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Carbonaceous Onion-Like Particles: A Possible Component of the Interstellar Medium

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Natural Fullerenes and Related Structures of Elemental Carbon

Part of the book series: Developments in Fullerene Science ((DFUL,volume 6))

Abstract

A carbonaceous material formed from a hydrocarbon plasma called quenched carbonaceous composite (QCC) is shown to have functional groups that approximate the positions of the interstellar 217.5 nm absorption and the infrared emission features at 3.3—11.3 μm. A form of this material, called “dark-QCC” has abundant carbonaceous onion-like particles. We present the results of various experiments involving QCC and conjecture that the carbonaceous onion-like particles in QCC may be a good laboratory analog to the carrier of the interstellar absorption and emission features. A scenario for dust formation from carbonaceous onion-like particles is presented.

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References

  • Allain, T., Leach, S. and Sedlmayr, E. (1996) Photodestruction of PAHs in the interstellar medium. I. Photodissociation rates for the loss of an acetylenic group. Astron. Astrophys., 305, 602–615.

    CAS  Google Scholar 

  • Blakes, E.L.O., Bauschlicher, C. and Tielens, A.G.G.M. (2004) Models of the Unidentified Infrared Emission Features. In Astrophysics of Dust, A.N. Witt, G.C. Clayton and B.T. Draine, Eds., ASP Conf. Ser., 309, 731–753, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

  • Bradley, J., Dai, Z.R., Erni, R., Browning, N., Graham, G., Weber, P., Smith, J., Hutcheon, I., Ishii, H., Bajt, S., Floss, C., Stadermann, F. Sandford, S. (2005) An astronomical 2175 Å feature in interplanetary dust particles. Science, 307, 244–247.

    Article  CAS  Google Scholar 

  • Clayton, G.C., Gordon, K.D., Salama, F., Allamandola, L.J., Martin, P.G., Snow, T.P., Whittet, D.C.B., Witt, A.N. and Wolff, M.J. (2003) The role of polycyclic aromatic hydrocarbons in ultraviolet extinction. I. Probing small molecular polycyclic aromatic hydrocarbons. Astrophys. J., 592, 947–952.

    Article  CAS  Google Scholar 

  • de Heer, W.A. and Ugarte, D. (1993) Carbon onions produced by heat treatment of carbon soot and their relation to the 217.5 nm interstellar absorption feature. Chem. Phys. Lett., 207, 480–486.

    Article  Google Scholar 

  • Draine, B.T. (2003) Interstellar dust grains. Ann. Rev. Astron. Astrophys., 41, 241–289.

    Article  Google Scholar 

  • Drilling, J.S. and Schoenberner, D. (1989) On the nature of newly formed dust around the hydrogen-deficient star V348 Sagittarii. Astrophys. J., 343, L45–L48.

    Article  CAS  Google Scholar 

  • Duley, W.W. and Lazarev, S. (2004) Ultraviolet absorption in amorphous carbons: Polycyclic aromatic hydrocarbons and the 2175 Å extinction feature. Astrophys. J., 612, L33–L35.

    Article  CAS  Google Scholar 

  • Fitzpatrick, E.L. (2004) Interstellar extinction in the Milky Way galaxy. In Astrophysics of Dust, A.N. Witt, G.C. Clayton and B.T. Draine, Eds., ASP Conf. Ser., 309, 33–55, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

  • Gehrz, R.D. (1989) Sources of stardust in the galaxy. In Interstellar Dust, L.J. Allamandola and A.G.G.M. Tielens, Eds., IAU Symp., 135, 445–453, Kluwer Academic Publishers.

    Google Scholar 

  • Goto, M., Maihara, T., Terada, H., Kaito, C., Kimura, S. and Wada, S. (2000) Infrared spectral sequence of quenched carbonaceous composite subjected to thermal annealing. Astron. Astrophys. Suppl. Ser., 141, 149–156.

    Article  CAS  Google Scholar 

  • Hecht, J.H., Holm, A.V., Donn, B. and Wu, C.-C. (1984) The dust around R Coronae Borealis type stars. Astrophys. J., 280, 228–234.

