Skip to main content
SpringerLink
Log in

Concept of Ion Association in the Theory of Electrolyte Solutions

Application of the multidensity integral equation theory of associating fluids

  • Conference paper
Ionic Soft Matter: Modern Trends in Theory and Applications

Part of the book series: NATO Science Series II: Mathematics, Physics and Chemistry ((NAII,volume 206))

Abstract

Analytical solution of the associative mean spherical approximation (AMSA) and the modified version of the mean spherical approximation — the mass action law (MSA-MAL) approach for ion and ion-dipole models are used to revise the concept of ion association in the theory of electrolyte solutions. In the considered approach in contrast to the traditional one both free and associated ion electrostatic contributions are taken into account and therefore the revised version of ion association concept is correct for weak and strong regimes of ion association. It is shown that AMSA theory is more preferable for the description of thermodynamic properties while the modified version of the MSA-MAL theory is more useful for the description of electrical properties. The capabilities of the developed approaches are illustrated by the description of thermodynamic and transport properties of electrolyte solutions in weakly polar solvents. The proposed theory is applied to explain the anomalous properties of electrical double layer in a low temperature region and for the treatment of the effect of electrolyte on the rate of intramolecular electron transfer. The revised concept of ion association is also used to describe the concentration dependence of dielectric constant in electrolyte solutions.

This is a preview of subscription content, log in via an institution to check access.

Access this chapter

Log in via an institution
Chapter
USD 29.95
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
eBook
USD 84.99
Price excludes VAT (USA)
  • Available as PDF
  • Read on any device
  • Instant download
  • Own it forever
Softcover Book
USD 109.99
Price excludes VAT (USA)
  • Compact, lightweight edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info
Hardcover Book
USD 109.99
Price excludes VAT (USA)
  • Durable hardcover edition
  • Dispatched in 3 to 5 business days
  • Free shipping worldwide - see info

Tax calculation will be finalised at checkout

Purchases are for personal use only

Institutional subscriptions

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. Bjerrum, N. Mat.-Fys. Medd. K. Dan. Vidensk, Selsk, 1926, 7, p. 1.

    Google Scholar 

  2. Debye, P., and Hückel, E. Physik. Z., 1923, 24, p. 185.

    Google Scholar 

  3. Barthel, J., Krienke, H., and Kunz, W. (1998). Physical Chemistry of Electrolyte Solutions — Modern Aspects. New York: Springer.

    Google Scholar 

  4. Waisman, E., and Lebowitz, J.L. J. Chem. Phys., 1972, 56, p. 3086, 3093.

    Article  ADS  Google Scholar 

  5. Blum, L. Mol. Phys., 1975, 30, p. 1529.

    Article  ADS  Google Scholar 

  6. Krienke, H., Barthel, J., Holovko, M., Protsykevich, J.A., and Kalyuzhnyi, Yu. J. Mol. Liq., 2000, 87, p. 191.

    Article  Google Scholar 

  7. Holovko, M.F., and Kalyuzhnyi, Yu.V. Mol. Phys., 1991, 73, p. 1145.

    Article  ADS  Google Scholar 

  8. Blum, L., and Bernard, O. J. Stat. Phys., 1995, 79, p. 569.

    Article  MATH  ADS  Google Scholar 

  9. Wertheim, M.S. J. Stat. Phys., 35, p. 19, 35.

    Google Scholar 

  10. Wertheim, M.S. J. Stat. Phys., 1986, 42, p. 459, 477.

    Article  MathSciNet  ADS  Google Scholar 

  11. Holovko, M.F. Cond. Matter Phys., 1999, 2, No. 2(18), p.205.

    Google Scholar 

  12. Holovko, M.F. J. Mol. Liq., 2002, 96–97, p. 65.

    Article  Google Scholar 

  13. Barthel, J., Krienke, H., Holovko, M.F., Kapko, V.J., and Protsykevich, J.A. Cond. Matter Phys., 2000, 3, No. 3(23), p. 657.

