Abstract
The layering of like-charged particles or macroions confined by two plane-parallel and two inclined surfaces is studied using a canonical Monte Carlo method combined with a simulation cell that contains both the confined and bath regions. The macroion solution is modelled within a one-component fluid approach that in an effective way incorporates a conventional double layer repulsion due to the ions of suspending electrolyte as well as an extra contribution due to the discrete nature of an aqueous solvent. The plane parallel and wedge-shaped geometries mimic the confinements that naturally occur in large number of systems widely known as colloidal dispersions. The effects of macroion charge, macroion and electrolyte concentrations on the particle layering and in-layer structuring are analyzed. The relation of obtained results to experiments on confined ionic micelle solutions and suspensions of charged polysterene spheres is discussed.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Nikolov, A.D., Wasan, D.T. J. Colloid Interface Sci., 1989, 133, p. 1.
Nikolov, A.D., Wasan, D.T., Denkov, N.D., Kralchevsky, P.A., Ivanov, I.B. Progr. Colloid Polym. Sci., 1990, 82, p. 87.
Nikolov, A.D., Wasan, D.T. Langmuir, 1992, 8, p. 2985.
Wasan, D.T., Nikolov, A.D., Lobo, L.A., Koczo, K., Edwards, D.A. Progr. Surface Sci., 1992, 39, p. 119.
Koczo, K., Nikolov, A.D., Wasan, D.T., Borwankar, R.P., Gonsalves, A. Layering of Sodium Caseinate Submicelles in Thin Liquid Films — A New Stability Mechanism for Food Dispersions. J. Colloid Interface Sci., 1996, 178, p. 694.
Nikolov, A.D., Kralchevsky, P.A., Ivanov, I.B., Wasan, D.T. J. Colloid Interface Sci., 1989, 133, p. 13.
Kralchevsky, P.A., Nikolov, A.D., Wasan, D.T., Ivanov, I.B. Langmuir, 1990, 6, p. 1180.
Bergeron, V., Radke, C.J. Langmuir, 1992, 8, p. 3020.
Richetti, P., Kékicheff, P. Phys. Rev. Lett., 1992, 68, p. 1951.
Wasan, D.T., Nikolov, A.D. In: Supramolecular in Confined Geometries, S. Manne and G. Warr, Eds., 1999, ACS Symposium Series No. 736, p. 40.
Wasan, D.T., Nikolov, A.D., Henderson, D., Trokhymchuk, A. (2002). Encyclopedia of Surface and Colloid Science, p. 1181. New York: Marcel Dekker.
Parsegian, V.A., Brenner, S.L. The Role of Longe Range Forces in Ordered Arrays of Tobacco Mosaic Virus. Nature, 1976, 259, p. 632.
Furusawa, K., Tomotsu, N. Direct Observation Studies for the Structure of the Electrical Double Layer of Concentrated Monodisperse Latices. J. Colloid Interface Sci., 1983, 92, p. 504.
Trokhymchuk, A., Henderson, D., Nikolov, A., Wasan, D.T. J. Phys. Chem., 2003, 107, p. 3927.
Henderson, D., Trokhymchuk, A., Nikolov, A., Wasan, D.T. Ind. Eng. Chem. Res., 2005, 44, p. 1175.
Trokhymchuk, A., Henderson, D., Nikolov, A. and Wasan, D.T. Langmuir, 2005, in press.
Derjaguin, B., Landau, L. Acta. Phys. Chim. URSS, 1941, 14, p. 633.
Verwey, E.J.W., Overbeek, J.Th.G. (1948). Theory of the Stability of Lyophobic Colloids, Amsterdam: Elsevier.
Henderson, D., Lozada-Cassou, M. J. Colloid Interface Sci., 1986, 114, p. 180.
Zhang, L., Davis, H.T. and White, H.S. J. Chem. Phys., 1993, 98, p. 5793.
Murray, C.A., Van Winkle, D.H. Phys. Rev. Lett., 1987, 58, p. 1200.
Pieransky, P., Strzelecki, L. and Pansu, B. Phys. Rev. Lett., 1983, 50, p. 900.
Reiss-Husson, F., Luzzati, V. J. Phys. Chem., 1964, 68, p. 3504.
