Abstract
This chapter is devoted to magnetic resonance spectroscopy for the investigation of unpaired electron spins. Two terms are used in the literature: electron paramagnetic resonance (EPR) and electron spin resonance (ESR). We will use the first term in this chapter. During the sixty years since its discovery in 1944 by E.K. Zavoisky [1], EPR spectroscopy has been exploited as a very sensitive and informative technique for the investigation of different kinds of paramagnetic species in solid or liquid states.
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References
Zavoisky, E. (1945) J. Phys. USSR 9, 211–4.
Weil, J.A., Bolton, J.R. & Wertz, J.E. (1994) Electron Paramagnetic Resonance. Elementary Theory and Practical Applications (New York: Wiley).
Pilbrow, J.R. (1990) Transition Ion Electron Paramagnetic Resonance (Oxford: Clarendon).
Atherton, N.M. (1993) Principles of Electron Spin Resonance (NY: Ellis Horwood).
Carrington, A. & McLachlan, A.D. (1979) Introduction to Magnetic Resonance (London: Chapman and Hall).
Poole, C.P. (1996) Electron Spin Resonance: A Comprehensive Treatise on Experimental Techniques (New York: Dover).
Poole, C.P. & Farach, H.A. (1987) Theory of Magnetic Resonance (New York: Wiley).
Abraham, A. & Bleaney, B. (1970) Electron Paramagnetic Resonance of Transition Ions (Oxford: Clarendon).
Spaeth, J.M., Niklas, J.R. & Bartram, R.H. (1992) Structural Analysis of Point Defects in Solids, Springer Series in Solid—State Sources, Vol. 43 (Berlin: Springer).
Box, H.C. (1977) Radiation Effects: ESR and ENDOR Analysis (New York: Academic).
Symons, M.C.R. & Atkins, P.W. (1967) The structure of inorganic radicals: An application of Electron Spin Resonance to the Study of Molecular Structure (Amsterdam: Elsevier).
Mabbs, F.E. & Collison, D. (1992) Electron Paramagnetic Resonance of d-Transition Metal Compounds, Studies in Inorganic Chemistry Series, Vol. 16 (Amsterdam: Elsevier).
Slichter, C.P. (1996) Principles of Magnetic Resonance (Berlin: Springer).
Gordy, W. (1980) Theory and Applications of Electron Spin Resonance (New York: Wiley).
Pake, G.E. (1962) Paramagnetic Resonance (New York: Benjamin).
Dixon, W.T. (1972) Theory and Interpretation of Magnetic Resonance Spectra (London: Plenum).
Bencini, A. & Gatteschi, D. (1990) EPR of Exchange Coupled System (Berlin: Springer).
Hoff, A.J. (Ed.) (1989) Advanced EPR. Applications in Biology and Biochemistry (Elsevier: Amsterdam).
Kevan, L. & Bowman, M.K. (Eds.) (1990) Modern Pulsed and Continuous-Wave Electron Spin Resonance (New York: Wiley).
Poole, C.P. & Farach, H.A. (Eds.) (1994) Handbook of Electron Spin Resonance (AIP Press).
Poole, C.P. & Farach, H.A. (Eds.) (1999) Handbook of Electron Spin Resonance Vol. 2, (New-York: Springer).
A Specialist Periodical Reports. Electron Spin Resonance (Cambridge: Royal Society of Chemistry).
Schweiger, A. & Jeschke, G., (2001) Principles of Pulse Electron Paramagnetic Resonance (Oxford: Clarendon).
Salikhov, K.M. Semenov, A.G. & Tsvetkov, Yu D. (1976) Electron Spin Echo and Its Applications (Science: Novosibirsk) (in Russian).
Dikanov, S.A. & Tsvetkov, Yu D. (1992) Electron Spin Echo Envelope Modulation (ESEEM) Spectroscopy (Boca Raton, FL: CRC).
Keijzers, C.P. Reijerse, E.J. & Schmidt, J. (Eds.) (1989) Pulsed EPR: A New Field of Applications (North Holland: Amsterdam).
