (2005) Singlewall carbon nanotubes covered with polypyrrole nanoparticles by the miniemulsion polymerization. Polymer 46:6308–6315

    Article  CAS  Google Scholar 

  81. Lu HF, Fei B, Xin JH, et al. (2006) Fabrication of UV-blocking nanohybrid coating via miniemulsion polymerization. J Colloid Interface Sci 300:111–116

    Article  CAS  Google Scholar 

  82. Luo YD, Dai CA, Chiu WY (2008) Synthesis of P(AA-SA)/ZnO composite latex particles via inverse miniemulsion polymerization and its application in pH regulation and UV shielding. J Polym Sci Part A Polym Chem 46:8081–8090

    Article  CAS  Google Scholar 

  83. Zhang JJ, Gao G, Zhang M, et al. (2006) ZnO/PS core-shell hybrid microspheres prepared with miniemulsion polymerization. J Colloid Interface Sci 301:78–84

    Article  CAS  Google Scholar 

  84. Mahdavian A, Sarrafi Y, Shabankareh M (2009) Nanocomposite particles with core–shell morphology. III. Preparation and characterization of nano Al2O3–poly(styrene-methyl methacrylate) particles via miniemulsion polymerization. Polym Bull 63:329–340

    Article  CAS  Google Scholar 

  85. Lopez-Martinez EI, Marquez-Lucero A, Hernandez-Escobar CA, et al. (2007) Incorporation of silver/carbon nanoparticles into poly(methyl methacrylate) via in situ miniemulsion polymerization and its influence on the glass-transition temperature. J Polym Sci Part B Polym Phys 45:511–518

    Article  CAS  Google Scholar 

  86. Crespy D, Landfester K (2009) Synthesis of polyvinylpyrrolidone/silver nanoparticles hybrid latex in non-aqueous miniemulsion at high temperature. Polymer 50:1616–1620

    Article  CAS  Google Scholar 

  87. Erdem B, Sully Y, Sudol ED, et al. (2000) Determination of miniemulsion droplet size via soap titration. Langmuir 16:4890–4895

    Article  CAS  Google Scholar 

  88. Erdem B, Sudol ED, Dimonie VL, et al. (2000) Encapsulation of inorganic particles via miniemulsion polymerization. III. Characterization of encapsulation. J Polym Sci Part A Polym Chem 38:4441–4450

    Article  CAS  Google Scholar 

  89. Erdem B, Sudol ED, Dimonie VL, et al. (2000) Encapsulation of inorganic particles via miniemulsion polymerization. II. Preparation and characterization of styrene miniemulsion droplets containing TiO2 particles. J Polym Sci Part A Polym Chem 38:4431–4440

    Article  CAS  Google Scholar 

  90. Erdem B, Sudol ED, Dimonie VL, et al. (2000) Encapsulation of inorganic particles via miniemulsion polymerization. I. Dispersion of titanium dioxide particles in organic media using OLOA 370 as stabilizer. J Polym Sci Part A Polym Chem 38:4419–4430

    Article  CAS  Google Scholar 

  91. Erdem B, Sudol ED, Dimonie VL, et al. (2000) Encapsulation of inorganic particles via mini-emulsion polymerization. Macromol Symp 155:181–198

    Article  CAS  Google Scholar 

  92. Al-Ghamdi GH, Sudol ED, Dimonie VL, et al. (2006) Encapsulation of titanium dioxide in styrene/n-butyl acrylate copolymer by miniemulsion polymerization. J Appl Polym Sci 101:3479–3486

    Article  CAS  Google Scholar 

  93. Al-Ghamdi GH, Sudol ED, Dimonie VL, et al. (2006) High PVC film-forming composite latex particles via miniemulsification, part 3: optical properties. J Appl Polym Sci 101: 4526–4537

    Article  CAS  Google Scholar 

  94. Al-Ghamdi GH, Sudol ED, Dimonie VL, et al. (2006) High PVC film-forming composite latex particles via miniemulsification, part 2: efficiency of encapsulation. J Appl Polym Sci 101:4517–4525

    Article  CAS  Google Scholar 

  95. Al-Ghamdi GH, Sudol ED, Dimonie VL, et al. (2006) High PVC film-forming composite latex particles via miniemulsification, part 1: preparation. J Appl Polym Sci 101:4504–4516