    Article  CAS  Google Scholar 

  • Henning, T., Jäger, C. and Mutschke, H. (2004) Laboratory studies of carbonaceous dust analogs. In Astrophysics of Dust, A.N. Witt, G.C. Clayton and B.T. Draine, Eds., ASP Conf. Ser., 309, 603–628, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

  • Hudgins, D. and Allamandola, L.J. (2004) Polycyclic aromatic hydrocarbons and infrared astrophysics: The state of the PAH model and a possible tracer of nitrogen in carbon-rich dust. In Astrophysics of Dust, A.N. Witt, G.C. Clayton and B.T. Draine, Eds., ASP Conf. Ser., 309, 665–688, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

  • Inagaki, M., Kaneko, K. and Nishizawa, T. (2004) Nanocarbons-recent research in Japan. Carbon, 42, 1401–1417.

    Article  CAS  Google Scholar 

  • Jones, A.P. (1997) The lifecycle of interstellar dust. In From Stardust to Planetesimals, Y.J. Pendleton and A.G.G.M. Tielens, Eds., ASP Conf. Ser., 122, 97–106, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

  • Kwok, S. (2004) The synthesis of organic and inorganic compounds in evolved stars, Nature, 430, 985–991.

    Article  CAS  Google Scholar 

  • Mennella, V. (2004) Laboratory simulation of processing grains. In Astrophysics of Dust, A.N. Witt, G.C. Clayton and B.T. Draine, Eds., ASP Conf. Ser., 309, 629–648, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

  • Mennella, V., Colangeli, L., Palumbo, P., Rotundi, A., Schutte, W. and Bussoletti, E. (1996) Activation of an ultraviolet resonance in hydrogenated amorphous carbon grains by exposure to ultraviolet radiation. Astrophys. J., 464, L191–L194.

    Article  CAS  Google Scholar 

  • Mennella, V., Baratta, G.A., Colangeli, L., Palumbo, P., Rotundi, A., Bussoletti, E. and Strazzulla, G. (1997) Ultraviolet spectral changes in amorphous carbon grains induced by ion irradiation. Astrophys. J., 481, 545–549.

    Article  CAS  Google Scholar 

  • Mennella, V., Brucato, J.R., Colangeli, L. and Palumbo, P. (2002) C—H bond formation in carbon grains by exposure to atomic hydrogen: The evolution of the carrier of the interstellar 3.4 micron band. Astrophys. J., 569, 531–540.

    Article  CAS  Google Scholar 

  • Oberlin, A. (1989) High-resolution TEM studies of carbonization and graphitization. In Chemistry and Physics of Carbon, P.L. Walker, Ed., 22, 1–143, Marcel Dekker, Inc., New York, USA.

    Google Scholar 

  • Oberlin, A. and Bonmamy, S. (2001) Carbonization and graphitization. In Graphite and Precursors, P. Delhaés, Ed., 199–220, Gordon and Breach Science Publishers, Australia.

    Google Scholar 

  • Onaka, T., Yamamura, I., Tanabe, T., Roellig, T.L. and Yuen, L. (1996) Detection of the midinfrared unidentified bands in the diffuse galactic emission by IRTS, Publ. Astron. Soc. Japan, 48, L59–L63.

    Google Scholar 

  • Papoular, R., Conard, J., Guillois, O., Nenner, I., Reynaud, C. and Rouzaud, J.-N. (1996) A comparison of solid-state carbonaceous models of cosmic dust, Astron. Astrophys., 315, 222–236.

    CAS  Google Scholar 

  • Peeters, E., Allamandola, L.J., Hudgins, D.M., Hony, S. and Tielens, A.G.G.M. (2004) The unidentified infrared features after ISO. In Astrophysics of Dust, A.N. Witt, G.C. Clayton and B.T. Draine, Eds., ASP Conf. Ser., 309, 141–162, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

  • Rotundi, A., Rietmeijer, F.J.M., Colangeli, L., Mennella, V., Palumbo, P. and Bussoletti, E. (1998) Identification of carbon forms in soot materials of astrophysical interest. Astron. Astrophys., 329, 1087–1096.

    CAS  Google Scholar 

  • Rouleau, F., Henning, T. and Stognienko, R. (1997) Constraints on the properties of the 2175 Å interstellar feature carrier. Astron. Astrophys., 322, 633–645.

    Google Scholar 

  • Sakata, A. (1980) On the formation of interstellar linear molecules. In Interstellar Molecules, B.H. Andrew, Ed., IAU Symp., 87, 325–329, Reidel, Dordrecht, the Netherlands.