Kevan, L. & Schwartz, R.N. (Eds.) (1979) Time Domain Electron Spin Resonance (New York: Wiley).
Minis, W.B. (1972) Phys. Rev. B 5, 2409–19.
Minis, W.B. (1972) Phys. Rev. B 6, 3543–5.
Bowman, M.K., Berry, E.A., Roberts, A.G. & Kramer, D.M. (2004) Biochemistry 43, 430–6.
Weil, J.A., Buch, T. & Clapp, J.E. (1973) Adv. Magn. Reson. 6, 183–257.
Shane, J.J., van der Heiden, P.A. Reijerse, A.W. & de Beer, EJ. (1994) Appl. Magn. Reson. 6, 427–54.
Pöpple, A., Simon, J. & Völkel, G. (1994) Appl. Magn. Reson. 6, 455–70.
Lippard, S.J. & Berg, J.M. (1994) Principles of Bioinorganic Chemistry (Mill Valley, CA: University Science Book); p. 86.
Link, T.A. (1999) Adv. Inorg. Chem. 47, 83–157.
Guigliarelli, B. & Bertrand, P. Adv. Inorg. Chem. 47, 421–497.
Konovalova, T.A., Krzystek, J., Bratt, P.J., van Tol, J. Brunei, L-C. & Kispert, L.D. (1999) J. Phys. Chem. B, 103, 5782–6.
Gerfen, G.J., Bellew, B.F. Un, S., Bollinger, Jr. J.M. Stubbe, J. Griffin, R.G. & Singel D.J. (1993) J. Am. Chem. Soc. 115, 6420–1.
Grimaldi, S. MacMillan, F. Ostermann, T. Ludwig, B. Michel, H. & Prisner, T. (2001) Biochemistry 40, 1037–43.
Kolling, D.R.J., Samoilova, R.I. Holland, J.T. Berry, E.A. Dikanov, S.A. & Crofts, A.R. (2003) J. Biol. Chem. 278, 39747–54.
Merks, R.P. & de Beer, R. (1979) J. Phys. Chem. 83, 3319–22.
Barkhuijsen, H., de Beer, R., de Wild, E.L. & van Ormondt, D. (1982) J. Magn. Reson. 50, 299–315.
Höfer, P., Grupp, A., Nebenführ, H. & Mehring, M. (1986) Chem. Phys. Lett. 132, 279–84.
Goldfarb, D., Kofman, V., Libman, J., Shanzer, A., Rahmatouline, R., Van Doorslaer, S. & Schweiger, A. (1998) J. Am. Chem. Soc. 120, 7020–9.
Dikanov, S.A. & Bowman, M.K. (1995) J. Magn. Reson. A 116, 125–8.
Dikanov, S.A., Davydov, R.M., Graslund, A. & Bowman, M.K. (1998) J. Am. Chem. Soc. 120, 6797–805.
Deligiannakis, Y., Louloudi, M. & Hadjiliadis, N. (2000) Coord. Chem. Rev. 204, 1–112.
Makinen, M.W. & Wells, G.B. (1987) Metal Ions Biol. Systems 22, 129–206.
Lakshmi, K.V. & Brudvig, G.W. (2000) Biol. Magn. Reson. 19, 513–67.
Brudvig, G. (1995) Methods Enzymol 246, 536–54.
Schweiger, A. & Ernst, R.R. (1988) J. Magn. Reson. 77, 512–23.
Bowman, M.K. (1993) In Magnetic Resonance of Carbonaceous Solids Eds Boto, R.E. & Sanada, Y. (Washington, DC: ACS) p. 91.
Lorigan, G.A. & Britt, R.D. (1994) Biochemistry 33, 12072–6.
Hoffman, S.K., Hilczer, W. & Goslar, J. (1996) J. Magn. Reson, A 122, 37–41.
Du, J.-L., Eaton, G.R. & Eaton, S.S. (1996) J. Magn. Reson, A 119, 240–6.
