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Routes to monomeric lanthanide alkoxides

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Organolanthoid Chemistry: Synthesis, Structure, Catalysis

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 179))

Abstract

The following contribution deals with lanthanide alkoxide chemistry under the aspects of “organic ligand synthesis — metal complexation — application”. Special emphasis is put on the design and synthesis of tailor-made ligand environments. In particular, the methodology of donor-functionalization opens the way to creating several intriguing properties simultaneously — prerequisites for potential applications as highly selective catalysts for organic synthesis and precursors to ceramic materials. Detailed structural information on such tailored metal complexes, which is now available, provides the basics to understanding and optimizing the pursued applications. Concrete examples document the unique breaking and generation of lanthanide alkoxide bonds under thermal stress as well as under catalytic and related reaction conditions. The literature is covered until mid-1995.

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Abbreviations

al:

aliphatic

Am:

amyl

Ar:

Aryl

BINOL:

binaphthol

cat:

catecholate

CN:

coordination number

CH:

hydrocarbon-based

CHF:

fluorinated hydrocarbon

Cp:

η5-cyclopentadienyl

Cp*:

η5-pentamethylcyclopentadienyl

DHPEX:

α, α′-di[(S)-2-hydroxy-2-phenylethyl]-o-xylenedioxide

diglyme:

di-β-methoxyethylether

ditox:

di-tert-butyl methoxide

DME:

1,2-dimethoxyethane

do:

donor-functionalized

Hbdmap:

1,3-bis(dimethylamino)propan-2-ol

Hbdmmp:

2,6-bis[(dimethylamino)methyl]-4-methylphenol

H3(1,2,4-btt):

N,N′,N″′-tris(2-hydroxybenzyl)triethylenetetramine

hfa:

hexafluoroacetate

hfacac:

1,1,1,5,5,5-hexafluoroacetylacetonate

hftb:

2,2,2,4,4,4-hexafluor-tert-butanol

HMPA:

hexamethylphosphoramide

H3trac:

tris[(4-hydroxypentenylidene-2-imino)ethyl]amine

Ind:

indenyl

L:

ligand

Ln:

lanthanide (Sc, Y, La, Ce-Lu)

meditox:

di-tert-butylmethyl methoxide

pftb:

perfluor-tert-butanol

pip:

piperidine

proditox:

di-tert-butylisopropyl methoxide

silox:

tri-tert-butyl siloxide

sipox:

tri-isopropyl siloxide

TBHP:

tert-butylhydroperoxide

tea:

triethanolamine

thd:

2,2,6,6-tetramethyl-3,5-heptanedionate

THF:

tetrahydrofurane

TMEDA:

tetramethylethylenediamine

tritox:

tri-tert-butyl methoxide

trop:

tropolonate

tripox:

tri-isopropyl methoxide

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  1. Institute of Chemical Technology I, University of Stuttgart, D-70550, Stuttgart, Germany

    Reiner Anwander

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© 1996 Springer-Verlag

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Anwander, R. (1996). Routes to monomeric lanthanide alkoxides. In: Organolanthoid Chemistry: Synthesis, Structure, Catalysis. Topics in Current Chemistry, vol 179. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0015597

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