    Google Scholar 

  14. Barthel, J., Krienke, H., Neuder, R., and Holovko, M.F. Fluid Phase Eq., 2002, 194–197, p. 107.

    Article  Google Scholar 

  15. Holovko, M.F., and Kapko, V.J. Cond. Matter Phys., 1998, 1, No. 2(14), p. 239.

    Google Scholar 

  16. Holovko, M.F., and Kapko, V.J. J. Mol. Liq., 2000, 87, p. 109.

    Article  Google Scholar 

  17. Kalyuzhnyi, Yu., Holovko, M.F., and Haymet, A.D.J. J. Chem. Phys., 1991, 95, p. 1951.

    Article  Google Scholar 

  18. Kalyuzhnyi, Yu., and Holovko, M.F. J. Mol. Phys., 1993, 80, p. 1165.

    Article  ADS  Google Scholar 

  19. Ebeling, W. Z. Phys. Chem. (Leipzig), 1968, 238, p. 400.

    Google Scholar 

  20. Falkenhagen, H., Ebeling, W., and Hertz, H.G. (1971). Theorie der Elektrolyte. Leipzig: S. Hizzel-Verlag.

    Google Scholar 

  21. Vakarin, E.V., Holovko, M.F., and Piotrowiak, P. Chem. Phys. Let., 2002, 363, p. 7.

    Article  ADS  Google Scholar 

  22. Kapko, V.I., Holovko, M.F., Miller, J., and Piotrowiak, P. J. Phys. Chem. B, (in press).

    Google Scholar 

  23. Holovko, M., Kapko, V.I., Henderson, D., and Boda, D. Chem. Phys. Let., 2001, 341, p. 363.

    Article  ADS  Google Scholar 

  24. Holovko, M., Kapko, V., Henderson, D., and Boda, D. (in preparation).

    Google Scholar 

  25. Werthein, M.S. J. Chem. Phys., 1986, 85, p. 2929.

    Article  ADS  Google Scholar 

  26. Bernard, O., and Blum, L. J. Chem. Phys., 1996, 104, p. 4746.

    Article  ADS  Google Scholar 

  27. Carnahan, N.F., and Starling, K.E. J. Chem. Phys., 1969, 51, p. 635.

    Article  ADS  Google Scholar 

  28. Blum, L., and Hoye, J.S. J. Phys. Chem., 1977, 81, p. 134.

    Google Scholar 

  29. Barthel, J., Neuder, R., Poepke, H., and Wittmann, H. J. Solution Chem., 1998, 27, p. 1055.

    Article  Google Scholar 

  30. Barthel, J., Neuder, R., Poepke, H., and Wittmann, H. J. Solution Chem., 1999, 28, p. 489, 1263, 1277.

    Article  Google Scholar 

  31. Fuoss, R.M., and Kraus, C.A. J. Am. Chem. Soc., 1933, 55, p. 2387.

    Article  Google Scholar 

  32. Chhih, A., Turq, P., Bernard, O., Barthel, J., and Blum, L. Ber. Bunsenges Phys. Chem., 1994, 98, p. 1516.

    Google Scholar 

  33. Turq, P., Blum, L., Bernard, O., and Kunz, W. J. Phys. Chem., 1995, 99, p. 822.

    Article  Google Scholar 

  34. Delsignore, M., Farber, H., and Petrucci, S. J. Phys. Chem., 1985, 89, p. 4968.

    Article  Google Scholar 

  35. Marcus, R.A., and N. Sutin, Biochim. Biophys. Acta, 1985, 811, p. 285.

    Google Scholar 

  36. Marcus, R.A. J. Phys. Chem., 1956, 24, p. 966.

    Article  Google Scholar 

  37. Perng, B.C., Newton, M.D., Raineri, F.O., and Friedman, H.L. J. Chem. Phys., 1996, 104, p. 7153,7177.

    Article  ADS  Google Scholar 

  38. Rossky, P.J., and Simon, J.D. Nature, 1999, 370, p. 263.

    Article  ADS  Google Scholar 

  39. Piotrowiak, P., and Miller, J.R. J. Phys. Chem., 1993, 97, p. 13052.

    Article  Google Scholar 