    Google Scholar 

  • Sakata, A., Wada, S., Okutsu, Y., Shintani, H. and Nakada, Y (1983) Does a 2,200 A hump observed in an artificial carbonaceous composite account for UV interstellar extinction? Nature, 301, 493–494.

    Article  CAS  Google Scholar 

  • Sakata, A., Wada, S., Onaka, T. and Tokunaga, A.T. (1987) Infrared spectrum of quenched carbonaceous composite (QCC). II — 2 A new identification of the 7.7 and 8.6 micron unidentified infrared emission bands. Astrophys. J., 320, L63–L67.

    Article  CAS  Google Scholar 

  • Sakata, A., Wada, S., Onaka, T. and Tokunaga, A.T. (1990) Quenched carbonaceous composite. III — Comparison to the 3.29 micron interstellar emission feature. Astrophys. J., 353, 543–548.

    Article  CAS  Google Scholar 

  • Sakata, A., Wada, S., Tokunaga, A.T., Narisawa, T., Nakagawa, H. and Ono, H. (1994) Ultraviolet spectra of quenched carbonaceous composite derivatives: Comparison to the ’217 nanometer’ interstellar absorption feature. Astrophys. J., 430, 311–316.

    Article  CAS  Google Scholar 

  • Schnaiter, M., Mutschke, H., Dorschner, J., Henning, T. and Salama, F. (1998) Matrix-isolated nano-sized carbon grains as an analog for the 217.5 nanometer feature carrier. Astrophys. J., 498, 486–496.

    Article  CAS  Google Scholar 

  • Scott, A. and Duley, W.W. (1996) The decomposition of hydrogenated amorphous carbon: A connection with polycyclic aromatic hydrocarbon molecules, Astrophys. J., 472, L123–125.

    Article  CAS  Google Scholar 

  • Sellgren, K. (2001) Aromatic hydrocarbons, diamonds, and fullerenes in interstellar space: Puzzles to be solved by laboratory and theoretical astrochemistry. Spectrochim. Acta, A, 57, 627–642.

    Article  CAS  Google Scholar 

  • Tokunaga, A.T. (1997) A summary of the “UIR” bands. In Diffuse Infrared Radiation and the IRTS, H. Okuda, T. Matsumoto and T. Rollig, Eds., ASP Conf. Ser., 124, 149–160, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

  • Tomita, S., Sakurai, T., Ohta, H., Fujii, M. and Hayashi, S. (2001) Structure and electronic properties of carbon onions. J. Chem. Phys., 114, 7477–7482.

    Article  CAS  Google Scholar 

  • Tomita, S., Fujii, M. and Hayashi, S. (2004) Defective carbon onions in interstellar space as the origin of the optical extinction bump at 217.5 nanometers. Astrophys. J., 609, 220–224.

    Article  CAS  Google Scholar 

  • van Winckel, H. (2003) Post-AGB stars. Ann. Rev. Astron. Astrophys., 41, 391–427.

    Article  Google Scholar 

  • Vuong, M.H. and Foing, B.H. (2000) Dehydrogenation of polycyclic aromatic hydrocarbons in the diffuse interstellar medium. Astron. Astrophys., 363, L5–L8.

    CAS  Google Scholar 

  • Wada, S., Tokunaga, A.T., Kaito, C. and Kimura, S. (1998) Fitting the unusual UV extinction curve of V348 SGR. Astron. Astrophys., 339, L61–L64.

    CAS  Google Scholar 

  • Wada, S., Kaito, C., Kimura, S., Ono, H. and Tokunaga, A.T. (1999) Carbonaceous onionlike particles as a component of interstellar dust. Astron. Astrophys., 345, 259–264.

    CAS  Google Scholar 

  • Waters, L.B.F.M. (2004) Dust in evolved stars. In Astrophysics of Dust, A.N. Witt, G.C. Clayton and B.T. Draine, Eds., ASP Conf. Ser., 309, 229–244, Astronomical Society of the Pacific, San Francisco, California, USA.

    Google Scholar 

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Wada, S., Tokunaga, A.T. (2006). Carbonaceous Onion-Like Particles: A Possible Component of the Interstellar Medium. In: Natural Fullerenes and Related Structures of Elemental Carbon. Developments in Fullerene Science, vol 6. Springer, Dordrecht. https://doi.org/10.1007/1-4020-4135-7_3

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