Skip to main content
SpringerLink
Log in

Thermodynamics and Micro Heterogeneity of Ionic Liquids

  • Chapter
  • First Online:
Ionic Liquids

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 290))

Abstract

The high degree of organisation in the fluid phase of room-temperature ionic liquids has major consequences on their macroscopic properties, namely on their behaviour as solvents. This nanoscale self-organisation is the result of an interplay between two types of interaction in the liquid phase – Coulomb and van der Waals – that eventually leads to the formation of medium-range structures and the recognition of some ionic liquids as composed of a high-charge density, cohesive network permeated by low-charge density regions.

In this chapter, the structure of the ionic liquids will be explored and some of their consequences to the properties of ionic liquids analyzed.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 259.00
Price excludes VAT (USA)
  • Available as EPUB and PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 329.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 329.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Notes

  1. 1.

    1This simple “red and green” color scheme was reused in several publications, including some by other authors. It had been used in previous Monte Carlo simulation studies involving nano-segregated binary mixtures of Lennard-Jones atom, where the colors had been chosen just by numerical order in the RGB system: red is 001 (1 in binary), green is 010 (2 in binary), and they are followed by yellow (011) and blue (100). The fact that red and green are the colors of the Portuguese flag (the nationality of the authors) is merely a coincidence.

References

  1. Dupont J, Suarez PAZ (2006) Phys Chem Chem Phys 8:2441

    Article  CAS  Google Scholar 

  2. Antonietti M, Kuang D, Smarsly B, Zhou Y (2004) Angew Chem Int Ed 43:4988

    Article  CAS  Google Scholar 

  3. Hansen J-P, McDonald IR (2006) Theory of simple liquids, 3rd edn. Academic, New York

    Google Scholar 

  4. Canongia Lopes JN, Padua AAH (2006) J Phys Chem B 110:3330

    Article  CAS  Google Scholar 

  5. Wang J, Voth GA (2005) J Am Chem Soc 127:12192

    Article  CAS  Google Scholar 

  6. Triolo A, Russina O, Bleif H-J, Di Cola E (2007) J Phys Chem B 111:4641

    Article  CAS  Google Scholar 

  7. Bates ED, Mayton RD, Ntai I, Davis JHJ (2002) J Am Chem Soc 124:926

    Article  CAS  Google Scholar 

  8. Kumar P, Mittal KL (eds) (1999) Handbook of microemulsion science and technology. Marcel Dekker, New York

    Google Scholar 

  9. Gordon CM, Holbrey JD, Kennedy AR, Seddon KR (1998) J Mater Chem 8:2627

    Article  CAS  Google Scholar 

  10. Shah JK, Brennecke JF, Maginn EJ (2002) Green Chem 4:112

    Article  CAS  Google Scholar 

  11. Hanke CG, Price SL, Linden-Bell RM (2001) Mol Phys 99:801

    Article  CAS  Google Scholar 

  12. de Andrade J, Boes ES, Stassen H (2002) J Phys Chem B 106:3546

    Article  CAS  Google Scholar 

  13. Margulis CJ, Stern HA, Berne BJ (2002) J Phys Chem B 106:12017

    Article  CAS  Google Scholar 

  14. Canongia Lopes JN, Deschamps J, Padua AAH (2004) J Phys Chem B 108:2038

    Article  CAS  Google Scholar 

  15. Canongia Lopes JN, Padua AAH (2004) J Phys Chem B 108:16893

    Article  CAS  Google Scholar 

  16. Canongia Lopes JN, Padua AAH (2006) J Phys Chem B 110:19586

    Article  CAS  Google Scholar 

  17. Canongia Lopes JN, Padua AAH, Shimizu K (2008) J Phys Chem B 112:5039

    Article  CAS  Google Scholar 

  18. Borodin O, Smith GD (2006) J Phys Chem B 110:11481

    Article  CAS  Google Scholar 

  19. Yan TY, Burnham CJ, Del Popolo MG, Voth GA (2004) J Phys Chem B 108:11877

    Article  CAS  Google Scholar 

  20. Bhargava BL, Balasubramanian S, Klein M (2008) Chem Commun:3339

    Google Scholar 

  21. Jorgensen WL, Maxwell DS, Tirado-Rives J (1996) J Am Chem Soc 118:11225

    Article  CAS  Google Scholar 

  22. Bonifacio RP, Filipe EJM, McCabe C, Costa Gomes MF, Padua AAH (2002) Mol Phys 100:2547

    Article  CAS  Google Scholar 

  23. Liu ZP, Huang SP, Wang WC (2004) J Phys Chem B 108:12978

    Article  CAS  Google Scholar 

  24. Earle MJ, Esperança JMSS, Gilea MA, Canongia Lopes JN, Rebelo LPN, Magee JW, Seddon KR, Widegren JA (2006) Nature 439:831

    Article  CAS  Google Scholar 

  25. Santos LMNBF, Canongia Lopes JN, Coutinho JAP, Esperança JMSS, Gomes LR, Marrucho IM, Rebelo LPN (2007) J Am Chem Soc 129:284

