Skip to main content

Modern Synthetic and Application Aspects of Polysilanes: An Underestimated Class of Materials?

  • Chapter
  • First Online:
Silicon Polymers

Part of the book series: Advances in Polymer Science ((POLYMER,volume 235))

Abstract

Polysilanes can be synthesized by various methods still lacking satisfactory product control in respect to quality and purity. Nonetheless polysilanes are promising in a number of applications like e.g. organic electronic devices. This review summarizes recent progress in the synthesis and possible applications of polysilanes.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Notes

  1. 1.

    For a more detailed and comprehensive description of the mechanism see also the review of Jones and Holder [18].

References

  1. Kipping FS (1921) J Chem Soc 119:830

    Article  CAS  Google Scholar 

  2. Kipping FS (1923) J Chem Soc 125:2291

    Google Scholar 

  3. Miller DR, Michl J (1989) Chem Rev 89:1359

    Article  CAS  Google Scholar 

  4. Stock A (1926) Z Elektrochem 32:341

    CAS  Google Scholar 

  5. Fehér F, Schinkitz D, Schaaf J (1971) Z Anorg Allg Chem 383:303

    Article  Google Scholar 

  6. Fehér F, Schinkitz D, Wronka G (1971) Z Anorg Allg Chem 384:226

    Article  Google Scholar 

  7. F Fehér, D Schinkitz, H Strack (1971) Z Anorg Allg Chem 358:202

    Article  Google Scholar 

  8. Fehér F, Baier H, Enders B, Krancher M, Laakmann J, Ocklenburg FJ, Skrodski D (1985) Z Anorg Allg Chem 530:191

    Article  Google Scholar 

  9. Auner GA, Bauch C, Lippold G, Deltschew R (2008) DE 102006034061 A1 CAN 115: 115263

    Google Scholar 

  10. Friedel C, Ladenburg A (1869) C R Hebd Seances Acad Sci 68:920

    Google Scholar 

  11. Kipping FS (1924) J Chem Soc 125:2291

    Article  CAS  Google Scholar 

  12. Ziegler JM, Rozell JM, Pannell KH (1987) Macromolecules 6:399

    Google Scholar 

  13. Fujino M, Hisaki T, Fujiki M, Matsumoto N (1992) Macromolecules 1079

    Google Scholar 

  14. Ziegler JM (1986) Polym Prepr 27:109

    Article  CAS  Google Scholar 

  15. Ziegler JM, Harrah LA (1987) Macromolecules 20:601

    Article  Google Scholar 

  16. Horguchi R, Onishi Y, Hayase S (1988) Macromolecules 21:304

    Article  Google Scholar 

  17. Miller DR, Sooriyakumaran R (1988) Macromolecules 21:3120

    Article  CAS  Google Scholar 

  18. Jones RG, Holder SJ (2000) Synthesis of polysilanes by the wurtz reductive-coupling reaction. In: Silicon-containing polymers. Kluwer, Dordrecht

    Google Scholar 

  19. Jones RG, Holder SJ (2006) Polym Int 55:711

    Article  CAS  Google Scholar 

  20. Ziegler JM (1987) Polym Prepr 27:109

    Google Scholar 

  21. Cragg RH, Jones RG, Swain AC, Webb SJ (1990) J Chem Soc Chem Commun 1147

    Google Scholar 

  22. Miller MD, Ginsberg EJ, Thompson D (1993) Polym J 25:807

    Article  CAS  Google Scholar 

  23. Jones RG, Budnik U, Holder SJ, Wong WKC (1996) Macromolecules 29:8036

    Article  CAS  Google Scholar 

  24. Holder SJ, Achilleos M, Jones RG (2006) J Am Chem Soc 128:12418

    Article  CAS  Google Scholar 

  25. Gauthier S, Worsford DJ (1989) Macromolecules 22:2213

    Article  CAS  Google Scholar 

  26. Kim HK, Matyjaszewski K (1988) J Am Chem Soc 110:3321

    Article  CAS  Google Scholar 

  27. Matyjaszewski K, Chen YL, Kim HK (1988) Inorganic and organometallic polymers. In: ACS Symp Series. ACS, Washington DC