    Article  CAS  Google Scholar 

  96. Kim H, Daniels ES, Li S, et al. (2007) Polymer encapsulation of yttrium oxysulfide phosphorescent particles via miniemulsion polymerization. J Polym Sci Part A Polym Chem 45:1038–1054

    Article  CAS  Google Scholar 

  97. Yang Y, Wen Z, Dong Y, et al. (2006) Incorporating CdTe nanocrystals into polystyrene microspheres: towards robust fluorescent beads. Small 2:898–901

    Article  CAS  Google Scholar 

  98. Fleischhaker F, Zentel R (2005) Photonic crystals from core-shell colloids with incorporated highly fluorescent quantum dots. Chem Mater 17:1346–1351

    Article  CAS  Google Scholar 

  99. Esteves ACC, Bombalski L, Trindade T, et al. (2007) Polymer grafting from Cds quantum dots via AGET ATRP in miniemulsion. Small 3:1230–1236

    Article  CAS  Google Scholar 

  100. Tiarks F, Landfester K, Antonietti M (2001) Silica nanoparticles as surfactants and fillers for latexes made by miniemulsion polymerization. Langmuir 17:5775–5780

    Article  CAS  Google Scholar 

  101. Zhang SW, Zhou SX, Weng YM, et al. (2005) Synthesis of SiO2/polystyrene nanocomposite particles via miniemulsion polymerization. Langmuir 21:2124–2128

    Article  CAS  Google Scholar 

  102. Zhou J, Zhang SW, Qiao XG, et al. (2006) Synthesis of SiO2/poly(styrene-co-butyl acrylate) nanocomposite microspheres via miniemulsion polymerization. J Polym Sci Part A Polym Chem 44:3202–3209

    Article  CAS  Google Scholar 

  103. Qi DM, Bao YZ, Weng ZX, et al. (2006) Preparation of acrylate polymer/silica nanocomposite particles with high silica encapsulation efficiency via miniemulsion polymerization. Polymer 47:4622–4629

    Article  CAS  Google Scholar 

  104. Zhou J, Chen M, Qiao XG, et al. (2006) Facile preparation method of SiO2/PS/TiO2 multilayer core-shell hybrid microspheres. Langmuir 22:10175–10179

    Article  CAS  Google Scholar 

  105. Lu W, Chen M, Wu L (2008) One-step synthesis of organic–inorganic hybrid asymmetric dimer particles via miniemulsion polymerization and functionalization with silver. J Colloid Interface Sci 328:98–102

    Article  CAS  Google Scholar 

  106. Qiang W, Wang Y, He P, et al. (2008) Synthesis of asymmetric inorganic/polymer nanocomposite particles via localized substrate surface modification and miniemulsion polymerization. Langmuir 24:606–608

    Article  CAS  Google Scholar 

  107. Ge X, Wang M, Yuan Q, et al. (2009) The morphological control of anisotropic polystyrene/silica hybrid particles prepared by radiation miniemulsion polymerization. Chem Commun 2765–2767

    Google Scholar 

  108. Wang Y, Xu H, Qiang W, et al. (2009) Asymmetric composite nanoparticles with anisotropic surface functionalities. J Nanomater 2009:5. Article ID 620269

    Google Scholar 

  109. Bailly B, Donnenwirth AC, Bartholome C, et al. (2006) Silica-polystyrene nanocomposite particles synthesized by nitroxide-mediated polymerization and their encapsulation through miniemulsion polymerization. J Nanomater 2006:1–10

    Article  CAS  Google Scholar 

  110. Bombalski L, Min K, Dong H, et al. (2007) Preparation of well-defined hybrid materials by ATRP in miniemulsion. Macromolecules 40:7429–7432

    Article  CAS  Google Scholar 

  111. Toepfer O, Schmidt-Naake G (2007) Surface – functionalized inorganic nanoparticles in miniemulsion polymerization. Macromol Symp 248:239–248

    Article  CAS  Google Scholar 

  112. Monteil V, Stumbaum J, Thomann R, et al. (2006) Silica/poly ethylene nanocomposite particles from catalytic emulsion polymerization. Macromolecules 39:2056–2062

    Article  CAS  Google Scholar 

  113. Boutti S, Bourgeat-Lami E, Zydowicz N (2005) Silica/polyamide nanocomposite synthesis via an original double emulsification process in miniemulsion. Macromol Rapid Commun 26:1860–1865

