Abstract
Electron distributions in the main compounds of rare-earths and actinides are described in relation with the valence of these elements. Their changes as a function of the physical conditions, temperature, pressure and some potential applications of these materials are discussed. Cerium compounds are particularly considered.
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Notes
- 1.
Antiferromagnetism is due to coupling between spin moments carried by near ions in the solid and it is present below the Néel temperature , i.e. at low temperatures. This atomic description is well adapted to rare-earth compounds because of the presence of incomplete 4f sub shell localized on each rare-earth ion.
- 2.
The coercivity of a material is the value of the magnetic field required to reduce to zero the magnetization.
- 3.
Laves phases are structures characteristic of AB2 type intermetallic compounds. The unit cell is cubic or hexagonal. Tetrahedrally close packet structure is obtained if the ratio of the spheres characteristic of the A and B atoms is equal to √(3/2).
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Bonnelle, C., Spector, N. (2015). Electron Distributions and Physicochemical Properties. In: Rare-Earths and Actinides in High Energy Spectroscopy. Progress in Theoretical Chemistry and Physics. Springer, Dordrecht. https://doi.org/10.1007/978-90-481-2879-2_2
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