Skip to main content

Atmospheric Oxidation of the Chlorinated Solvents, 1,1,1-Trichloroethane, Trichloroethene and Tetrachloroethene

  • Conference paper
Environmental Simulation Chambers: Application to Atmospheric Chemical Processes

Part of the book series: Nato Science Series: IV: Earth and Environmental Science ((NAIV,volume 62))

Abstract

Chlorinated solvents are widely used in metal degreasing, dry cleaning, paint stripping, extraction of pharmaceuticals and foodstuffs, and electronic circuit board production (Sidebottom and Franklin, 1996). Emission data for trichloroethene (CHCl=CCl2) and tetrachloroethene (CCl2=CCl2) show that emissions of these compounds are declining steadily, largely as a result of constant improvements in the efficiency with which they are being used and recycled. While 1,1,1-trichloroethane (CH3CCl3) was formerly widely used as a solvent, it is now strictly regulated as an ozone-depleting compound under the Montreal Agreement. Despite the decline in emissions of these chlorinated solvents their atmospheric fate and impact is still of concern.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 299.00
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 379.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 379.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  • Atkinson R.; Gas-phase tropospheric chemistry of organic compounds, J. Phys. Chem. Ref. Data, Monograph no. 2 (1994).

    Google Scholar 

  • Kindler T.P., W.L. Chameides, P.H. Wine, D.M. Cunnold, F.N. Alyea and J.A. Franklin; The fate of atmospheric phosgene and the stratospheric chlorine loadings of its parent compounds: CC14, C2C14, C2HC13, CH3CCl3 and CHC13, J. Geophys. Res. 100 (Dl) (1995) 1235–1251.

    Article  CAS  Google Scholar 

  • Nelson L., I. Shanahan, H.W. Sidebottom, J. Treacy and O.J. Nielsen; Kinetics and mechanism for the oxidation of 1,1,1-trichloroethane, Int. J. Chem. Kinet. 22 (1990) 577–590.

    CAS  Google Scholar 

  • Platz J., O.J. Nielsen, J. Sehested and T.J. Wallington; Atmospheric chemistry of 1,1,1-trichloroethane: UV absorption spectra and self-reaction kinetics of CC13CH2 and CC13CH2O2 radicals, kinetics of the reactions of the CC13CH2O2 radicals with NO and NO2 and the fate of the alkoxy radical CC13CH2O, J. Phys. Chem. 99 (17) (1995) 6570–6579.

    Article  CAS  Google Scholar 

  • Sidebottom H., and J. Franklin; The atmospheric fate and impact of hydrofluorocarbons and chlorinated solvents, Pure and Appl. Chem. 68 (1996) 1757–1769.

    CAS  Google Scholar 

  • Talukdar R.K., A. Mellouki, J.B. Burkholder, M.K. Gilles, G. Le Bras and A.R. Ravishankara; Quantification of the tropospheric removal of chloral (CC13CHO): Rate coefficient for the reaction with OH, UV- absorption and quantum yields, J. Phys. Chem. 105 (2001) 5188–5196.

    CAS  Google Scholar 

  • Tuazon E.G., R. Atkinson, S.M. Aschmann, M.A. Goodman and A.M. Winer; Atmospheric reactions of chloroethenes with the OH radical, Int. J. Chem. Kinet. 20 (1988) 241–265.

    Article  CAS  Google Scholar 

  • Wenger J., S. Le Calvé, H.W. Sidebottom, K. Wirtz, M.M. Reviejo and J.A. Franklin; Photolysis of chloral under atmospheric conditions, Environ. Sci. Technol. 38 (2004) 831–837.

    Article  CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Editor information

Editors and Affiliations

Rights and permissions

Reprints and permissions

Copyright information

© 2006 Springer

About this paper

Cite this paper

Nolan, L., Guihur, AL., Manning, M., Sidebottom, H. (2006). Atmospheric Oxidation of the Chlorinated Solvents, 1,1,1-Trichloroethane, Trichloroethene and Tetrachloroethene. In: Barnes, I., Rudzinski, K.J. (eds) Environmental Simulation Chambers: Application to Atmospheric Chemical Processes. Nato Science Series: IV: Earth and Environmental Science, vol 62. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4232-9_14

Download citation

Publish with us

Policies and ethics