Sasaki, T.; Hattori, M., Sasaki, J., Nukina, K. Bulletin of the Chem. Soc. of Japan 1975, 48, p. 1397.
Hartley, G.S. (1936). Aqueous Solutions of Paraffin-Chain Salts. Paris: Hermann.
Israelachvili, J.N. (1992). Intermolecular and Surface Forces, 2nd edition. London: Academic Press.
Sogami, I., Ise, N. J. Chem. Phys., 1984, 81, p. 6329.
Spalla, O., Belloni, L. Phys. Rev. Lett., 1995, 74, p. 2515.
Ise, N., Smalley, M.V. Phys. Rev. B, 1994, 50, p. 16722.
Ito, K., Yoshida, H., Ise, N. Science, 1994, 263, p. 66.
Larsen, A.E., Grier, D.G. Nature, 1997, 385, p. 230.
Crocker, J.C.; Grier, D.G. Phys. Rev. Lett., 1996, 77, p. 1897.
Ornstein, L.S. and Zernike, F. Proc. Acad. Sci. Amsterdam, 1914, 17, p. 793.
Attard, P., Bernard, D., Ursenbach, C., Patey, G.N. Phys. Rev. A, 1991, 44, p. 8224.
Henderson, D. (1991). 11th Symposium on Thermophysical Properties, Boulder CO, June 23–27; Fluid Phase Equil., 1992, 76, p. 1; J. Chem. Phys., 1992, 97, p. 1266.
Hansen, J.P., and McDonald, I.R. (1986). Theory of Simple Liquids. New York: Academic Press.
Barker, J.A. and Henderson, D. Rev. Mod. Phys., 1976, 48, p. 587.
Blum, L., Hye, J.S. J. Chem. Phys., 1977, 81, p. 1311.
Henderson, D. J. Colloid Interface Sci., 1988, 121, p. 486.
Roth, R., Evans, R., Dietrich, S. Phys. Rev. E, 2000, 62, p. 5360.
Asakura, S., Oosawa, J. J. Chem. Phys., 1954, 22 p. 1255.
Trokhymchuk, A., Henderson, D., Wasan, D. J. Colloid Interface Sci., 1999, 210, 320.
Trokhymchuk, A., Henderson, D., Nikolov, A., Wasan, D.T. Langmuir, 2001, 17, p. 4940.
Trokhymchuk, A., Holovko, M.F., Henderson, D. Molec. Phys., 1993, 80, 1009.
Imhof, A., Dhont, J.K.G. Phys. Rev. E, 1995, 52, p. 6344.
Tohver, V., Smay, J.E., Braem, A., Braun, P.V., Lewis, J.A. Proc. Natl. Acad. Sci., 2001, 98, p. 8950.
Pollard, M.L., Radke, C.J. J. Chem. Phys., 1994, 101, p. 6979.
Pashley, R.M., Ninham, B.W. J. Phys. Chem., 1987, 91, p. 2902.
Boda, D., Chan, K-Y., Henderson, D., Wasan, D.T., Nikolov, A.D. Langmuir, 1999, 15, p. 4311.
Garibay-Alonso, R., Mendez-Alcaraz, J.M., Klein, R. Physica A, 1997, 235, p. 159.
Trokhymchuk, A., Henderson, D., Nikolov, A., Wasan, D.T. Phys. Rev. E, 2001, 64, 012401.
Trokhymchuk, A., Henderson, D., Nikolov, A., Wasan, D.T. J. Colloid Interface Sci., 2001, 243, p. 116.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2005 Springer
About this paper
Cite this paper
Trokhymchuk, A.D., Henderson, D., Wasan, D.T., Nikolov, A. (2005). Macroions Under Confinement. In: Henderson, D., Holovko, M., Trokhymchuk, A. (eds) Ionic Soft Matter: Modern Trends in Theory and Applications. NATO Science Series II: Mathematics, Physics and Chemistry, vol 206. Springer, Dordrecht. https://doi.org/10.1007/1-4020-3659-0_10
Download citation
DOI: https://doi.org/10.1007/1-4020-3659-0_10
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-3662-0
Online ISBN: 978-1-4020-3659-0
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)