    Google Scholar 

  28. Worsfold DJ (1988) Inorganic and organometallic polymers. In: ACS Symp Series. ACS, Washington DC

    Google Scholar 

  29. Gauthier S, Worsfold DJ (1990) Mechanistic studies in polysilane polymerization. In: Silicon-based polymer science: a comprehensive resource. In: ACS Series. ACS, Washington DC

    Google Scholar 

  30. Matyjaszewski K (1987) Polym Prepr 28:224

    Article  CAS  Google Scholar 

  31. Sakamoto K, Obata K, Hirata H, Nakajima M, Sakurai H (1989) J Am Chem Soc 111:7641

    Article  CAS  Google Scholar 

  32. Raabe G, Michl J (1989) The chemistry of organic silicon compounds, Part 2 Wiley, Chichester

    Google Scholar 

  33. Roark DN, Peddle GJD (1972) J Am Chem Soc 94:5837

    Article  CAS  Google Scholar 

  34. Sakamoto K, Yoshida M, Sakurai H (1990) Macromolecules 23:4494

    Article  CAS  Google Scholar 

  35. Sakurai H, Yoshida M (2000) Synthesis of polysilanes by new procedures. Part 1: Ring opening polymerisations and the polymerisation of masked disilenes. In: Silicon-containing polymers. Kluwer, Dorndrecht

    Google Scholar 

  36. Sakurai H, Sakamoto K, Funada Y, Yoshida M (1993) Polym Prepr 34:218

    Article  CAS  Google Scholar 

  37. Sanji T, Kawabata K, Sakurai H (2000) J Organomet Chem 611:32

    Article  CAS  Google Scholar 

  38. Sanji T, Isozaki S, Yoshida M, Sakamoto K, Sakurai H (2003) J Organomet Chem 685:65

    Article  CAS  Google Scholar 

  39. Sakurai H, Honbori R, Sanji T (2005) Organometallics 24:4119

    Article  CAS  Google Scholar 

  40. Li J, Li Z, Tang HD, Zeng HY, Qin JG (2003) J Organomet Chem 685:258

    Article  CAS  Google Scholar 

  41. Sakamoto K, Yoshida M, Sakurai H (1984) Polymer 35:4990

    Article  Google Scholar 

  42. Chandrasekhar V (2005) Polysilanes and other silicon containing Polymers. In: Inorganic and organometallic polymers. Springer, Berlin Heidelberg New York

