Abstract
With the constant growing complexity of electronic devices, the top-down approach used with silicon based technology is facing both technological and physical challenges. Carbon based nanomaterials are good candidates to be used in the construction of electronic circuitry using a bottom-up approach, because they have semiconductor properties and dimensions within the required physical limit to establish electrical connections. The unique electronic properties of fullerenes for example, have allowed the construction of molecular rectifiers and transistors that can operate with more than two logical states. Carbon nanotubes have shown their potential to be used in the construction of molecular wires and FET transistors that can operate in the THz frequency range. On the other hand, graphene is not only the most promising material for replacing ITO in the construction of transparent electrodes but it has also shown quantum Hall effect and conductance properties that depend on the edges or chemical doping. The purpose of this review is to present recent developments on the utilization carbon nanomaterials in molecular electronics.
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References
Green JR, Korkin A, Labanowski J (2003) Nano and giga: challenges in microelectronics. Elsevier, Amsterdam
Avouris P, Chen Z, Perebeinos V (2007) Carbon-based electronics. Nat Nanotechnol 2:605–615
Theis TN, Solomon PM (2010) It’s time to reinvent the transistor! Science 327:1600–1601
Lu W, Lieber CM (2007) Nanoelectronics from the bottom up. Nat Mater 6:841–850
Xu B, Tao NJ (2003) Measurement of single-molecule resistance by repeated formation of molecular junctions. Science 301:1221–1223
Xu BQ, Xiao XY, Yang X et al (2005) Large gate modulation in the current of a room temperature single molecule transistor. J Am Chem Soc 127:2386–2387
Akasaka T, Fred W, Nagase S (2010) Chemistry of nanocarbons. Wiley, Hoboken, NJ
Sablon K (2008) Nanoelectrodes for molecular devices: a controllable fabrication. Nanoscale Res Lett 3:268–270
Venkataraman L, Klare JE, Nuckolls C et al (2006) Dependence of single-molecule junction conductance on molecular conformation. Nature 442:904–907
Kroto HW, Heath JR, O’Brien SC et al (1985) C60: buckminsterfullerene. Nature 318:162–163
Iijima S (1991) Helical microtubules of graphitic carbon. Nature (London) 354:56–58
Iijima S, Ichihashi T (1993) Single-shell carbon nanotubes of 1-nm diameter. Nature 363:603–605
Bethune DS, Kiang CH, de Vries MS et al (1993) Cobalt-catalyzed growth of carbon nanotubes with single-atomic-layer walls. Nature (London) 363:605–607
Iijima S (1980) Direct observation of the tetrahedral bonding in graphitized carbon black by high resolution electron microscopy. J Cryst Growth 50:675–683
Iijima S (1987) The 60-carbon cluster has been revealed. J Phys Chem 91:3466–3467
Ugarte D (1992) Curling and closure of graphitic networks under electron-beam irradiation. Nature 359:707–709
Kuznetsov VL, Chuvilin AL, Butenko YV et al (1994) Onion-like carbon from ultra-disperse diamond. Chem Phys Lett 222:343–348
Sano N, Wang H, Chhowalla M et al (2001) Synthesis of carbon ‘onions’ in water. Nature 414:506–507
Liu W, Meng QS (2009) An effective method of increasing production rate of onion-like fullerenes. J Phys Conf Ser 188:012035
Alexandrou I, Wang H, Sano N et al (2004) Structure of carbon onions and nanotubes formed by arc in liquids. J Chem Phys 120:1055–1058
Iijima S, Yudasaka M, Yamada R et al (1999) Nano-aggregates of single-walled graphitic carbon nano-horns. Chem Phys Lett 309:165–170
Heath JR, O’Brien SC, Zhang Q et al (1985) Lanthanum complexes of spheroidal carbon shells. J Am Chem Soc 107:7779–7780
Chai Y, Guo T, Jin C et al (1991) Fullerenes with metals inside. J Phys Chem 95:7564–7568
Dunsch L, Yang S (2007) Metal nitride cluster fullerenes: their current state and future prospects. Small 3:1298–1320
Chaur MN, Melin F, Ortiz AL et al (2009) Chemical, electrochemical, and structural properties of endohedral metallofullerenes. Angew Chem Int Ed 48:7514–7538
Stevenson S, Mackey MA, Stuart MA et al (2008) A distorted tetrahedral metal oxide cluster inside an icosahedral carbon cage. synthesis, isolation, and structural characterization of Sc4(?3-O)2@Ih-C80. J Am Chem Soc 130:11844–11845