    Article  CAS  Google Scholar 

  114. Diaconu G, Asua JM, Paulis M, et al. (2007) High-solids content waterborne polymer-clay nanocomposites. Macromol Symp 259:305–317

    Article  CAS  Google Scholar 

  115. Diaconu G, Micusik M, Bonnefond A, et al. (2009) Macroinitiator and macromonomer modified montmorillonite for the synthesis of acrylic/MMT nanocomposite latexes. Macromolecules 42:3316–3325

    Article  CAS  Google Scholar 

  116. Moraes RP, Santos AM, Oliveira PC, et al. (2006) Poly(styrene-co-butyl acrylate)-Brazilian montmorillonite nanocomposites, synthesis of hybrid latexes via miniemulsion polymerization. Macromol Symp 245/246:106–115

    Article  CAS  Google Scholar 

  117. Bouanani F, Bendedouch D, Hemery P, et al. (2008) Encapsulation of montmorillonite in nanoparticles by miniemulsion polymerization. Colloid Surf A Physicochem Eng Asp 317:751–755

    Article  CAS  Google Scholar 

  118. Moraes RP, Valera TS, Demarquette NR, et al. (2009) Influence of granulometry and organic treatment of a Brazilian montmorillonite on the properties of poly(styrene-co-n-butyl acrylate)/layered silicate nanocomposites prepared by miniemulsion polymerization. J Appl Polym Sci 112:1949–1958

    Article  CAS  Google Scholar 

  119. Samakande A, Sanderson RD, Hartmann PC (2009) Rheological properties of RAFT-mediated poly(styrene-co-butyl acrylate)-clay nanocomposites [P(S-co-BA)-PCNs]: emphasis on the effect of structural parameters on thermo-mechanical and melt flow behaviors. Polymer 50:42–49

    Article  CAS  Google Scholar 

  120. Samakande A, Sanderson RD, Hartmann PC (2008) Encapsulated clay particles in polystyrene by RAFT mediated miniemulsion polymerization. J Polym Sci Part A Polym Chem 46:7114–7126

    Article  CAS  Google Scholar 

  121. Tong ZH, Deng YL (2006) Synthesis of water-based polystyrene-nanoclay composite suspension via miniemulsion polymerization. Ind Eng Chem Res 45:2641–2645

    Article  CAS  Google Scholar 

  122. Tong ZH, Deng YL (2008) Kinetics of miniemulsion polymerization of styrene in the presence of organoclays. Macromol Mater Eng 293:529–537

    Article  CAS  Google Scholar 

  123. Diaconu G, Paulis M, Leiza JR (2008) High solids content waterborne acrylic/montmorillonite nanocomposites by miniemulsion polymerization. Macromol React Eng 2:80–89

    Article  CAS  Google Scholar 

  124. Mirzataheri M, Mahdavian A, Atai M (2009) Nanocomposite particles with core-shell morphology IV: an efficient approach to the encapsulation of Cloisite 30B by poly (styrene-co-butyl acrylate) and preparation of its nanocomposite latex via miniemulsion polymerization. Colloid Polym Sci 287:725–732

    Article  CAS  Google Scholar 

  125. Sun QH, Deng YL, Wang ZL (2004) Synthesis and characterization of polystyrene-encapsulated laponite composites via miniemulsion polymerization. Macromol Mater Eng 289:288–295

    Article  CAS  Google Scholar 

  126. Tong ZH, Deng YL (2007) Synthesis of polystyrene encapsulated nanosaponite composite latex via miniemulsion polymerization. Polymer 48:4337–4343

    Article  CAS  Google Scholar 

  127. Samakande A, Juodaityte JJ, Sanderson RD, et al. (2008) Novel cationic RAFT-mediated polystyrene/clay nanocomposites: synthesis, characterization, and thermal stability. Macromol Mater Eng 293:428–437

    Article  CAS  Google Scholar 

  128. Zhang QY, Zhang HP, Xie G, et al. (2007) Effect of surface treatment of magnetic particles on the preparation of magnetic polymer microspheres by miniemulsion polymerization. J Magn Magn Mater 311:140–144

    Article  CAS  Google Scholar 

  129. Chen ZJ, Peng K, Mi YL (2007) Preparation and properties of magnetic polystyrene microspheres. J Appl Polym Sci 103:3660–3666