    Google Scholar 

  43. Cypryrk M, Gupta Y, Matyjaszewski K (1991) J Am Chem Soc 113:1046

    Article  Google Scholar 

  44. Suzuki M, Kotani J, Gyobu S, Kaneko T, Saegusa T (1994) Macromolecules 27:2360

    Article  CAS  Google Scholar 

  45. Koe JR, Powell DR, Buffy JJ, Hayase S, West R (1998) Angew Chem 37:1441

    Article  CAS  Google Scholar 

  46. Grimmond BJ, Corey JY (2002) Inorg Chim Acta 330:89

    Article  CAS  Google Scholar 

  47. Imori T, Tilley TD (1994) Polyhedron 13:2231

    Article  CAS  Google Scholar 

  48. Banovetz JP, Suzuki H, Waymouth RM (1993) Organometallics 12:4700

    Article  CAS  Google Scholar 

  49. Hashimoto H, Obara S, Kira M (2000) Chem Lett 188

    Google Scholar 

  50. Obora Y, Tanaka M (2000) J Organomet Chem 595:1

    Article  CAS  Google Scholar 

  51. Mu Y, Harrod JF, John F (1991) Inorg Organomet Oligomers Polym, Proc IUPAC Symp Macromol 33:23

    Google Scholar 

  52. Rosenberg L, Kobus DN (2003) J Organomet Chem 685:107

    Article  CAS  Google Scholar 

  53. Aitken C, Harrod JF, Samuel E (1985) J Organomet Chem 279:C11

    Article  CAS  Google Scholar 

  54. Shankar R, Saxena A, Brar AS (2001) J Organomet Chem 628:262

    Article  CAS  Google Scholar 

  55. Hengge E, Gspaltl P, Pinter E (1996) J Organomet Chem 521:145

    Article  CAS  Google Scholar 

  56. Woo HG, Tilley TD (1989) J Am Chem Soc 111:8043

    Article  CAS  Google Scholar 

  57. Corey JY, Zhu XH (1992) J Organomet Chem 439:1

    Article  CAS  Google Scholar 

  58. Corey JY (2004) Adv Organomet Chem 51:1

    Article  CAS  Google Scholar 

  59. Dioumaev VK, Harrod JF (1996) J Organomet Chem 521:133

    Article  CAS  Google Scholar 

  60. Grimmond BJ, Corey JY (2000) Organometallics 19:3776

    Article  CAS  Google Scholar 

  61. Gray GM, Corey JY (2000) Synthesis of polysilanes by new procedures. Part 2: Catalytic dehydropolymerisation of hydrosilanes. In: Silicon-containing polymers. Kluwer, Dordrecht

    Google Scholar 

  62. Shaltout RM, Corey JY (1995) Tetrahedron 51:4309

    Article  CAS  Google Scholar 

  63. Shaltout RM, Corey JY (1995) Main Group Chem 1:115

    Article  CAS  Google Scholar 

  64. Minato M, Matsumoto T, Ichikawa M, Ito T (2003) Chem Commun 2968

    Google Scholar 

  65. Kim B, Woo HG, Kim W, Li H (2006) J Chem Technol Biotechnol 81:782

    Article  CAS  Google Scholar 

  66. Ojima I, Inaba S, Kogure T, Nagai Y (1973) J Organomet Chem 55:C7

    Article  CAS  Google Scholar 

  67. Berris C, Diefenbach SP (1992) U.S. 5003100 CAN 115:115263

    Google Scholar 

  68. Fontaine FG, Kadkhodazadeh T, Zargarian D (1998) Chem Commun 1253

    Google Scholar 

  69. Fontaine FG, Zargarian D (2002) Organometallics 21:401

    Article  CAS  Google Scholar 

  70. Tanaka M, Bannu P (1998) JP 10 67859 CAN 128:244528

    Google Scholar 

  71. Chauhan BPS, Shimizu T, Tanaka M (1997) Chem Lett 785

    Google Scholar 

  72. Sakakura T, Lautenschlager HJ, Nakajima M, Tanaka M (1991) Chem Lett 913

    Google Scholar 

  73. Kobayashi T, Sakakura T, Hayashi T, Yamura M, Tanaka M (1992) Chem Lett 1157

    Google Scholar 

  74. Aitken CT, Harrod JF, Samuel E (1986) J Am Chem Soc 108:4059

    Article  CAS  Google Scholar 

  75. Tilley TD (1993) Acc Chem Res 26:22

    Article  CAS  Google Scholar 

  76. Dioumaev VK, Harrod JF (1997) Organometallics 16:1452

    Article  CAS  Google Scholar 

  77. Dioumaev VK, Harrod JF (1996) J Organomet Chem 521:133

    Article  CAS  Google Scholar 

  78. Lunzer F, Marschner C, Landgraf S (1998) J Organomet Chem 568:253

    Article  CAS  Google Scholar 

  79. Ishifune M, Kashimura S, Kogai Y, Fukuhara Y, Kato T, Bu HB, Yamashita N, Murai Y, Murase H, Nishida R (2000) J Organomet Chem 611:26