Wang T, Chen N, Xiang J et al (2009) Russian-doll-type metal carbide endofullerene: synthesis, isolation, and characterization of Sc4C2@C80. J Am Chem Soc 131:16646–16647
Chen N, Chaur MN, Moore C et al (2010) Synthesis of a new endohedral fullerene family, Sc2S@C2n (n?=?40–50) by the introduction of SO2. Chem Commun 46:4818–4820
Dunsch L, Yang S, Zhang L et al (2010) Metal sulfide in a C(82) fullerene cage: a new form of endohedral clusterfullerenes. J Am Chem Soc 132:5413–5421
Kratschmer W, Lamb LD, Fostiropoulos K et al (1990) Solid C60: a new form of carbon. Nature 347:354–358
Krätschmer W, Fostiropoulos K, Huffman DR (1990) The infrared and ultraviolet absorption spectra of laboratory-produced carbon dust: evidence for the presence of the C60 molecule. Chem Phys Lett 170:167–170
Haufler RE, Conceicao J, Chibante LPF et al (1990) Efficient production of C60 (buckminsterfullerene), C60H36, and the solvated buckide ion. J Phys Chem 94:8634–8636
Taylor R, Hare JP, Abdul-Sada AK et al (1990) Isolation, separation and characterization of the fullerenes C60 and C70: the third form of carbon. J Chem Soc Chem Commun 20:1423–1425
Howard JB, McKinnon JT, Makarovsky Y et al (1991) Fullerenes C60 and C70 in flames. Nature (London) 352:139–141
McKinnon JT, Bell WL, Barkley RM (1992) Combustion synthesis of fullerenes. Combust Flame 88:102–112
Goel A, Hebgen P, Vander Sande JB et al (2002) Combustion synthesis of fullerenes and fullerenic nanostructures. Carbon 40:177–182
Takehara H, Fujiwara M, Arikawa M et al (2005) Experimental study of industrial scale fullerene production by combustion synthesis. Carbon 43:311–319
Alford JM, Bernal C, Cates M et al (2008) Fullerene production in sooting flames from 1,2,3,4-tetrahydronaphthalene. Carbon 46:1623–1625
Murayama H, Tomonoh S, Alford JM et al (2004) Fullerene production in tons and more: from science to industry. Fullerenes, Nanotubes, Carbon Nanostruct 12:1–9
Fulcheri L, Schwob Y, Fabry F et al (2000) Fullerene production in a 3-phase AC plasma process. Carbon 38:797–803
Song X, Liu Y, Zhu J (2006) The effect of furnace temperature on fullerene yield by a temperature controlled arc discharge. Carbon 44:1584–1586
Ahmad B, Riaz M, Ahmad M et al (2008) Synthesis and characterization of higher fullerene (C84) in dc arc discharge using Cu as a catalyst. Mater Lett 62:3367–3369
Huczko A, Lange H, Byszewski P et al (1997) Fullerene formation in carbon arc: electrode gap dependence and plasma spectroscopy. J Phys Chem A 101:1267–1269
Gonzalez-Aguilar J, Moreno M, Fulcheri L (2007) Carbon nanostructures production by gas-phase plasma processes at atmospheric pressure. J Phys D: Appl Phys 40:2361–2374
Kareev IE, Bubnov VP, Fedutin DN (2009) Electric-arc high-capacity reactor for the synthesis of carbon soot with a high content of endohedral metallofullerenes. Tech Phys 54:1695–1698
Yamada M, Akasaka T, Nagase S (2010) Endohedral metal atoms in pristine and functionalized fullerene cages Acc Chem Res 43:92–102
Tsuchiya T, Akasaka T, Nagase S (2010) New vistas in fullerene endohedrals: functionalization with compounds from main group elements. Pure Appl Chem 82:505–521
Dunsch L, Georgi P, Krause M et al (2003) New clusters in endohedral fullerenes: the metalnitrides. Synth Met 135–136:761–762
Dunsch L, Krause M, Noack J et al (2004) Endohedral nitride cluster fullerenes. Formation and spectroscopic analysis of L3-xMxN@C2n (0???x???3; N?=?39,40). J Phys Chem Solids 65:309–315
Krause M, Ziegs F, Popov AA et al (2007) Entrapped bonded hydrogen in a fullerene: the five-atom cluster Sc3CH in C80. ChemPhysChem 8:537–540
Stevenson S, Rice G, Glass T et al (1999) Small-bandgap endohedral metallofullerenes in high yield and purity. Nature 401:55–57
Chen N, Klod S, Rapta P et al (2010) Direct Arc-discharge assisted synthesis of C60H2(C3H5N): a cis-1-pyrrolino C60 fullerene hydride with unusual redox properties. Chem Mater 22:2608–2615
Haddon RC, Brus LE, Raghavachari K (1986) Electronic structure and bonding in icosahedral carbon cluster (C60). Chem Phys Lett 125:459–464
Xie Q, Perez-Cordero E, Echegoyen L (1992) Electrochemical detection of C60 6- and C70 6-: enhanced stability of fullerides in solution. J Am Chem Soc 114:3978–3980
