Abstract
The crystal field interaction is an essential ingredient in a discussion of the magnetic properties of materials. It is therefore important to be able to describe and characterize the bonding between the central magnetic ion and its (nonmagnetic) ligand ions in terms of some electronic theory. For such a procedure it is obvious to classify the central magnetic ions according to the character of the partly filled electronic shells giving rise to a permanent magnetic dipole moment due to the orbital motion of the electrons, or to their intrinsic spin, or to both.
Access this chapter
Tax calculation will be finalised at checkout
Purchases are for personal use only
Preview
Unable to display preview. Download preview PDF.
References
Abragam, A. & Bleaney, B. (1970) Electron Paramagnetic Resonance (Oxford: Clarendon).
Purwins, H.G. & Leson A. (1990) Adv. Phys. 39, 309–405.
Bethe, H.A. (1929) Ann. Phys. 3, 133–208.
Stevens, K.W.H. (1952) Proc. Phys. Soc. A, 65, 209–15.
Stevens, K.W.H. (1967) Rep. Progr. Phys. 30, 189–226.
Elliott, RJ. & Stevens, K.W.H. (1953) Proc. R. Soc. A, 219, 387–404.
Judd, B.R. (1963) Operator Techniques in Atomic Spectroscopy (New York: McGraw-Hill).
Hutchings M.T. (1964) Solid State Physics 16, 227–73.
Newman, D.J. (1971) Adv. Phys. 20, 197–255.
Fulde, P. (1978) Handbook on the Physics and Chemistry of Rare Earths, Chapter 17 (Amsterdam: North-Holland).
Freeman, A.J. & Desclaux, J.P. (1979) J. Magn. Magn. Mater. 12, 11–21.
Lea, K.R., Leask, M.J.M. & Wolf, W.P. (1962) J. Phys. Chem. Solids 23, 1381–405.
Wybourne, E.G. (1965) Spectroscopic Properties of Rare Earths (New York: John Wiley).
Nielson C.W. & Koster, G.F. (1964) Spectroscopic Coefficients for the pn, dn, and fn configurations (Cambridge: M.I.T. Press).
Sternheimer, R.M. (1966) Phys. Rev. 146, 140–60.
Morrison, C.A. (1988) Angular Momentum Theory Applied to Interactions in Solids (Berlin: Springer).
Tellenbach, U. (1974) Report AF-SSP-75 (ETH Zurich, unpublished).
Urland, W. (1976) Chem. Phys. 14, 393–401.
Jorgensen C.K., Pappalardo, R. & Schmidtke, H.H. (1963) Chem. Phys. 39, 1422–30.
Blaha, P., Schwarz, K. & Luitz (1997) WIEN91 (Vienna Technical University, unpublished).
Divis, M., Rusz, J., Hilscher, G., Michor, H., Blaha, P. & Schwarz, K. (2002) Czech. J. Phys. 52, 283–6.
Novak, P. (1996) Phys. Stat. Sol. B, 198, 729–40.
Gasser, U., Allenspach, P., Fauth, F., Henggeler, W., Mesot, J., Furrer, A., Rosenkranz, S., Vorderwisch, P. & Buchgeister, M. (1996) Z. Phys. B, 101, 345–52.
Strässle, Th., Divis, M., Rusz, J., Janssen, S., Juarnyi, F., Sadikov, R. & Furrer, A. (2003) J. Phys. Condens. Matter 15, 3257–66.
Furrer, A. & Güdel, H.U. (1997) Phys. Rev. B, 56, 15062–72.
Elsenhans, O., Furrer, A., Purwins, H.G. & Hulliger, F. (1990) Z. Phys. B, 80, 281–6.
Hodges, J.A., Bonville, P., Imbert, P., Jéhanno, G. & Debray, P. (1991) Physica C, 184, 270–82.
Jandl, S., Dufour, P., Strach, T., Ruf, T., Cardona, M., Nekvasil, V., Chen, C., Wanklyn, B.M. & Pinol, S. (1996) Phys. Rev B, 53, 8632–7.
Strach, T., Ruf T., Cardona, M., Lin, C.T., Jandl. S., Nekvasil, V., Zhigunov, D.I., Barilo, S.N. & Shiryaev, S.V. (1996) Phys. Rev. B, 54, 4276–82.
Henggeler W., Chattopadhyay, T., Roessli, B., Vorderwisch, P., Thalmeier, P., Zhigunov, D.I., Barilo, S.N. & Furrer, A. (1997) Phys. Rev. B, 55, 1269–79.
Brockhouse, B.N. (1955) Can. J. Phys. 33, 889–91.
Halpern, O. & Johnson, M.H. (1939) Phys. Rev, 55, 898–923.
Squires, G.L. (1996) Thermal Neutron Scattering (New York: Dover Publications).