    Article  CAS  Google Scholar 

  130. Betancourt-Galindo R, Saldivar R, Rodriguez-Fernandez OS, et al. (2004) Preparation and characterization of magnetic latexes using styrene monomer. Polym Bull 51:395–402

    Article  CAS  Google Scholar 

  131. Betancourt-Galindo R, Saldivar-Guerrero R, Rodriguez-Fernandez OS, et al. (2004) Preparation of magnetic latexes using styrene monomer. J Alloy Compd 369:87–89

    Article  CAS  Google Scholar 

  132. Zhang QY, Xie G, Zhang HP, et al. (2007) Encapsulation of magnetic particles via miniemulsion polymerization of styrene. II. Effect of some parameters on the polymerization of styrene. J Appl Polym Sci 105:3525–3530

    CAS  Google Scholar 

  133. Baharvand H (2008) Preparation and characterization of fluorescent polymer magnetic particles. J Appl Polym Sci 109:1823–1828

    Article  CAS  Google Scholar 

  134. Quian Z, Zhicheng Z, Yun C (2008) A novel preparation of surface-modified paramagnetic magnetite/polystyrene nanocomposite microspheres by radiation-induced miniemulsion polymerization. J Colloid Interface Sci 327:354–361

    Article  CAS  Google Scholar 

  135. Ramírez LP, Landfester K (2003) Magnetic polystyrene nanoparticles with a high magnetite content obtained by miniemulsion processes. Macromol Chem Phys 204:22–31

    Article  Google Scholar 

  136. Landfester K, Ramírez LP (2003) Encapsulated magnetite particles for biomedical application. J Phys Condens Matter 15:S1345–S1361

    Article  CAS  Google Scholar 

  137. Joumaa N, Toussay P, Lansalot M, et al. (2007) Surface modification of iron oxide nanoparticles by a phosphate-based macromonomer and further encapsulation into submicrometer polystyrene particles by miniemulsion polymerization. J Polym Sci Part A Polym Chem 46:327–340

    Article  CAS  Google Scholar 

  138. Mahdavian AR, Ashjari M, Mobarakeh HS (2008) Nanocomposite particles with core-shell morphology. I. Preparation and characterization of Fe3O4-poly(butyl acrylate-styrene) particles via miniemulsion polymerization. J Appl Polym Sci 110:1242–1249

    Article  CAS  Google Scholar 

  139. Mahdavian AR, Sehri Y, Salehi-Mobarakeh H (2008) Nanocomposite particles with core-shell morphology. II. An investigation into the affecting parameters on preparation of Fe3O4-poly (butyl acrylate-styrene) particles via miniemulsion polymerization. Eur Polym J 44:2482–2488

    Article  CAS  Google Scholar 

  140. Liu XQ, Guan YP, Ma ZY, et al. (2004) Surface modification and characterization of magnetic polymer nanospheres prepared by miniemulsion polymerization. Langmuir 20:10278–10282

    Article  CAS  Google Scholar 

  141. Lu SH, Forcada J (2006) Preparation and characterization of magnetic polymeric composite particles by miniemulsion polymerization. J Polym Sci Part A Polym Chem 44:4187–4203

    Article  CAS  Google Scholar 

  142. Csetneki I, Faix MK, Szilagyi A, et al. (2004) Preparation of magnetic polystyrene latex via the miniemulsion polmerization technique. J Polym Sci Part A Polym Chem 42:4802–4808

    Article  CAS  Google Scholar 

  143. Mori Y, Kawaguchi H (2007) Impact of initiators in preparing magnetic polymer particles by miniemulsion polymerization. Colloid Surf B Biointerfaces 56:246–254

    Article  CAS  Google Scholar 

  144. Qiu GH, Wang Q, Wang C, et al. (2007) Polystyrene/Fe3O4 magnetic emulsion and nanocomposite prepared by ultrasonically initiated miniemulsion polymerization. Ultrason Sonochem 14:55–61

    Article  CAS  Google Scholar 

  145. Qiu GH, Wang Q, Wang C, et al. (2006) Ultrasonically initiated miniemulsion polymerization of styrene in the presence of Fe3O4 nanoparticles. Polym Int 55:265–272

    Article  CAS  Google Scholar 

  146. Gong T, Yang D, Hu J, et al. (2009) Preparation of monodispersed hybrid nanospheres with high magnetite content from uniform Fe3O4 clusters. Colloid Surf A Physicochem Eng Asp 339:232–239