Xie Q, Arias F, Echegoyen L (1993) Electrochemically-reversible, single-electron oxidation of C60 and C70. J Am Chem Soc 115:9818–9819
Echegoyen L, Echegoyen LE (1998) Electrochemistry of fullerenes and their derivatives. Acc Chem Res 31:593–601
Anderson MR, Dorn HC, Stevenson SA et al (1998) The voltammetry of C84 isomers. J Electroanal Chem 444:151–154
Chaur MN, Athans AJ, Echegoyen L (2008) Metallic nitride endohedral fullerenes: synthesis and electrochemical properties. Tetrahedron 64:11387–11393
Lu X, Slanina Z, Akasaka T et al (2010) Yb@C(2n) (n?=?40, 41, 42): new fullerene allotropes with unexplored electrochemical properties. J Am Chem Soc 132:5896–5905
Zhao J, Miao B, Zhao L et al (2004) Electronic transport properties of single C60 molecules and device applications. Int J Nanotechnol 1:157–169
Joachim C, Gimzewski JK (1995) Analysis of low-voltage I(V) characteristics of a single C60 molecule. Europhys Lett 30:409–414
Joachim C, Gimzewski J, Schlittler R et al (1995) Electronic transparence of a single C60 molecule. Phys Rev Lett 74:2102–2105
Néel N, Kröger J, Limot L et al (2007) Controlled contact to a C60 molecule. Phys Rev Lett 98:065502
Saffarzadeh A (2008) Electronic transport through a C60 molecular bridge: the role of single and multiple contacts. J Appl Phys 103:083705–083706
Mishra S (2005) Quantum transport through a C60-X molecular bridge with the extra atom at the center. Phys Rev B 72:075421
Porath D, Levi Y, Tarabiah M et al (1997) Tunneling spectroscopy of isolated C60 molecules in the presence of charging effects. Phys Rev B 56:9829–9833
Porath D, Millo O (1997) Single electron tunneling and level spectroscopy of isolated C60 molecules. J Appl Phys 81:2241
Amman M, Wilkins R, Ben-Jacob E et al (1991) Analytic solution for the current-voltage characteristic of two mesoscopic tunnel junctions coupled in series. Phys Rev B 43:1146–1149
Allemand PM, Koch A, Wudl F et al (1991) Two different fullerenes have the same cyclic voltammetry. J Am Chem Soc 113:1050–1051
Imahori H, Tkachenko NV, Vehmanen V et al (2001) An extremely small reorganization energy of electron transfer in porphyrin?fullerene dyad. J Phys Chem A 105:1750–1756
Marcus RA (1956) The theory of oxidation-reduction reactions involving electron transfer. I J Chem Phys 24:966–978
Marcus RA, Sutin N (1985) Electron transfers in chemistry and biology. Biochim Biophys Acta Rev Bioenerg 811:265–322
Marcus RA (1993) Electron transfer reactions in chemistry: theory and experiment (Nobel lecture). Angew Chem Int Ed 32:1111–1121
Guldi DM, Illescas BM, Atienza CM et al (2009) Fullerene for organic electronics. Chem Soc Rev 38:1587–1597
Imahori H, Yamada H, Guldi DM et al (2002) Comparison of reorganization energies for intra- and intermolecular electron transfer. Angew Chem Int Ed 41:2344–2347
Schuster DI, Li K, Guldi DM et al (2007) Azobenzene-linked porphyrin-fullerene dyads. J Am Chem Soc 129:15973–15982
Imahori H, Guldi DM, Tamaki K et al (2001) Charge separation in a novel artificial photosynthetic reaction center lives 380 ms. J Am Chem Soc 123:6617–6628
Guldi DM, Imahori H, Tamaki K et al (2004) A molecular tetrad allowing efficient energy storage for 1.6 s at 163 K. J Phys Chem A 108:541–548
Ito O, Yamanaka K (2009) Roles of molecular wires between fullerenes and electron donors in photoinduced electron transfer. Bull Chem Soc Jpn 82:316–332
De la Torre G, Giacalone F, Segura JL et al (2005) Electronic communication through pi-conjugated wires in covalently linked porphyrin/C60 ensembles. Chem Eur J 11:1267–1280
Ikemoto J, Takimiya K, Aso Y et al (2002) Porphyrin?oligothiophene?fullerene triads as an efficient intramolecular electron-transfer system. Org Lett 4:309–311
Guldi DM, Giacalone F, de la Torre G et al (2005) Topological effects of a rigid chiral spacer on the electronic interactions in donor-acceptor ensembles. Chem Eur J 11:7199–7210
Oike T, Kurata T, Takimiya K et al (2005) Polyether-bridged sexithiophene as a complexation-gated molecular wire for intramolecular photoinduced electron transfer. J Am Chem Soc 127:15372–15373