Zhou, Y., Bowler, B.E., Eaton, G.R. & Eaton, S.S. (1999) J. Magn. Reson 139, 240–6.
Lawrence, C.C., Bennati, M., Obias, H.V., Bar, G. Griffin, R.G. & Stubbe, J. (1999) Proc. Natl. Acad. Sci. USA 96, 8979–84.
Pinhal, N.M., Vugman, N.V., Herbst, M.H. & Dias, G.H. (2000) J. Phys. Chem. A 104, 1162–4.
Tsvetkov, Yu D. (1983) Russ. Chem. Rev. 52, 866–80.
Raitsimring, A.M. & Salikhov, K.M. (1985) Bull. Magn. Reson. 7, 184.
Kurshev, V.V., Raitsimring, A.M. & Tsvetkov, Yu.D. (1989) J. Magn. Reson. 81, 441–54.
Saxena, S. & Freed, J.H. Chem. Phys. Lett. 251, 102–10.
Shigemori, K., Kara, H., Kawamori, A. & Akabori, K. (1998) Bioch. Bioph. Acta 1363, 187–98.
Ralowsky, M.H., Zecevic, A., Eaton, G.R. & Eaton, S.S. (1998) J. Magn. Reson. 131, 97–110.
Dzuba, S.A., Salikhov, K.M. & Tsvetkov, Yu.D. (1981) Chem. Phys. Lett. 79, 568–72.
Dzuba, S.A., Maryasov, A.G., Salikhov, K.M. & Tsvetkov, Yu D. (1984) J. Magn. Reson. 58, 95–117.
Gorcester, J., Millhauser, G.L. & Freed, J.H. (1990) In Modern Pulsed and Continuous Wave Electron Spin Resonance Eds. Kevan, L. & Bowman, M.K. (New York: Wiley) pp.119–94.
Tyryshkin, A.M., Lyon, S.A., Astasthkin, A.V. & Raitsimring, A.M. (2003) Phys. Rev. B 68, 193207.
Berliner, L.J., Eaton, G.R. & Eaton, S.S. (Eds.) (2000) Biological Magnetic Resonance Vol. 19 (New York: Kluwer).
Milov, A.D., Salikhov, K.M. & Schirov, M.D. (1981) Solid State Physics (Leningrad) 23, 975–82 (in Russian).
Milov, A.D., Ponomarev, A.B. & Tsvetkov, Yu D. (1985) J. Struct. Chem. 25, 710–3.
Schiemann, O., Weber, A., Edwards, T.E., Priesner, T.F. & Sigurdsson, S.T. (2003) J. Am. Chem. Soc. 125, 3434–5.
Pannier, M., Veit, S., Godt, A., Jeschke, G. & Spiess, H.W. (2000) J. Magn. Reson. 331–40.
Jeschke, G., Bender, A., Paulsenl, H., Zimmermann, H. & Godt, A. (2004) J. Magn. Reson. 1–12.
Pannier, M., Schädler, V., Schöps, M., Wiesner, U., Jeschke, G. & Spiess, H.W. (2000) Macromolecules 33, 7812–8.
Milov, A.D., Tsvetkov, Yu D., Formaggio, F., Crisma, M., Toniolo, C. & Raap, J. (2001) J. Am. Chem. Soc. 123, 3784–9.
Kuroiwa, S., Tonaka, M., Kawamori, A. & Akabori, K. (2000) Bioch. Bioph. Acta 1460, 330–7.
Codd, R., Astashkin, A.V., Pacheco, A., Raitsimring, A.M. & Enemark, J.H. (2002) J. Biol. Inorg. Chem. 7, 338–50.
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Dikanov, S.A., Crofts, A.R. (2006). ELECTRON PARAMAGNETIC RESONANCE SPECTROSCOPY. In: Vij, D. (eds) Handbook of Applied Solid State Spectroscopy. Springer, Boston, MA. https://doi.org/10.1007/0-387-37590-2_3
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DOI: https://doi.org/10.1007/0-387-37590-2_3
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