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Features of organolanthanide complexes

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Organolanthoid Chemistry: Synthesis, Structure, Catalysis

Part of the book series: Topics in Current Chemistry ((TOPCURRCHEM,volume 179))

Abstract

The intrinsic properties of the lanthanide elements guarantee promising applications in the fields of catalysis and material science. How to cope with these features on a molecular level and under anaerobic conditions is discussed, including thermodynamic and kinetic considerations. Due to the importance of a prolific metal/ligand synergism, current developments in ligand design are emphasized.

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Abbreviations

BINOL:

binaphthol

CN:

coordination number

Cp:

η5-cyclopentadienyl

DME:

1,2-dimethoxyethane

Diglyme:

di-β-methoxyethylether

E:

element

hfc:

3-(heptafluoropropylhydroxymethylene)-d-camphorato

HSAB:

hard soft acid base

Im:

imidazole

L:

ligand

Ln:

lanthanide (Sc, Y, La, Ce-Lu)

MOCVD:

metal-organic chemical vapor deposition

Py:

pyridine

TBP:

tri-n-butylphosphane

Tf:

“triflate” ligand, CF3SO3

thd:

2,2,6,6-tetramethyl-3,5-heptandionate

THF:

tetrahydrofurane

TMEDA:

tetramethylethylenediamine

tritox:

tri-tert-butyl methoxide

Z:

nuclear charge

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Authors and Affiliations

  1. Institut für Technische Chemie, Universität Stuttgart, D-70550, Stuttgart, Germany

    Reiner Anwander

  2. Anorganisch-Chemisches Institut, Technische Universität München, D-85747, Garching, Germany

    Wolfgang A. Herrmann

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Anwander, R., Herrmann, W.A. (1996). Features of organolanthanide complexes. In: Organolanthoid Chemistry: Synthesis, Structure, Catalysis. Topics in Current Chemistry, vol 179. Springer, Berlin, Heidelberg. https://doi.org/10.1007/BFb0015594

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