D’Souza F, Maligaspe E, Ohkubo K et al (2009) Photosynthetic reaction center mimicry: low reorganization energy driven charge stabilization in self-assembled cofacial zinc phthalocyanine dimer-fullerene conjugate. J Am Chem Soc 131:8787–8797
Megiatto JD, Schuster DI, Abwandner S et al (2010) [2]Catenanes decorated with porphyrin and [60]fullerene groups: design, convergent synthesis, and photoinduced processes. J Am Chem Soc 132:3847–3861
Takai A, Chkounda M, Eggenspiller A et al (2010) Efficient photoinduced electron transfer in a porphyrin tripod-fullerene supramolecular complex via pi-pi interactions in nonpolar media. J Am Chem Soc 132:4477–4489
De la Escosura A, Martinez-Diaz MV, Guldi DM et al (2006) Stabilization of charge-separated states in phthalocyanine-fullerene ensembles through supramolecular donor-acceptor interactions. J Am Chem Soc 128:4112–4118
Metzger RM (2006) Unimolecular rectifiers and what lies ahead. Colloids Surf A 284–285:2–10
Metzger RM (2006) Unimolecular rectifiers: methods and challenges. Anal Chim Acta 568:146–155
Aviram A, Ratner MA (1974) Molecular rectifiers. Chem Phys Lett 29:277–283
Viani L, dos Santos MC (2006) Comparative study of lower fullerenes doped with boron and nitrogen. Solid State Commun 138:498–501
Xie R, Bryant GW, Zhao J et al (2003) Tailorable acceptor C60-nBn and donor C60-mNm pairs for molecular electronics. Phys Rev Lett 90:206602/1–206602/4
Metzger RM (2003) One-molecule-thick devices: rectification of electrical current by three Langmuir-Blodgett monolayers. Synth Met 137:1499–1501
Metzger RM, Baldwin JW, Shumate WJ et al (2003) Electrical rectification in a Langmuir-Blodgett monolayer of dimethyanilinoazafullerene sandwiched between gold electrodes. J Phys Chem B 107:1021–1027
Wang B, Zhou Y, Ding X et al (2006) Conduction mechanism of Aviram-Ratner rectifiers with single pyridine-s-C60 oligomers. J Phys Chem B 110:24505–24512
Gayathri SS, Patnaik A (2006) Electrical rectification from a fullerene[60]-dyad based metal-organic-metal junction. Chem Commun (Cambridge, UK) 1977–1979
Matino F, Arima V, Piacenza M et al (2009) Rectification in supramolecular zinc porphyrin/fulleropyrrolidine dyads self-organized on gold(111). Chemphyschem 10:2633–2641
Acharya S, Song H, Lee J et al (2009) An amphiphilic C60 penta-addition derivative as a new U-type molecular rectifier. Org Electron 10:85–94
Koiry SP, Jha P, Aswal DK et al (2010) Diodes based on bilayers comprising of tetraphenyl porphyrin derivative and fullerene for hybrid nanoelectronics. Chem Phys Lett 485:137–141
Joachim C, Gimzewski JK (1997) An electromechanical amplifier using a single molecule. Chem Phys Lett 265:353–357
Joachim C, Gimzewski JK, Tang H (1998) Physical principles of the single-C60 transistor effect. Phys Rev B: Condens Matter Mater Phys 58:16407–16417
Park H, Park J, Lim AKL et al (2000) Nanomechanical oscillations in a single-C60 transistor. Nature (London) 407:58–60
Park H, Lim AKL, Alivisatos AP et al (1999) Fabrication of metallic electrodes with nanometer separation by electromigration. Appl Phys Lett 75:301
Winkelmann CB, Roch N, Wernsdorfer W et al (2009) Superconductivity in a single-C60 transistor. Nat Phys 5:876–879
Roch N, Winkelmann CB, Florens S et al (2008) Kondo effect in a C60 single-molecule transistor. Phys Status Solid B 245:1994–1997
Mentovich ED, Belgorodsky B, Kalifa I et al (2010) 1-Nanometer-sized active-channel molecular quantum-dot transistor. Adv Mater 22:2182–2186
Morita T, Lindsay S (2008) Reduction-induced switching of single-molecule conductance of fullerene derivatives. J Phys Chem B 112:10563–10572
Ortiz AL, Rivera DM, Athans AJ et al (2009) Regioselective addition of N-(4-thiocyanatophenyl)pyrrolidine addends to fullerenes. Eur J Org Chem 3396–3403:S3396/1–S3396/25
Ortiz AL, Echegoyen L (2010) Unexpected and selective formation of an (e, e, e, e)-tetrakis-[60]fullerene derivative via electrolytic retro-cyclopropanation of a D2h-hexakis-[60]fullerene adduct. J Mater Chem 21:1362–1364
Zhang S, Lukoyanova O, Echegoyen L (2006) Synthesis of fullerene adducts with terpyridyl- or pyridylpyrrolidine groups in trans-1 positions. Chem Eur J 12:2846–2853
Yu M, Lourie O, Dyer MJ et al (2000) Strength and breaking mechanism of multiwalled carbon nanotubes under tensile load. Science 287:637–640