Lovesey, S.W. (1987) Theory of Neutron Scattering from Condensed Matter (Oxford: Oxford Science Publishers).
Johnston, D.F. (1966) Proc. Phys. Soc, 88, 37–52.
Van Hove, L. (1954) Phys. Rev. 93, 268–9.
Schmid, B., Hälg, B., Furrer, A., Urland, W. & Kremer, R. (1987) J. Appl. Phys. 61, 3426–8.
Birgeneau, R.J. (1972) J. Phys. Chem. Solids. 33, 59–68.
Lewis Ian, R. & Edwards Howell, G.M. (2001) Handbook of Raman Spectroscopy (New York: Marcel Dekker).
Sanjurjo, J.A., Martins, G.B., Pagliuso, P.G., Granado, E., Torriani, I., Rettori, C., Oseroff, S. & Fisk, Z. (1995) Phys. Rev. B, 51, 1185–9.
Berry, A.J., McCaw, C.S., Morrison, I.D. & Denning, R.G. (1996) J. Lumin. 66, & 67, 272–7.
Cardona, M. (1982) Light Scattering in Solids II (Berlin: Springer).
Yanson, I.K. (1974) Sov. Phys. JETP 39, 506–13.
Jansen, A.G.M., van Gelder, A.P. & Wyder, P. (1980) J. Phys. C, 13, 6073–118.
Akimenko, A.I., Ponomarenko, N.M., Yanson, I.K., Janos, S. & Reiffers, M. (1984) Sov. Phys. Solid State 26, 1374–9.
Amato, A., Bührer, W., Grayevski, A., Gygax, F.N., Furrer, A., Kaplan, N. & Schenck, A. (1992) Solid State Comm. 82, 767–71.
Reiffers, M., Naidyuk, Yu.G., Janseen, A.G.M., Wyder, P., Yanson, I.K., Gignoux, D. & Schmitt, D.P. (1989) Phys. Rev. Lett. 62, 1560–3.
Naidyuk, Yu.G. & Yanson, I.K. (2004) Point-Contact Spectroscopy (Berlin: Springer).
Richardson, F.S., Reid, M.F., Dallara, J.J. & Smith, R.D. (1985) J. Chem. Phys. 83, 3813–30.
Mesot, J., Rubio, Temprano, D. & Furrer, A. (2002) Trends in Applied Spectroscopy, Vol. 4 (Trivandrum: Research Trends) p 75.
Mesot, J., Allenspach, P., Staub, U., Furrer, A., Mutka, H., Osborn, R. & Taylor, A. (1993) Phys. Rev. B, 47, 6027–36.
Mesot, J. & Furrer, A. (1998) Neutron Scattering in Layered Copper-Oxide Superconductors p 335 (Dordrecht: Kluwer).
Roeland, L.W., de Boer, F.R., Huang, Y.K., Menovsky, A.A. & Kadowaki, K. (1988) Physica C, 152, 72–6.
Dunlap, B.D., Slaski, M., Hinks, D.G., Soderholm, L., Beno, M., Zhang, K., Segre, C., Crabtree, G.W., Kwok, W.K., Malik, S.K., Schuller, I.K., Jorgensen, J.D. & Sungaila, Z. (1987) J. Magn. Magn. Mater. 68, L139–44.
Van der Meulen, H.P., Franse, J.J.M., Tarnawski, Z., Kadowaki, K., Klasse, J.C.P. & Menovsky, A.A. (1988) Physica C, 152, 65–71.
Hodges, J.A., Imbert, P., Marimon de Cunha, J.B. & Sanchez, J.P. (1989) Physica C, 160, 49–54.
Heitler, W. & Teller, E. (1936) Proc. Roy. Soc. A, 155, 629–39.
Kronig, R. de L. (1939) Physica 6, 33–43.
van Vleck, J.H. (1939) J. Chem. Phys. 7, 72–84; 1940 Phys. Rev. 57, 426–47.
Orbach, R. (1961) Proc. Roy. Soc. A, 264, 458–84.
Korringa, J. (1950) Physica (Utrecht) 16, 601–10.
Becker, K.W., Fulde, P. & Keller, J. (1977) Z. Phys. B, 28, 9–18.
Feile R., Loewenhaupt M., Kjems J.K. & Hoenig H.E. (1987) Phys. Rev. Lett. 47, 610–3.
Buyers, W.J.L., Holden, T.M., Svenson, B.C., Cowley, R.A. & Hutchings, M.T. (1971) J.Phys. C, 4, 2139–59.
Bednorz, J.G. & Mtiller, K.A. (1986) Z. Phys. B, 64, 189–93.
Cava, R.J., Hewat, A.W., Hewat, E.A., Batlogg, B., Marezio, M., Rabe, K.M., Krajevski, J.J., Peck, W.F.Jr. & Rupp, L. W. (1990) Physica C, 165, 419–33.
