Abstract
The growth of fullerene C60 films on InP(001)-(2×4) was studied by a set of surface science techniques under ultra-high vacuum (UHV) conditions. Spectral signature measured by photoelectron and electron energy-loss spectroscopies (UPS, XPS, EELS, HREELS) corresponds to that of bulk C60 both at low (1–2 monolayers (ML)) and high (10 ML) coverage. The result shows a weak bonding, most probably van der Waals interaction, at the molecule-substrate interface. Spectroscopic and microscopic data indicate, that C60 forms 3D clusters at the initial stages of deposition. Electron diffraction (LEED) and tunnelling microscopy (STM) measurements reveal, that further molecule deposition leads to the formation of a well ordered single domain film. From the analysis of our microscopic data a C60-film structure with fcc (111) orientation follows.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
H.W. Kroto, J.R. Heath, S.C. O’Brien, R.F. Curl, and R.E. Smalley, Nature 318 (1985), 162
H.W. Kroto Science 242 (1988) 1139
W. Kratschmer, L.D. Lamb, K. Fostiropoulos, and D.R. Huffman, Nature 347 (1990), 354
H. Xu, D.M. Chen, and W.N. Creager, Physical Review Letters, 70 (1993) 1850
T. Sato, T. Sueyoshi, M. Iwatsuki, Surface Science, 321 (1994) L137
J. Schmidt, M.R.C. Hunt, P. Miao, and R.E. Palmer, Physical Review B, 56 (1997) 9918
X.D. Wang, T. Hashizume, H. Shinohara, Y. Saito, Y. Nishina, and T. Sakurai, Physical Review B, 47 (1993) 15923
Y.Z. Li, M. Chander, J.C. Patrin, J.H. Weaver, L.P.F. Chibante, and R.E. Smalley, Science 253 (1991) 429
Y.Z. Li, J.C. Patrin, M. Chander, J.H. Weaver, L.P.F. Chibante, and R.E. Smalley, Science 252 (1991) 547
T. Sakurai, Q. Xue, T. Hashizume, and Y. Hasegawa, J. Vac. Sci. Technol. B, 15 (1997) 1628
C.D. MacPherson, R.A. Wolkow, C.E.J. Mitchell, and A.B. McLean, Physical Review Letters, 77 (1996) 691
W.G. Schmidt, F. Bechstedt, N. Esser, M. Pristovsek, Ch. Schultz, and W. Richter, Physical Review B, 57 (1998) 14596
Y. Chao, K. Svensson, D. Radosavkié, V.R. Dhanak, L. Šiller, and M.R.C. Hunt, Physical Review B, 64 (2001) 235331
H. Ibach, D.L. Mills, Electron energy loss spectroscopy and surface vibrations, Academic Press, New York, 1982
R. Unwin, Spectra Presenter, Ver.7.0, 1997 Razor Library software designed by Spectrum Square Associates B.G. Frederick, G.L. Nyberg and N.V. Richardson, Journal of Electron Spectroscopy and Related Phenomena, 64/65 (1993)825–834
J. A. Schaefer, Hydrogen in Semiconductors: Bulk and surface Properties, p. 45–68, eds M. Stutzmann, J. Chevallier, North-Holland, 1991
F. Stietz, J. Woll, V. Persch, Th. Allinger, W. Erfurth, A. Goldmann, and J. A. Schaefer, Physica status solidi (a), 159 (1996) 185
F. Stietz, V. Persch, Th. Allinger, and J.A. Schaefer, Journal of Electron Spectroscopy and Related Phenomena, 64/65 (1993) 413
E.I. Altman and R.J. Colton, Physical Review B, 48 (1993) 18244
F. Lodders, J. Westhof, J.A. Schaefer, H. Hopfinger, A. Goldmann, and S. Witzel, Zeitschrift für Physik B-Condensed Matter, 83 (1991), 263.
W.G. Schmidt, N. Esser, A.M. Frisch, P. Vogt, J. Bernholc, F. Bechstedt, M. Zorn, Th. Hannappel, S. Visbeck, F. Willig, and W. Richter, Physical Review B, 61 (2000), R16335.
T.R. Ohno, Y. Chen, S.E. Harvey, G.H. Kroll, J.H. Weaver, R.E. Haufler, and R.E. Smalley, Physical Review B, 44 (1991), 13747.
G. Gensterblum, J.J. Pireaux, P.A. Thiry, R. Caudano, J.P. Vigneron, Ph. Lambin, and A.A. Lucas, Physical Review Letters, 67 (1991) 2171
J.L. Feldman, J.Q. Broughton, L.L. Boyer, D.E. Reich, and M.D. Kluge, Physical Review B, 46 (1992) 12731
C. Silien, Y. Caudano, A. Peremans, and P.A. Thiry, Applied Surface Science, 162–163 (2000) 445
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2004 Kluwer Academic Publishers
About this paper
Cite this paper
Schaefer, J.A. et al. (2004). Surface Science Tools and Their Application to Nanosystems Like C60 on Indium Phosphide. In: Buzaneva, E., Scharff, P. (eds) Frontiers of Multifunctional Integrated Nanosystems. NATO Science Series II: Mathematics, Physics and Chemistry, vol 152. Springer, Dordrecht. https://doi.org/10.1007/1-4020-2173-9_13
Download citation
DOI: https://doi.org/10.1007/1-4020-2173-9_13
Publisher Name: Springer, Dordrecht
Print ISBN: 978-1-4020-2171-8
Online ISBN: 978-1-4020-2173-2
eBook Packages: Chemistry and Materials ScienceChemistry and Material Science (R0)