Hamada N, Sawada S, Oshiyama A (1992) New one-dimensional conductors: graphitic microtubules. Phys Rev Lett 68:1579–1581
Pillai SK, Ray SS, Moodley M (2007) Purification of single-walled carbon nanotubes. J Nanosci Nanotechnol 7:3011–3047
Journet C, Maser WK, Bernier P et al (1997) Large-scale production of single-walled carbon nanotubes by the electric-arc technique. Nature 388:756–758
Guo T, Nikolaev P, Thess A et al (1995) Catalytic growth of single-walled manotubes by laser vaporization. Chem Phys Lett 243:49–54
Bonard J, Croci M, Conus F et al (2002) Watching carbon nanotubes grow. Appl Phys Lett 81:2836
Marchand M, Journet C, Guillot D et al (2009) Growing a carbon nanotube atom by atom: “and yet it does turn”. Nano Lett 9:2961–2966
Meyyappan M (2009) A review of plasma enhanced chemical vapour deposition of carbon nanotubes. J Phys D 42:213001
Hou S, Chung D, Lin T (2009) Flame synthesis of carbon nanotubes in a rotating counterflow. J Nanosci Nanotechnol 9:4826–4833
Sun BM, Liu YC, Ding ZY (2009) Carbon nanotubes preparation using carbon monoxide from the pyrolysis flame. Adv Mater Res 87–88:104–109
Zhang L, Zaric S, Tu X et al (2008) Assessment of chemically separated carbon nanotubes for nanoelectronics. J Am Chem Soc 130:2686–2691
Pillai SK, Ray SS, Moodley M (2008) Purification of multi-walled carbon nanotubes. J Nanosci Nanotechnol 8:6187–6207
Matlhoko L, Pillai SK, Ray SS et al (2008) Purification of laser synthesized SWCNTs by different methods: a comparative study. J Nanosci Nanotechnol 8:6023–6030
Matlhoko L, Pillai SK, Moodley M et al (2009) A comparison of purification procedures for multi-walled carbon nanotubes produced by chemical vapor deposition. J Nanosci Nanotechnol 9:5431–5435
Hersam MC (2008) Progress towards monodisperse single-walled carbon nanotubes. Nat Nanotechnol 3:387–394
Collins PG, Arnold MS, Avouris P (2001) Engineering carbon nanotubes and nanotube circuits using electrical breakdown. Science 292:706–709
Krupke R, Hennrich F, Lohneysen H et al (2003) Separation of metallic from semiconducting single-walled carbon nanotubes. Science 301:344–347
Arnold MS, Green AA, Hulvat JF et al (2006) Sorting carbon nanotubes by electronic structure using density differentiation. Nat Nanotechnol 1:60–65
Wei L, Lee CW, Li L et al (2008) Assessment of (n, m) selectively enriched small diameter single-walled carbon nanotubes by density differentiation from cobalt-incorporated MCM-41 for macroelectronics. Chem Mater 20:7417–7424
Zheng M, Jagota A, Strano MS et al (2003) Structure-based carbon nanotube sorting by sequence-dependent DNA assembly. Science 302:1545–1548
Zheng M, Jagota A, Semke ED et al (2003) DNA-assisted dispersion and separation of carbon nanotubes. Nat Mater 2:338–342
Huang X, Mclean RS, Zheng M (2005) High-resolution length sorting and purification of DNA-wrapped carbon nanotubes by size-exclusion chromatography. Anal Chem 77:6225–6228
Zheng M, Semke ED (2007) Enrichment of single chirality carbon nanotubes. J Am Chem Soc 129:6084–6085
Tu X, Zheng M (2008) A DNA-based approach to the carbon nanotube sorting problem. Nano Res 1:185–194
Zhang L, Tu X, Welsher K et al (2009) Optical characterizations and electronic devices of nearly pure (10,5) single-walled carbon nanotubes. J Am Chem Soc 131:2454–2455
Paolucci D, Franco MM, Iurlo M et al (2008) Singling out the electrochemistry of individual single-walled carbon nanotubes in solution. J Am Chem Soc 130:7393–7399
Kavan L, Rapta P, Dunsch L (2000) In situ Raman and Vis-NIR spectroelectrochemistry at single-walled carbon nanotubes. Chem Phys Lett 328:363–368
Kavan L, Rapta P, Dunsch L et al (2001) Electrochemical tuning of electronic structure of single-walled carbon nanotubes: in-situ Raman and Vis-NIR study. J Phys Chem B 105:10764–10771
Melle-Franco M, Marcaccio M, Paolucci D et al (2004) Cyclic voltammetry and bulk electronic properties of soluble carbon nanotubes. J Am Chem Soc 126:1646–1647
Guldi DM, Marcaccio M, Paolucci D et al (2003) Single-wall carbon nanotube-ferrocene nanohybrids: observing intramolecular electron transfer in functionalized SWNTs. Angew Chem Int Ed 42:4206–4209
Zheng M, Diner BA (2004) Solution redox chemistry of carbon nanotubes. J Am Chem Soc 126:15490–15494