Staub, U., Mesot, J., Guillaume, M., Allenspach, P., Furrer, A., Mutka, H., Bowden, Z. & Taylor, A. (1994) Phys. Rev. B, 50, 4068–74.
Radaelli, P.O., Segre, C.U., Hinks, D.G. & Joergensen, J.D. (1992) Phys. Rev. B, 45, 4923–9.
Mesot, J., Allenspach, P., Staub, U., Furrer, A. & Mutka, H. (1993) Phys. Rev. Lett. 70, 865–8.
Niedermayer, C., Bernhard, C., Blasius, T., Golnik, A., Moodenbaugh, A. & Budnick, J.I. (1998) Phys. Rev. Lett. 80, 3843–6.
Hizhnyakov, V. & Sigmund, E. (1988) Physica C, 156, 655–66.
Kremer, R., Sigmund, E., Hizhnyakov, V., Hentsch, F., Simon, A., Mtiller, K.A. & Mehring, M. (1992) Z Phys. B, 86, 319–24.
Kirkpatrick, S. (1973) Rev. Mod Phys. 45, 574–88.
Allenspach, P., Furrer, A. & Rupp, B. (1990) Progress in High-Temperature Superconductivity (Singapore: World Scientific) p 318.
Furrer, A., Allenspach, P., Fauth, F., Guillaume, M., Henggeler, W., Mesot, J. & Rosenkranz, S. (1994) Physica C, 235–240 261–4.
Hammel, P.C., Reyes, A.P., Fisk, Z., Takigawa, M., Thompson, J.D., Heffher, K.H. & Cheong, S.W. (1990) Phys. Rev. B, 42, 6781–3.
Wtibbeler, G. & Schirmer, O. F. (1990) Phys. Stat. Sol. (b) 174 K21–5.
Poulakis, N., Palles, D., Liarokapis, E., Conder, K. & Kaldis, E. (1996) Phys. Rev. B, 53, R534–7.
Emery, V.J., Kivelson, S.A. & Lin, H.Q. (1990) Phys. Rev. Lett. 64, 475–8.
Grilli, M., Raimondi, R., Castellani, C., di Castro, C. & Kotliar, G. (1991) Phys. Rev. Lett. 67, 259–62.
Batlogg, B. & Varma, C. (2000) Physics World 13 (No 2) 33–7.
Furrer, A. (2005) Structure and Bonding 114, 171–204.
Raffa, F., Ohno, T., Mali, M., Roos, J., Brinkmann, D., Conder, K. & Eremin, M. (1998) Phys. Rev. Lett. 81, 5912–5.
Rubio Temprano, D., Mesot, J., Janssen, S., Conder, K., Furrer, A., Mutka, H. & Mtiller, K.A. (2000) Phys. Rev. Lett. 84, 1990–3.
Rubio Temprano, D., Mesot, J., Janssen, S., Conder, K., Furrer, A., Sokolov, A., Trounov, V., Kazakov, S.M., Karpinski, J. & Mtiller, K.A. (2001) Eur. Phys. J. B, 19, 5–8.
Rubio Temprano, D., Conder, K., Furrer, A., Mutka, H., Trounov, V. & Mtiller, K.A. (2002) Phys. Rev. B, 66, 184506.
Furrer, A., Conder, K., Hafliger, P.S. & Podlesnyak, A. (2004) Physica C, 408–410 773–4.
Hafliger, P.S., Podlesnyak, A., Conder, K., Pomjakushina, E. & Furrer, A. (2004) Europhys. Lett. 67, 1018–23.
Podlesnyak, A., Häfliger, P.S., Conder, K. & Furrer, A. (2005) J. Phys.: Condens. Matter 11, S801–6.
Andergassen, S., Caprara, S., di Castro, C. & Grilli, M. (2001) Phys. Rev. Lett. 87, 056401.
Bussmann-Holder, A. (2000) J. Supercond. 13, 773–6.
Gor'kov, L.P. (2000) J. Supercond. 13, 765–9.
Moze, O. (1998) Handbook of Magnetic Materials, Vol. 11 (Amsterdam: Elsevier) p 493.
Author information
Authors and Affiliations
Editor information
Editors and Affiliations
Rights and permissions
Copyright information
© 2006 Springer
About this chapter
Cite this chapter
Furrer, A., Podlesnyak, A. (2006). CRYSTAL FIELD SPECTROSCOPY. In: Vij, D. (eds) Handbook of Applied Solid State Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/0-387-37590-2_6
Download citation
DOI: https://doi.org/10.1007/0-387-37590-2_6
Publisher Name: Springer, Boston, MA
Print ISBN: 978-0-387-32497-5
Online ISBN: 978-0-387-37590-8
eBook Packages: Physics and AstronomyPhysics and Astronomy (R0)