Skip to main content

Part of the book series: Nato Science Series: IV: Earth and Environmental Science ((NAIV,volume 62))

Abstract

Aldehydes are emitted directly into the atmosphere from a variety of natural and anthropogenic sources and are also formed in situ from the atmospheric degradation of volatile organic compounds (VOCs). The atmospheric fate of aldehydes is controlled by photolysis and reaction with hydroxyl (OH) or nitrate (NO3) radicals and, in the case of unsaturated compounds, reaction with ozone (Atkinson, 1994). The photolysis of aldehydes is of particular importance because it is a source of free radicals in the troposphere, and thus may significantly influence the oxidizing capacity of the lower atmosphere (Finlayson-Pitts and Pitts, 1986).

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 299.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 379.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 379.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Atkinson, R; Gas-phase tropospheric chemistry of organic compounds, J. Phys. Chem. Ref. Data, Monograph 2 (1994)1–216.

    Google Scholar 

  • Becker, K.H. (Ed.); The European Photoreactor EUPHORE, Final Report of the EC Project EV5V-CT92–0059, Wuppertal (1996).

    Google Scholar 

  • Clifford, G.M.; Atmospheric chemistry of aromatic aldehydes, PhD thesis, University College Cork (2004).

    Google Scholar 

  • Finlayson-Pitts, B.J., J.N. Pitts Jr.; Atmospheric Chemistry, John Wiley, New York (1986)

    Google Scholar 

  • Magneron, I., R. Thévenet, A. Mellouki, G. Le Bras, G.K. Moortgat and K. Wirtz; A study of the photolysis and OH-initiated oxidation of acrolein and trns-crotonaldehyde, J. Phys. Chem. A 106 (2002) 2526.

    Article  CAS  Google Scholar 

  • Moortgat, G.K. (Ed.); Evaluation of radical sources in atmospheric chemistry through chamber and laboratory studies, Final Report of the EC Project ENV4-CT97–0419, Mainz (2000).

    Google Scholar 

  • Tadić, J., I. Juranić and G.K. Moortgat; Photoxidation of n-hexanal in air, Molecules, 6 (2001) 287–299.

    Google Scholar 

  • Thiault, G., A. Mellouki, G. Le Bras and K. Wirtz; The photolysis of aromatic aldehydes in The European Photoreactor, EUPHORE, 4th report, (2001), 29.

    Google Scholar 

  • Thiault, G., A. Mellouki, G. Le Bras; Kinetics of gas phase reactions of OH and Cl with aromatic aldehydes; Phys. Chem. Chem. Phys, 4 (2002) 2194–2199.

    CAS  Google Scholar 

  • Thiault, G., A. Mellouki , G. Le Bras,A. Chakir, N. Sokolowski-Gomez, D. Daumont; UV-absorption cross sections of benzaldehyde, ortho-, meta-, and para-tolualdehyde, J. Photochem. Photobiol. A: Chem. 162 (2004) 273.

    Article  CAS  Google Scholar 

  • Volkamer, R., U. Platt and K. Wirtz; OH reaction rate constants and photolysis frequencies of a series of aromatic aldehydes and phenols in The European Photoreactor, EUPHORE, 3rd report, (2000) 1.

    Google Scholar 

  • Wenger, J.C., S. Le Calvé, H.W. Sidebottom, K. Wirtz, M. Martin-Reviejo and J.A. Franklin; Photolysis of chloral under atmospheric conditions, Environ. Sci. Technol. 38 (2004) 831–837.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2006 Springer

About this paper

Cite this paper

Wenger, J.C. (2006). Chamber Studies on the Photolysis of Aldehydes Environmental. In: Barnes, I., Rudzinski, K.J. (eds) Environmental Simulation Chambers: Application to Atmospheric Chemical Processes. Nato Science Series: IV: Earth and Environmental Science, vol 62. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4232-9_8

Download citation

Publish with us

Policies and ethics