Pénicaud A, Poulin P, Derré A et al (2005) Spontaneous dissolution of a single-wall carbon nanotube salt. J Am Chem Soc 127:8–9
Wang Z, Pedrosa H, Krauss T et al (2007) Reply. Phys Rev Lett 98:019702
Dukovic G, Wang F, Song D et al (2005) Structural dependence of excitonic optical transitions and band-gap energies in carbon nanotubes. Nano Lett 5:2314–2318
Saito R, Fujita M, Dresselhaus G et al (1992) Electronic structure of chiral graphene tubules. Appl Phys Lett 60:2204
Perello DJ, Chulim S, Chae SJ et al (2010) Anomalous Schottky barriers and contact band-to-band tunneling in carbon nanotube transistors. ACS Nano 4:3103–3108
Tans SJ, Devoret MH, Dai H et al (1997) Individual single-wall carbon nanotubes as quantum wires. Nature 386:474–477
Zhong Z, Gabor NM, Sharping JE et al (2008) Terahertz time-domain measurement of ballistic electron resonance in a single-walled carbon nanotube. Nat Nanotechnol 3:201–205
Yao Z, Kane C, Dekker C (2000) High-field electrical transport in single-wall carbon nanotubes. Phys Rev Lett 84:2941–2944
Frank S, Poncharal P, Wang ZL et al (1998) Carbon nanotube quantum resistors. Science 280:1744–1746
Bachtold A, Hadley P, Nakanishi T et al (2001) Logic circuits with carbon nanotube transistors. Science 294:1317–1320
Javey A, Guo J, Paulsson M et al (2004) High-field quasiballistic transport in short carbon nanotubes. Phys Rev Lett 92:106804
Guo X, Nuckolls C (2009) Functional single-molecule devices based on SWNTs as point contacts. J Mater Chem 19:5470–5473
Bruque NA, Ashraf MK, Beran GJO et al (2009) Conductance of a conjugated molecule with carbon nanotube contacts. Phys Rev B Condens Matter Mater Phys 80:155455/1–155455/13
Shen X, Sun L, Benassi E et al (2010) Spin filter effect of manganese phthalocyanine contacted with single-walled carbon nanotube electrodes. J Chem Phys 132:054703/1–054703/6
Feldman AK, Steigerwald ML, Guo X et al (2008) Molecular electronic devices based on single-walled carbon nanotube electrodes. Acc Chem Res 41:1731–1741
Guo X, Small JP, Klare JE et al (2006) Covalently bridging gaps in single-walled carbon nanotubes with conducting molecules. Science 311:356–359
Whalley AC, Steigerwald ML, Guo X et al (2007) Reversible switching in molecular electronic devices. J Am Chem Soc 129:12590–12591
Wilson NR, Macpherson JV (2009) Carbon nanotube tips for atomic force microscopy. Nat Nanotechnol 4:483–491
Tans SJ, Verschueren ARM, Dekker C (1998) Room-temperature transistor based on a single carbon nanotube. Nature 393:49–52
Derycke V, Martel R, Appenzeller J et al (2001) Carbon nanotube inter- and intramolecular logic gates. Nano Lett 1:453–456
Javey A, Tu R, Farmer DB et al (2005) High performance n-type carbon nanotube field-effect transistors with chemically doped contacts. Nano Lett 5:345–348
Kim SM, Jang JH, Kim KK et al (2009) Reduction-controlled viologen in bisolvent as an environmentally stable n-type dopant for carbon nanotubes. J Am Chem Soc 131:327–331
Klinke C, Chen J, Afzali A et al (2005) Charge transfer induced polarity switching in carbon nanotube transistors. Nano Lett 5:555–558
Zhang Z, Liang X, Wang S et al (2007) Doping-free fabrication of carbon nanotube based ballistic CMOS devices and circuits. Nano Lett 7:3603–3607
Ding L, Wang S, Zhang Z et al (2009) Y-contacted high-performance n-type single-walled carbon nanotube field-effect transistors: scaling and comparison with Sc-contacted devices. Nano Lett 9:4209–4214
Martel R, Derycke V, Lavoie C et al (2001) Ambipolar electrical transport in semiconducting single-wall carbon nanotubes. Phys Rev Lett 87:256805
Xu G, Liu F, Han S et al (2008) Low-frequency noise in top-gated ambipolar carbon nanotube field effect transistors. Appl Phys Lett 92:223114
Yu WJ, Kim UJ, Kang BR et al (2009) Adaptive logic circuits with doping-free ambipolar carbon nanotube transistors. Nano Lett 9:1401–1405
Bandaru PR, Daraio C, Jin S et al (2005) Novel electrical switching behaviour and logic in carbon nanotube Y-junctions. Nat Mater 4:663–666
Kim D, Huang J, Rao BK et al (2006) Pseudo Y-junction single-walled carbon nanotube based ambipolar transistor operating at room temperature. IEEE Trans Nanotechnol 5:731–736