  40. Closs, C.L., and Miller, J.R. Science, 1988, 240, p. 440.

    Article  ADS  Google Scholar 

  41. Holovko, M.F., Kapko, V.I., and Piotrowiak, P. J. Phys. Chem B, (in press).

    Google Scholar 

  42. Nielson, R.M., Mc Manis, G.E., Sofford, L.K., and Weaver, M.J. J. Phys. Chem, 1989, 93, p. 2152.

    Article  Google Scholar 

  43. Kuznetsov, A.M., Pheklps, P.K., and Weaver, M.J. Int. J. Chem. Kinetic, 1990, 22, p. 815.

    Article  Google Scholar 

  44. Holovko, M.F., Kapko, V.I., and Piotrowiak, P., (in preparation).

    Google Scholar 

  45. Schatz, T.R., Kobetic, R., and Piotrowiak, P. J. Photochem and Photobiol. A., 1997, 105, p. 249.

    Article  Google Scholar 

  46. Piotrowiak, P. In Photochemistry Methods for the Study of Electron Transfer. Advances in Chemistry, 1998, No. 254, p. 219.

    Article  Google Scholar 

  47. Henderson, D., Blum, L., and Lebowitz, J.L. J. Electroanal. Chem., 1979, 102, p. 315.

    Article  Google Scholar 

  48. Landau, L.D., and Lifshitz, E.M. (1960). Electrodynamic of Continuous Media. Oxford: Pergamon Press.

    Google Scholar 

  49. Blum, L. J. Phys. Chem, 1977, 81, p. 136.

    Article  Google Scholar 

  50. Crozier, P.S., Rowley, R.L., Henderson, D., and Boda, D. Chem. Phys. Lett, 2000, 325, p. 675.

    Article  ADS  Google Scholar 

  51. Henderson, D. J. Mol. Liq., 2001, 92, p. 29.

    Article  Google Scholar 

  52. Boda, D., Chan, K.Y., Henderson, D., and Wasan, D.T. Chem. Phys. Lett., 1999, 308, p.473.

    Article  ADS  Google Scholar 

  53. Henderson, D., Abraham, F.F., and Barker, J.A. Mol. Phys., 1976, 31, p. 1291.

    Article  ADS  Google Scholar 

  54. Holovko, M.F., and Vakarin, E.V. Mol. Phys., 1995, 84, p. 1057.

    Article  ADS  Google Scholar 

  55. Golovko, M.F., and Yukhnovsij, I.R. (1985). In the Chemical Physics of Solvation, part A, chapter 6, ed. by Dogonadze, R.R., Kalman, E., Kornyshev, A.A. and Ulstrup, J. Amsterdam: Elsevier.

    Google Scholar 

  56. Klimontovich, Yu.L., Wilhelmsson, H., Yakimenko, I.P., and Zagorodny, A.G. (1990). Statistical Theory of Plasma-Molecular Systems. Moskov: Publishing of Moskov University.

    Google Scholar 

  57. Jancovici, B. J. Stat. Phys., 1982, 28, p. 43.

    Article  MathSciNet  ADS  Google Scholar 

  58. di Caprio, D., Stafiej, J., and Badiali, J.P. Mol. Phys, 2003, 101, p. 3197.

    Article  ADS  Google Scholar 

  59. Blum, L., and Henderson, D. J. Chem. Phys., 1981, p. 74.

    Google Scholar 

  60. Holovko, M.F., Kapko, V., Henderson, D., and Boda, D., (in preparation).

    Google Scholar 

  61. Blum, L. Chem. Phys. Lett, 1974, 26 p. 200; J. Chem. Phys., 1974, 61 p. 2129.

    Article  ADS  Google Scholar 

  62. Adelman, S.A., and Deutch, J.M. J. Chem. Phys., 1974, 60 p. 3935.

    Article  ADS  Google Scholar 

  63. Yukhnovsij, I.R., and Holovko, M.F. (1980). Statistical Theory of Classical Equilibrium Systems. Kyiv: Naukova dumka.