    Article  CAS  Google Scholar 

  147. Yan F, Li J, Zhang J, et al. (2009) Preparation of Fe3O4/polystyrene composite particles from monolayer oleic acid modified Fe3O4 nanoparticles via miniemulsion polymerization. J Nanopart Res 11:289–296

    Article  CAS  Google Scholar 

  148. Cui L, Xu H, He P, et al. (2007) Developing a hybrid emulsion polymerization system to synthesize Fe3O4/polystyrene latexes with narrow size distribution and high magnetite content. J Polym Sci Part A Polym Chem 45:5285–5295

    Article  CAS  Google Scholar 

  149. Tu C, Yang Y, Gao M (2008) Preparations of bifunctional polymeric beads simultaneously incorporated with fluorescent quantum dots and magnetic nanocrystals. Nanotechnology 19:105601

    Article  CAS  Google Scholar 

  150. Nunes JS, De Vasconcelos CL, Cabral FO, et al. (2006) Synthesis and characterization of poly(ethyl methacrylate-co-methacrylic acid) magnetic particles via miniemulsion polymerization. Polymer 47:7646–7652

    Article  CAS  Google Scholar 

  151. Nunes JS, de Vasconcelos CL, Dantas TNC, et al. (2008) Preparation of acrylic latexes with dispersed magnetite nanoparticles. J Dispersion Sci Technol 29:769–774

    Article  CAS  Google Scholar 

  152. Zheng WM, Gao F, Gu HC (2005) Carboxylated magnetic polymer nanolatexes: preparation, characterization and biomedical applications. J Magn Magn Mater 293:199–205

    Article  CAS  Google Scholar 

  153. Tan CJ, Tong YW (2007) Preparation of superparamagnetic ribonuclease a surface-imprinted submicrometer particles for protein recognition in aqueous media. Anal Chem 79:299–306

    Article  CAS  Google Scholar 

  154. Tan CJ, Chua HG, Ker KH, et al. (2008) Preparation of bovine serum albumin surface-imprinted submicrometer particles with magnetic susceptibility through core-shell miniemulsion polymerization. Anal Chem 80:683–692

    Article  CAS  Google Scholar 

  155. Qian H, Lin ZY, Xu HM, et al. (2009) The efficient and specific isolation of the antibodies from human serum by thiophilic paramagnetic polymer nanospheres. Biotechnol Progr 25:376–383

    Article  CAS  Google Scholar 

  156. Faridi-Majidi R, Sharifi-Sanjani N, Agend F (2006) Encapsulation of magnetic nanoparticles with polystyrene via emulsifier-free miniemulsion polymerization. Thin Solid Films 515:368–374

    Article  CAS  Google Scholar 

  157. Faridi-Majidi R, Sharifi-Sanjani N (2007) Emulsifier-free miniemulsion polymerization of styrene and the investigation of encapsulation of nanoparticles with polystyrene via this procedure using an anionic initiator. J Appl Polym Sci 105:1244–1250

    Article  CAS  Google Scholar 

  158. Faridi-Majidi R, Sharifi-Sanjani N (2007) Preparation of magnetic latexes functionalized with chloromethyl groups via emulsifier-free miniemulsion polymerization. J Magn Magn Mater 311:55–58

    Article  CAS  Google Scholar 

  159. Shao D, Xia A, Hu J, et al. (2008) Monodispersed magnetite/silica composite microspheres: preparation and application for plasmid DNA purification. Colloid Surf A Physicochem Eng Asp 322:61–65

    Article  CAS  Google Scholar 

  160. Xu ZZ, Wang CC, Yang WL, et al. (2004) Encapsulation of nanosized magnetic iron oxide by polyacrylamide via inverse miniemulsion polymerization. J Magn Magn Mater 277:136–143

    Article  CAS  Google Scholar 

  161. Wormuth K (2001) Superparamagnetic latex via inverse emulsion polymerization. J Colloid Interface Sci 241:366–377

    Article  CAS  Google Scholar 

  162. Ménager C, Sandre O, Mangili J, et al. (2004) Preparation and swelling of hydrophilic magnetic microgels. Polymer 45:2475–2481

    Article  CAS  Google Scholar 

  163. Xu ZZ, Wang CC, Yang WL, et al. (2005) Synthesis of superparamagnetic Fe3O4∕SiO2 composite particles via sol-gel process based on inverse miniemulsion. J Mater Sci 40:4667–4669

