Abstract
The mammalian olfactory and gustatory systems have inspired an emergent area of molecular recognition, which utilizes arrays of semiselective sensors to create patterns to distinguish analytes. Pattern-based recognition, combined with chemometric analysis, has provided chemists the tools necessary to create sensing ensembles that far exceed our ability to rationally design and synthesize sensors for complex molecules. These differential sensing arrays have been used for several biological, environmental, and industrial applications, and are becoming increasingly relevant to real world problems. Herein, we will examine the progress that has been made through differential molecular recognition. We will also discuss the different array platforms that have been employed and provide a brief introduction to the most commonly used chemometric analytical methods.
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References
Doty RL (2003) Handbook of Olfaction and Gustation, 2nd edn. Marcel Dekker, New York
Axel R (2005) Angew Chem Int Ed 44:6111
Lavigne JJ, Anslyn EV (2001) Angew Chem Int Ed 40:3118
Albert KJ, Lewis NS, Schauer CL, Sotzing GA, Stitzel SE, Vaid TP, Walt DR (2000) Chem Rev 100:2595
Epstein JP, Walt DR (2003) Chem Soc Rev 32:203
Toko K (1998) Biosens Bioelectron 13:701
Toko K (1998) Meas Sci Technol 9:1919
Walt DR (1998) Acc Chem Res 31:267
Laukis LR (1998) Acc Chem Res 31:317
Jurs PC, Bakken GA, McClelland HE (2000) Chem Rev 100:2649 and references therein
Jolliffe IT (2002) Principal Component Analysis, 2nd edn. Springer, Berlin Heidelberg New York
Brereton RG (2003) Chemometrics Data Analysis for the Laboratory and Chemical Plant. Wiley, Chichester, West Sussex, UK
Burns JA, Whitesides GM (1993) Chem Rev 93:2583
Lavigne JJ, Savoy S, Clevenger MB, Ritchie JE, McDonie B, Yoo S-J, Anslyn EV, McDevitt JT, Shear JB, Neikirk D (1998) J Am Chem Soc 120:6429
Goodey A, Lavigne JJ, Savoy SM, Rodriguez MD, Curey T, Tsao A, Simmons G, Wright J, Yoo S-J, Sohn Y, Anslyn EV, Shear J, Neikirk DP, McDevitt JT (2001) J Am Chem Soc 123:2559
Christodoulides N, Tran M, Floriano PN, Rodriguez M, Goodey A, Ali M, Neikirk D, McDevitt JT (2002) Anal Chem 74:3030
Curey TE, Goodey A, Tsao A, Lvigne J, Sohn Y, McDevitt JT, Anslyn EV, Neikirk D, Shear JB (2001) Anal Biochem 293:178
McCleskey SM, Griffin MJ, Schneider SE, McDevitt JT, Anslyn EV (2003) J Am Chem Soc 125:1114
Wright AT, Griffin MJ, Zhong Z, McCleskey SM, Anslyn EV, McDevitt JT (2005) Angew Chem Int Ed 44:6375
Wright AT, Anslyn EV, McDevitt JT (2005) J Am Chem Soc 127:17405
Wiskur S, Ait-Haddou H, Lavigne JJ, Anslyn EV (2001) Acc Chem Res 34:963
Schneider SE, O'Neil SN, Anslyn EV (2000) J Am Chem Soc 122:542
Baldini L, Wilson AJ, Hong J, Hamilton AD (2004) J Am Chem Soc 126:5658
Zhou H, Baldini L, Hong J, Wilson AJ, Hamilton AD (2006) J Am Chem Soc 128:2421
Wright AT, Anslyn EV (2004) Org Lett 6:1341
Goodey AP, McDevitt JT (2003) J Am Chem Soc 125:2870
Wei S, Jakusch M, Mizaikoff B (2006) Anal Chim Acta 578:50
Haupt K (2001) Analyst 126:747
Hirsch T, Kettenberger H, Wolfbeis OS, Mirsky VM (2003) Chem Commun, p 432
Greene NT, Morgan SL, Shimizu KD (2004) Chem Commun, p 1172
Greene NT, Shimizu KD (2005) J Am Chem Soc 127:5695
Rakow NA, Suslick KS (2000) Nature 406:710
Zhang C, Suslick KS (2005) J Am Chem Soc 127:11548
Zhang C, Bailey DP, Suslick KS (2006) J Agric Food Chem 54:4925
Reddy MM, Kodadek T (2005) Proc Natl Acad Sci 102:12672
Zimmerman R, Basabe-Desmonts L, van der Baan F, Reinhoudt DN, Crego-Calama M (2005) J Mater Chem 15:2772
Mayr T, Liebsch G, Klimant I, Wolfbeis OS (2002) Analyst 127:201
Mayr T, Igel C, Liebsch G, Klimant I, Wolfbeis OS (2003) Anal Chem 75:4389
Jain RK, Hamilton AD (2000) Org Lett 2:1721
Folmer-Andersen JF, Kitamura M, Anslyn EV (2006) J Am Chem Soc 128:5652
Stojanovic MN, Green EG, Semova S, Nikic DB, Landry DW (2003) J Am Chem Soc 125:6085
Wiskur SL, Floriano PN, Anslyn EV, McDevitt JT (2003) Angew Chem Int Ed 42:2070
McCleskey SC, Floriano PN, Wiskur SL, Anslyn EV, McDevitt JT (2003) Tetrahedron 59:10089
Rowan SJ, Cantrill SJ, Cousins GRL, Sanders JKM, Stoddart JF (2002) Angew Chem Int Ed 41:898
Buryak A, Severin K (2005) Angew Chem Int Ed 44:7935
Buryak A, Severin K (2006) J Comb Chem 8:540
Page NM (2005) Peptides 26:1356
Severini C, Improta G, Falconieri-Erspamer G, Salvadori S, Erspamer V (2002) Pharm Rev 54:285
Buryak A, Severin K (2005) J Am Chem Soc 127:3700
Zaubitzer F, Buryak A, Severin K (2006) Chem Eur J 12:3928
Lee JW, Lee J-S, Chang Y-T (2006) Angew Chem Int Edn 45:6485
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Collins, B.E., Wright, A.T., Anslyn, E.V. (2007). Combining Molecular Recognition, Optical Detection, and Chemometric Analysis. In: Schrader, T. (eds) Creative Chemical Sensor Systems. Topics in Current Chemistry, vol 277. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2007_114
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DOI: https://doi.org/10.1007/128_2007_114
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