    Google Scholar 

  64. Hoye, J.S., and Lomba, E. J. Chem. Phys., 1988, 88 p. 5790; Hoye, J.S., Lomba, E., and Stell, G. J. Chem. Phys., 1988, 89, p. 7642.

    Article  ADS  Google Scholar 

  65. Blum, L., and Wei, D.Q. J. Chem. Phys., 1987, 87, p. 555; Wei, D.Q., and Blum, L. J. Chem. Phys., 1987, 87, p. 2999.

    Article  ADS  Google Scholar 

  66. Golovko, M.F., and Protsykevich, I.A. Chem. Phys. Lett., 1987, 142, p. 463; J. Stat. Phys., 1989, 54, p. 707.

    Article  ADS  Google Scholar 

  67. Kalyuzhnyi, Yu.V., Protsykevich, J.A., and Holovko, M.F. Chem. Phys. Lett., 1993, 215, p. 1.

    Article  ADS  Google Scholar 

  68. Holovko, M.F., and Kapko, V.I. J. Chem. Phys., (in press).

    Google Scholar 

  69. Kapko, V.J. (2001). Dissertation. Lviv.

    Google Scholar 

  70. Hoye, J.S., and Stell, G. J. Chem. Phys., 1977, 67, p. 439.

    Article  ADS  Google Scholar 

  71. Kalyuzhnyi, Yu.V., and Holovko, M.F. J. Chem. Phys., 1998, 108, p. 3709.

    Article  ADS  Google Scholar 

  72. Mansoori, G.A., Carnahan, N.F., Starling, K.E., and Leland, T.W. J. Chem. Phys., 1971, 54, p. 1523.

    Article  ADS  Google Scholar 

  73. Kalyuzhnyi, Yu.V. Mol. Phys., 1998, 94, p. 735.

    Article  ADS  Google Scholar 

  74. Adelman, S.A. J. Chem. Phys., 1976, 64, p. 724.

    Article  MathSciNet  ADS  Google Scholar 

  75. Wertheim, M. J. Chem. Phys., 1971, 55, p. 4291.

    Article  ADS  Google Scholar 

  76. Lileev, A.S., Balakaeva, I.V., and Lyashchenko, A.K. Russian J. inorg. Chem., 1998, 43, p. 960.

    Google Scholar 

  77. Holovko, M.F., Kapko, V.I., and Lyashchenko, A.K. (in preparation).

    Google Scholar 

  78. Holovko, M.F., Kapko, V.I., Krienke, A., and Barthel, J. (in preparation).

    Google Scholar 

  79. Buchner, R., Chen, T., and Hefter, G. J. Phys. Chem. B., 2004, 108, p. 2365.

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Institute for Condensed Matter Physics of the National Academy of Sciences of Ukraine, 1 Svientsitskii Str., 79011, Lviv, Ukraine

    M. Holovko

Authors
  1. M. Holovko
    View author publications

    You can also search for this author in PubMed Google Scholar

Editor information

Editors and Affiliations

  1. Brigham Young University, Provo, USA

    Douglas Henderson  & Andrij Trokhymchuk  & 

  2. Institute for Condensed Matter Physics, National Academy of Sciences of Ukraine, Lviv, Ukraine

    Myroslav Holovko  & Andrij Trokhymchuk  & 

Rights and permissions

Reprints and permissions

Copyright information

© 2005 Springer

About this paper

Cite this paper

Holovko, M. (2005). Concept of Ion Association in the Theory of Electrolyte Solutions. In: Henderson, D., Holovko, M., Trokhymchuk, A. (eds) Ionic Soft Matter: Modern Trends in Theory and Applications. NATO Science Series II: Mathematics, Physics and Chemistry, vol 206. Springer, Dordrecht. https://doi.org/10.1007/1-4020-3659-0_3

Download citation

Publish with us

Policies and ethics

Search

Navigation