    Article  CAS  Google Scholar 

  26. Maginn E (2007) J Acc Chem Res 40:1200

    Article  CAS  Google Scholar 

  27. Canongia Lopes JN (1999) Mol Phys 96:1649

    Article  Google Scholar 

  28. Urahata SM, Ribeiro MCC (2004) J Chem Phys 120:1855

    Article  CAS  Google Scholar 

  29. Tokuda H, Hayamizu K, Kunikazu I, Susan MABH, Watanabe M (2005) J Phys Chem B 109:6103

    Article  CAS  Google Scholar 

  30. Mandal PK, Sarkar M, Samanta A (2004) J Phys Chem A 108:9048

    Article  CAS  Google Scholar 

  31. Paul A, Mandal PK, Samanta A (2005) J Phys Chem B 109:9148

    Article  CAS  Google Scholar 

  32. Anderson JL, Armstrong DW (2003) Anal Chem 75:4851

    Article  CAS  Google Scholar 

  33. Canongia Lopes JN, Shimizu K, Padua AAH, Umebayashi Y, Fukuda S, Fujii K, Ishiguro S (2008) J Phys Chem B 112:1465

    Article  CAS  Google Scholar 

  34. Canongia Lopes JN, Costa Gomes MF, Padua AAH (2006) J Phys Chem B 110:16816

    Article  CAS  Google Scholar 

  35. Padua AAH, Costa Gomes MF, Canongia Lopes JNA (2007) Acc Chem Res 40:1087

    Article  CAS  Google Scholar 

  36. Pison L, Canongia Lopes JN, Rebelo LPN, Padua AAH, Costa Gomes MF (2008) J Phys Chem B 112:12394

    Article  CAS  Google Scholar 

  37. Ferreira R, Blesic M, Trindade J, Marrucho IM, Canongia Lopes JN, Rebelo LPN (2008) Green Chem 10:918

    Article  CAS  Google Scholar 

  38. Lachwa J, Bento I, Duarte MT, Canongia Lopes JN, Rebelo LPN (2006) Chem Commun 2445

    Google Scholar 

  39. Deetlefs M, Hardacre C, Nieuwenhuyzen M, Sheppard O, Soper AK (2005) J Phys Chem B 109:1593

    Article  CAS  Google Scholar 

  40. Hanke CG, Johansson A, Harper JB, Lynden-Bell RM (2003) Chem Phys Lett 374:85

    Article  CAS  Google Scholar 

  41. Harper JB, Lynden-Bell RM (2004) Mol Phys 102:85

    Article  CAS  Google Scholar 

  42. Gutel T, Santini CC, Padua AAH, Fenet B, Chauvin Y, Canongia Lopes JN, Bayard F, Costa Gomes MF, Pensado A (2009) J Phys Chem B 113:170

    Google Scholar 

  43. Pitzer KS (1980) J Am Chem Soc 102:2902

    Article  CAS  Google Scholar 

  44. Pitzer KS (1984) J Phys Chem 88:2689

    Article  CAS  Google Scholar 

  45. Del Popolo MG, Mullan CL, Holbrey JD, Hardacre C, Ballone P (2008) J Am Chem Soc 130:7032

    Article  CAS  Google Scholar 

  46. Lachwa J, Szydlowski J, Makowska A, Seddon KR, Esperanca JMSS, Guedes HJR, Rebelo LPN (2006) Green Chem 8:262

    Article  CAS  Google Scholar 

  47. Kato R, Krummen M, Gmehling J (2004) Fluid Phase Equilibria 224:47

    Article  CAS  Google Scholar 

  48. Malham IB, Letellier P, Turmine M (2006) J Phys Chem B 110:14212

    Article  CAS  Google Scholar 

  49. Malham IB, Letellier P, Mayaffre A, Turmine M (2007) J Chem Thermodyn 39:1132

    Article  CAS  Google Scholar 

  50. Hong G, Jacquemin J, Husson P, Costa Gomes MF, Deetlefs M, Nieuwenhuyzen M, Sheppard O, Hardacre C (2006) Ind Eng Chem Res 45:8180

    Article  CAS  Google Scholar 

  51. Hildebrand JH, Scott RL (1950) The solubility of nonelectrolytes, 3rd edn. Reihnold, New York

    Google Scholar 

  52. Costa Gomes MF, Pádua AAH (2005) Pure Appl Chem 77:653

    Article  CAS  Google Scholar 

  53. Pison L, Pensado A, Padua AAH, Costa Gomes MF (2009) in preparation

    Google Scholar 

  54. Deschamps J, Costa Gomes MF, Pádua AAH (2004) Chem Phys Chem 5:1049

    CAS  Google Scholar 

  55. Parvulescu VI, Hardacre C (2007) Chem Rev 107:2615

    Article  CAS  Google Scholar 

  56. Rogers RD, Hough WL (2007) Bull Chem Soc Jpn 80:2262

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire Thermodynamique et Interactions Moléculaires, Université Blaise Pascal, Clermont-Ferrand/CNRS, Aubière, France

    Margarida F. Costa Gomes & A. A. H. Padua

  2. Instituto Superior Técnico, Centro de Quimica Estrutural, Lisbon, Portugal

    J. N. Canongia Lopes

  3. Instituto de Tecnologia Quimica e Biologica, Universidade Nova de Lisboa, Oeiras, Portugal

    J. N. Canongia Lopes

Authors
  1. Margarida F. Costa Gomes
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. J. N. Canongia Lopes
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. H. Padua
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Margarida F. Costa Gomes .

Editor information

Editors and Affiliations

  1. Wilhelm-Oswald Institut für, Universität Leipzig, Linnéstr. 2, Leipzig, 04103, Germany

    Barbara Kirchner

Rights and permissions

Reprints and permissions

Copyright information

© 2009 Springer-Verlag Berlin Heidelberg

About this chapter

Cite this chapter

Gomes, M.F.C., Lopes, J.N.C., Padua, A.A.H. (2009). Thermodynamics and Micro Heterogeneity of Ionic Liquids. In: Kirchner, B. (eds) Ionic Liquids. Topics in Current Chemistry, vol 290. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2009_2

Download citation

Publish with us

Policies and ethics

Search

Navigation