Rosenblatt S, Yaish Y, Park J et al (2002) High performance electrolyte gated carbon nanotube transistors. Nano Lett 2:869–872
Allen B, Kichambare P, Star A (2007) Carbon nanotube field-effect-transistor-based biosensors. Adv Mater 19:1439–1451
Katsura T, Yamamoto Y, Maehashi K et al (2008) High-performance carbon nanotube field-effect transistors with local electrolyte gates. Jpn J Appl Phys 47:2060–2063
Liu S, Shen Q, Cao Y et al (2010) Chemical functionalization of single-walled carbon nanotube field-effect transistors as switches and sensors. Coord Chem Rev 254:1101–1116
Zhao Y, Hu L, Grüner G et al (2008) A tunable photosensor. J Am Chem Soc 130:16996–17003
Huang SC, Artyukhin AB, Misra N et al (2010) Carbon nanotube transistor controlled by a biological ion pump gate. Nano Lett 10:1812–1816
Javey A, Guo J, Wang Q et al (2003) Ballistic carbon nanotube field-effect transistors. Nature 424:654–657
Li S, Yu Z, Yen S et al (2004) Carbon nanotube transistor operation at 2.6 GHz. Nano Lett 4:753–756
Dürkop T, Getty SA, Cobas E et al (2004) Extraordinary mobility in semiconducting carbon nanotubes. Nano Lett 4:35–39
Martin-Fernandez I, Sansa M, Esplandiu MJ et al (2010) Massive manufacture and characterization of single-walled carbon nanotube field effect transistors. Microelectron Eng 87:1554–1556
Li D, Müller MB, Gilje S et al (2008) Processable aqueous dispersions of graphene nanosheets. Nat Nanotechnol 3:101–105
Novoselov KS, Geim AK, Morozov SV et al (2004) Electric field effect in atomically thin carbon films. Science 306:666–669
Chen JH, Jang C, Xiao S et al (2008) Intrinsic and extrinsic performance limits of graphene devices on SiO2. Nat Nanotechnol 3:206–209
Lemme MC (2009) Current status of graphene transistors. Solid State Phenomena 156–158:499–509
Novoselov KS, McCann E, Morozov SV et al (2006) Unconventional quantum Hall effect and Berry’s phase of 2pi in bilayer graphene. Nat Phys 2:177–180
Ozyilmaz B, Jarillo-Herrero P, Efetov D et al (2007) Electronic transport and quantum hall effect in bipolar graphene p-n-p junctions. Phys Rev Lett 99:166804
Dubois SM, Zanolli Z, Declerck X et al (2009) Electronic properties and quantum transport in Graphene-based nanostructures. Eur Phys J B 72:1–24
Shibata N, Nomura K (2009) Fractional quantum Hall effects of graphene and its bilayer. J Phys Soc Jpn 78:104708/1–104708/7
Darancet P, Wipf N, Berger C et al (2008) Quenching of the quantum Hall effect in multilayered epitaxial graphene: the role of undoped planes. Phys Rev Lett 101:116806
Abanin DA, Novoselov KS, Zeitler U et al (2007) Dissipative quantum hall effect in graphene near the Dirac point. Phys Rev Lett 98:196806
Novoselov KS, Jiang Z, Zhang Y et al (2007) Room-temperature quantum hall effect in graphene. Science 315:1379
Kang YS, Seelaboyina R, Lahiri I et al (2010) Synthesis of graphene and its applications: a review. Crit Rev Solid State Mater Sci 35:52–71
Mohiuddin TMG, Zhukov AA, Elias DC et al (2009) Transverse spin transport in graphene. Int J Mod Phys B 23:2641–2646
Ponomarenko LA, Yang R, Mohiuddin TM et al (2009) Effect of a high-k environment on charge carrier mobility in graphene. Phys Rev Lett 102:206603/1–206603/4
Bolotin KI, Sikes KJ, Hone J et al (2008) Temperature-dependent transport in suspended graphene. Phys Rev Lett 101:096802/1–096802/4
Nair RR, Blake P, Grigorenko AN et al (2008) Fine structure constant defines visual transparency of graphene. Science 320:1308
Blake P (2008) Graphene-based liquid crystal device. Nano Lett 8:1704–1708
Booth TJ, Blake P, Nair RR et al (2008) Macroscopic graphene membranes and their extraordinary stiffness. Nano Lett 8:2442–2446
Wu J, Pisula W, Mullen K (2007) Graphenes as potential material for electronics. Chem Rev 107:718–747
Allen MJ, Tung VC, Kaner RB (2010) Honeycomb carbon: a review of graphene. Chem Rev 110:132–145
Castro Neto AH, Guinea F, Peres NMR et al (2009) The electronic properties of graphene. Rev Mod Phys 81:109–162
Geim AK (2009) Graphene: status and prospects. Science 324:1530–1534
Rao CNR, Biswas K, Subrahmanyam KS et al (2009) Graphene, the new nanocarbon. J Mater Chem 19:2457
Eda G, Lin Y, Miller S et al (2008) Transparent and conducting electrodes for organic electronics from reduced graphene oxide. Appl Phys Lett 92:233305/1–233305/3