    Article  CAS  Google Scholar 

  164. Lin CL, Chiu WY, Don TM (2006) Superparamagnetic thermoresponsive composite latex via W/O miniemulsion polymerization. J Appl Polym Sci 100:3987–3996

    Article  CAS  Google Scholar 

  165. Johnston APR, Cortez C, Angelatos AS, et al. (2006) Layer-by-layer engineered capsules and their applications. Curr Opin Colloid Interface Sci 11:203–209

    Article  CAS  Google Scholar 

  166. Wang Y, Angelatos AS, Caruso F (2007) Template synthesis of nanostructured materials via layer-by-layer assembly. Chem Mater 20:848–858

    Article  CAS  Google Scholar 

  167. zu Putlitz B, Landfester K, Fischer H, et al. (2001) The generation of “armored latexes” and hollow inorganic shells made of clay sheets by templating cationic miniemulsions and latexes. Adv Mater 13:500–503

    Article  CAS  Google Scholar 

  168. Tiarks F, Landfester K, Antonietti M (2001) Preparation of polymeric nanocapsules by miniemulsion polymerization. Langmuir 17:908–918

    Article  CAS  Google Scholar 

  169. Luo YW, Zhou XD (2004) Nanoencapsulation of a hydrophobic compound by a miniemulsion polymerization process. J Polym Sci Part A Polym Chem 42:2145–2154

    Article  CAS  Google Scholar 

  170. Cao Z, Shan G (2009) Synthesis of polymeric nanocapsules with a crosslinked shell through interfacial miniemulsion polymerization. J Polym Sci Part A Polym Chem 47:1522–1534

    Article  CAS  Google Scholar 

  171. Romio AP, Sayer C, Araújo PHH, et al. (2009) Nanocapsules by miniemulsion polymerization with biodegradable surfactant and hydrophobe. Macromol Chem Phys 210:747–751

    Article  CAS  Google Scholar 

  172. Zetterlund PB, Saka Y, Okubo M (2009) Gelation and hollow particle formation in nitroxide-mediated radical copolymerization of styrene and divinylbenzene in miniemulsion. Macromol Chem Phys 210:140–149

    CAS  Google Scholar 

  173. Volz M, Ziener U, Salz U, et al. (2007) Preparation of protected photoinitiator nanodepots by the miniemulsion process. Colloid Polym Sci 285:687–692

    Article  CAS  Google Scholar 

  174. Theisinger S, Schoeller K, Osborn B, et al. (2009) Encapsulation of a fragrance via miniemulsion polymerization for temperature-controlled release. Macromol Chem Phys 210:411–420

    Article  CAS  Google Scholar 

  175. Ni KF, Shan GR, Weng ZX (2006) Synthesis of hybrid nanocapsules by miniemulsion (co)polymerization of styrene and gamma-methacryloxypropyltrimethoxysilane. Macromolecules 39:2529–2535

    Article  CAS  Google Scholar 

  176. van Zyl AJP, Sanderson RD, de Wet-Roos D, et al. (2003) Core/shell particles containing liquid cores: morphology prediction, synthesis, and characterization. Macromolecules 36:8621–8629

    Article  CAS  Google Scholar 

  177. van Zyl AJP, Bosch RFP, McLeary JB, et al. (2005) Synthesis of styrene based liquid-filled polymeric nanocapsules by the use of RAFT-mediated polymerization in miniemulsion. Polymer 46:3607–3615

    Article  CAS  Google Scholar 

  178. Lu F, Luo Y, Li B (2007) A facile route to synthesize highly uniform nanocapsules: use of amphiphilic poly(acrylic acid)-block-polystyrene RAFT agents to interfacially confine miniemulsion polymerization. Macromol Rapid Commun 28:868–874

    Article  CAS  Google Scholar 

  179. Luo YW, Gu HY (2006) A general strategy for nano-encapsulation via interfacially confined living/controlled radical miniemulsion polymerization. Macromol Rapid Commun 27:21–25

    Article  CAS  Google Scholar 

  180. Luo Y, Gu H (2007) Nanoencapsulation via interfacially confined reversible addition fragmentation transfer (RAFT) miniemulsion polymerization. Polymer 48:3262–3272

    Article  CAS  Google Scholar 

  181. Scott C, Wu D, Ho CC, et al. (2005) Liquid-core capsules via interfacial polymerization: a free-radical analogy of the nylon rope trick. J Am Chem Soc 127:4160–4161