    Article  CAS  Google Scholar 

  80. Wesson JP, Williams TC (1981) J Polym Sci A Polym Chem 19:65

    Article  CAS  Google Scholar 

  81. Fogarty HA, Ottosson CH, Michl J (2000) J Mol Struct 556:105

    Article  CAS  Google Scholar 

  82. Fogarty HA, Ottosson CH, Michl J (2000) J Mol Struct Theochem 506:243

    Article  CAS  Google Scholar 

  83. Jones RG, Wong WKC, Holder SJ (1998) Organometallics 17:59

    Article  CAS  Google Scholar 

  84. Yajima S, Hayashi J, Omori M (1975) Chem Lett 931

    Google Scholar 

  85. Michl J (1990) Acc Chem Res 23:127

    Article  CAS  Google Scholar 

  86. Michl J, West R (2000) Structure and spectroscopy of polysilanes. In: Silicon containing polymers. Kluwer, Dordrecht

    Google Scholar 

  87. West R (1982) Organopolysilanes. In: Comprehensive organometallic chemistry. Pergamon, Oxford

    Google Scholar 

  88. Miller DR (1989) Angew Chem Int Ed Engl 28:1733

    Article  Google Scholar 

  89. West R (1986) J Organomet Chem 300:327

    Article  CAS  Google Scholar 

  90. Yajima S, Hasegawa Y, Hayashi J, Iimura M (1978) J Mater Sci 13:2569

    Article  CAS  Google Scholar 

  91. West R (1981) J Am Chem Soc 103:7352

    Article  CAS  Google Scholar 

  92. Orefice RL, Arnold JJ, Miller TM, Zamora MP, Brennan AB (1997) Polym Prepr 38:157

    CAS  Google Scholar 

  93. Matsuura K, Miura S, Naito H, Inoue H, Matsukawa K (2003) J Organomet Chem 230:6851

    Google Scholar 

  94. West R, Ikuo N, Xing-Hua Z (1984) Polym Prepr 25:4

    CAS  Google Scholar 

  95. Langguth K (1995) Ceram Int 21:237

    Article  CAS  Google Scholar 

  96. Langguth K, Bockhle S, Müller E, Röwer G (1995) J Mater Sci 30:5973

    Article  CAS  Google Scholar 

  97. Okamoto K, Shinohara M, Yamanishi T, Miyazaki S, Hirose M (1994) Appl Surf Sci 79:57

    Article  Google Scholar 

  98. Kotaro Y, Tazawa S, Kitsuno Y, Kawasaki K (1992) JP 6191821A2 CAN 121:219559

    Google Scholar 

  99. Fukujama K, Kitsuno Y, Sakawaki A, Takadera T, Kotaro Y (1998) JP 2000031066A2 CAN 132:95820

    Google Scholar 

  100. Yamamoto H, Takeuchi Y, Matsuki Y, Kato H, Hayakawa H, Endo M (2002) JP 2004186320A2 CAN 141:91765

    Google Scholar 

  101. Aoki T (2004) JP 2005219981A2 CAN 143:204477

    Google Scholar 

  102. Harrah LH, Ziegler JM (1985) J Polym Sci Polym Lett Ed. 23:209

    Article  CAS  Google Scholar 

  103. Trefonas P, Damewood JR, West R, Miller RD (1985) Organometallics 4:1318

    Article  CAS  Google Scholar 

  104. Peinado C, Alonso A, Catalina F, Schnabel W (2000) Macromol Chem Phys 201:1156

    Article  CAS  Google Scholar 

  105. Matsuura K, Matsukawa K, Kawabata R, Higashi N, Niwa M, Inoue H (2002) Polymer 43:1549

    Article  CAS  Google Scholar 

  106. Pyun J, Matyjaszewski K (2001) Chem Mater 12:3436

    Article  CAS  Google Scholar 

  107. Hamada Y, Tabei E, Mori S, Yamamoto Y, Noguchi N, Aramata M, Fukushima M (1998) Synth Metal 97:273

    Article  Google Scholar 

  108. Sakurai Y, Okuda S, Nagayama N, Yokoyama M (2001) J Mater Chem 11:1077

    Article  CAS  Google Scholar 

  109. Sakurai Y, Okuda S, Nishiguchi H, Nagayama N, Yokoyama M (2003) J Mater Chem 13:1862

    Article  CAS  Google Scholar 

  110. Hashimoto K, Nomura N (1991) JP 03139650 A CAN 116:245278

    Google Scholar 

  111. Kido J, Nagai K, Okamoto Y, Skotheim T (1991) Appl Phys Lett 59:2760

    Article  CAS  Google Scholar 

  112. Suzuki H, Meyer H, Simmerer J, Yang J, Haarer D (1993) Adv Mater 5:743

    Article  CAS  Google Scholar 

  113. Kido J, Nagai K, Okamoto K (1993) J Alloys Compd 192:30

    Article  CAS  Google Scholar 

  114. Suzuki H, Meyer H, Hoshino S, Haarer D (1995) J Appl Phys Lett 78:2648

    Google Scholar 

  115. Suzuki H, Hoshino S (1996) J. Appl Phys Lett 79:8816

    Article  CAS  Google Scholar 

  116. Kamata N, Ishii R, Tonsyo S, Terunuma D (2002) Appl Phys Lett 81:4350

    Article  CAS  Google Scholar 

  117. Seoul C, Park J, Lee J (2003) Polym Prepr (Am Chem Soc, Div Polym Chem) 44:435

    Google Scholar 

  118. Hoshino S, Suzuki H (1996) Appl Phys Lett 69:224

    Article  CAS  Google Scholar 

  119. Fujii A, Yoshimoto K, Yoshido M, Ohomori Y, Moshino K (1995) Jpn J Appl Phys 34:L1365

    Article  CAS  Google Scholar 

  120. Ebihara K, Koshihara S, Miyazawa T, Kira M (1996) Jpn J Appl Phys 35:L1278

    Article  CAS  Google Scholar 

  121. Hattori R, Sugano T, Fujiki T (1996) Jpn J Appl Phys 35:L1509

    Article  Google Scholar 

  122. Xu Y, Fujino T, Naito H, Oka K, Dohmaru T (1998) Chem Lett 299

    Google Scholar 

  123. Yuan C, Hoshino S, Toyoda S, Suzuki H, Fujiki M, Matsumoto N (1997) Appl Phys Lett 71:3326

    Article  CAS  Google Scholar 

  124. Tokito S, Shirane K, Kamachi M (2003) WO 2003/092334 CAN 139:351099

    Google Scholar 

  125. Kanai M, Tanaka H, Sako S (1991) JP 03181184 A CAN 116:162057

    Google Scholar 

  126. Kanai M, Tanaka H, Sakou H (1991) DE 4039519 A1 CAN 116:95256

    Google Scholar 

  127. Lee J, Seoul C, Park J, Youk JH (2004) Synth Metal 145:11

    Article  CAS  Google Scholar 

  128. Rybak A, Jung J, Ciesielski W, Ulanski J (2006) Mater Sci 24:527

    CAS  Google Scholar 

  129. Haga Y, Harada Y (2001) Jpn J Appl Phys 1 40:855

    Google Scholar 

  130. Fukushima M, Aramata M, Mori S (1998) JP 3275736 B2 CAN 129:41835

    Google Scholar 

  131. Yamaguchi F, Ueda M, Fujisawa K (1999) JP 11012362 A CAN 130:154129

    Google Scholar 

  132. Furukawa M, Kaimoto T, Matsuo S (2004) JP 2004063238 CAN 140:184763

    Google Scholar 

  133. Ohshita J, Kangai S, Yoshida H, Kunai A, Kajiwara S, Ooyama Y, Harima Y (2007) J Organomet Chem 692:801

    Article  CAS  Google Scholar 

  134. Nakayama T, Naito K (1998) JP 10319450 A CAN 130:87978

    Google Scholar 

  135. Nishizawa H, Uchikoga S, Shuichi N, Yoshihiko H, Hayase S (1993) EP 528662 A1 CAN 119:215411

    Google Scholar 

  136. Ogier SD, Veres J, Zeidan M (2007) WO 2007082584 A1 CAN 147:224628

    Google Scholar 

  137. (1992) JP 5275695 A2 CAN 120:313472

    Google Scholar 

  138. Okumoto H, Yatabe T, Richter A, Peng J, Shimomura M, Kaito A, Minami N (2003) Adv Mater 15:716

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Corresponding author

Correspondence to B. Rieger .

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2009 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Feigl, A., Bockholt, A., Weis, J., Rieger, B. (2009). Modern Synthetic and Application Aspects of Polysilanes: An Underestimated Class of Materials?. In: Muzafarov, A. (eds) Silicon Polymers. Advances in Polymer Science, vol 235. Springer, Berlin, Heidelberg. https://doi.org/10.1007/12_2009_1

Download citation

Publish with us

Policies and ethics