    Article  CAS  Google Scholar 

  182. Wu D, Scott C, Ho CC, et al. (2006) Aqueous-core capsules via interfacial free radical alternating copolymerization. Macromolecules 39:5848–5853

    Article  CAS  Google Scholar 

  183. Musyanovych A, Landfester K (2008) Synthesis of poly(butylcyanoacrylate) nanocapsules by interfacial polymerization in miniemulsions for the delivery of DNA molecules. In Auernhammer GK, Butt H-J, Vollmer D (eds) Surface and interfacial forces – from fundamentals to applications. Springer, Berlin/Heidelberg

    Google Scholar 

  184. Zhang Y, Zhu SY, Yin LC, et al. (2008) Preparation, characterization and biocompatibility of poly(ethylene glycol)-poly(n-butyl cyanoacrylate) nanocapsules with oil core via miniemulsion polymerization. Eur Polym J 44:1654–1661

    Article  CAS  Google Scholar 

  185. Marie E, Landfester K, Antonietti M (2002) Synthesis of chitosan-stabilized polymer dispersions, capsules, and chitosan grafting products via miniemulsion. Biomacromolecules 3:475–481

    Article  CAS  Google Scholar 

  186. Torini L, Argillier JF, Zydowicz N (2005) Interfacial polycondensation encapsulation in miniemulsion. Macromolecules 38:3225–3236

    Article  CAS  Google Scholar 

  187. Johnsen H, Schmid RB (2007) Preparation of polyurethane nanocapsules by miniemulsion polyaddition. J Microencapsulation 24:731–742

    Article  CAS  Google Scholar 

  188. Crespy D, Stark M, Hoffmann-Richter C, et al. (2007) Polymeric nanoreactors for hydrophilic reagents synthesized by interfacial polycondensation on miniemulsion droplets. Macromolecules 40:3122–3135

    Article  CAS  Google Scholar 

  189. Jagielski N, Sharma S, Hombach V, et al. (2007) Nanocapsules synthesized by miniemulsion technique for application as new contrast agent materials. Macromol Chem Phys 208: 2229–2241

    Article  CAS  Google Scholar 

  190. Paiphansiri U, Dausend J, Musyanovych A, et al. (2009) Fluorescent polyurethane nanocapsules prepared via inverse miniemulsion: surface functionalization for use as biocarriers. Macromol Biosci 9:575–584

    Article  CAS  Google Scholar 

  191. Rosenbauer E-M, Landfester K, Musyanovych A (2009) Surface-active monomer as a stabilizer for polyurea nanocapsules synthesized via interfacial polyaddition in inverse miniemulsion. Langmuir http://dx.doi.org/10.1021/la9017097

  192. Mailänder V, Landfester K (2009) Interaction of nanoparticles with cells. Biomacromolecules 10(9):2379–2400

    Article  CAS  Google Scholar 

  193. Paiphansiri U, Tangboriboonrat P, Landfester K (2006) Polymeric nanocapsules containing an antiseptic agent obtained by controlled nanoprecipitation onto water-in-oil miniemulsion droplets. Macromol Biosci 6:33–40

    Article  CAS  Google Scholar 

  194. Paiphansiri U, Tangboriboonrat P, Landfester K (2007) Antiseptic nanocapsule formation via controlling polymer deposition onto water-in-oil miniemulsion droplets. Macromol Symp 251:54–62

    Article  CAS  Google Scholar 

  195. Volz M, Walther P, Ziener U, et al. (2007) Nano-explosions of nanoparticles for sudden release of substances by embedded azo-components as obtained via the miniemulsion process. Macromol Mater Eng 292:1237–1244

    Article  CAS  Google Scholar 

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  1. Max Planck Institute for Polymer Research, Ackermannweg 10, 55128, Mainz, Germany

    Katharina Landfester & Clemens K. Weiss

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  1. Katharina Landfester
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  2. Clemens K. Weiss
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Correspondence to Katharina Landfester .

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  1. Dept. Chemical & Biomolecular, Engineering, University of Melbourne, Melbourne, 3010, Australia

    Frank Caruso

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Landfester, K., Weiss, C.K. (2010). Encapsulation by Miniemulsion Polymerization. In: Caruso, F. (eds) Modern Techniques for Nano- and Microreactors/-reactions. Advances in Polymer Science, vol 229. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2009_43

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