Novoselov KS, Jiang D, Schedin F et al (2005) Two-dimensional atomic crystals. Proc Natl Acad Sci USA 102:10451–10453
Gass MH, Bangert U, Bleloch AL et al (2008) Free-standing graphene at atomic resolution. Nat Nanotechnol 3:676–681
Huc V, Bendiab N, Rosman N et al (2008) Large and flat graphene flakes produced by epoxy bonding and reverse exfoliation of highly oriented pyrolytic graphite. Nanotechnology 19:455601
Shukla A, Kumar R, Mazher J et al (2009) Graphene made easy: high quality, large-area samples. Solid State Commun 149:718–721
Mermin N (1968) Crystalline order in two dimensions. Phys Rev 176:250–254
Meyer JC, Geim AK, Katsnelson MI et al (2007) The structure of suspended graphene sheets. Nature 446:60–63
Stolyarova E, Rim KT, Ryu S et al (2007) High-resolution scanning tunneling microscopy imaging of mesoscopic graphene sheets on an insulating surface. Proc Natl Acad Sci USA 104:9209–9212
Sakhaeepour A (2009) Elastic properties of single-layered graphene sheet. Solid State Commun 149:91–95
Lee C, Wei X, Kysar JW et al (2008) Measurement of the elastic properties and intrinsic strength of monolayer graphene. Science 321:385–388
Balandin AA, Ghosh S, Bao W et al (2008) Superior thermal conductivity of single-layer graphene. Nano Lett 8:902–907
Borysiuk J, Bozek R, Strupinski W et al (2010) Graphene growth on C and Si-face of 4 H-SiC – TEM and AFM studies. Mater Sci Forum 645–648:577–580
Berger C, Song Z, Li X et al (2006) Electronic confinement and coherence in patterned epitaxial graphene. Science 312:1191–1196
Morozov SV, Novoselov KS, Katsnelson MI et al (2008) Giant intrinsic carrier mobilities in graphene and its bilayer. Phys Rev Lett 100:016602/1–016602/4
Yong V, Tour JM (2010) Theoretical efficiency of nanostructured graphene-based photovoltaics. Small 6:313–318
Kim KS, Zhao Y, Jang H et al (2009) Large-scale pattern growth of graphene films for stretchable transparent electrodes. Nature 457:706–710
Gomez De Arco L, Zhang Y, Schlenker CW et al (2010) Continuous, highly flexible, and transparent graphene films by chemical vapor deposition for organic photovoltaics. ACS Nano 4:2865–2873
Geim AK, Novoselov KS (2007) The rise of graphene. Nat Mater 6:183–191
Katsnelson MI, Novoselov KS, Geim AK (2006) Chiral tunnelling and the Klein paradox in graphene. Nat Phys 2:620–625
Partoens B, Peeters F (2006) From graphene to graphite: electronic structure around the K point. Phys Rev B 74:075404
Girit CO, Meyer JC, Erni R et al (2009) Graphene at the edge: stability and dynamics. Science 323:1705–1708
Joseph Joly VL, Kiguchi M, Hao Si-Jia et al (2010) Observation of magnetic edge state in graphene nanoribbons. Phys Rev B 81:245428
Matte HSSR, Subrahmanyam KS, Rao CNR (2009) Novel magnetic properties of graphene: presence of both ferromagnetic and antiferromagnetic features and other aspects. J Phys Chem C 113:9982–9985
Ugeda MM, Brihuega I, Guinea F et al (2010) Missing atom as a source of carbon magnetism. Phys Rev Lett 104:96804
Castro EV, Peres NMR, Lopes dos Santos JMB (2008) Localized states at zigzag edges of multilayer graphene and graphite steps. Europhys Lett 84:17001
Takai K, Suzuki T, Enoki T et al (2010) Structure and magnetic properties of curved graphene networks and the effects of bromine and potassium adsorption. Phys Rev B 81:205420
Enoki T, Takai K (2008) Unconventional electronic and magnetic functions of nanographene-based host-guest systems. Dalton Trans 29:3773–3781
Kim WY, Kim KS (2010) Tuning molecular orbitals in molecular electronics and spintronics. Acc Chem Res 43:111–120
Enoki T, Kobayashi Y, Fukui K (2007) Electronic structures of graphene edges and nanographene. Int Rev Phys Chem 26:609–645
Zhou SY, Gweon GH, Fedorov AV et al (2007) Substrate-induced bandgap opening in epitaxial graphene. Nat Mater 6:770–775
Hass J, Varchon F, Millán-Otoya J et al (2008) Why multilayer graphene on 4 H-SiC(0001¯) behaves like a single sheet of graphene. Phys Rev Lett 100:125504
Novoselov KS, Geim AK, Morozov SV et al (2005) Two-dimensional gas of massless Dirac fermions in graphene. Nature 438:197–200
McCann E (2006) Asymmetry gap in the electronic band structure of bilayer graphene. Phys Rev B 74:161403
Castro EV, Novoselov KS, Morozov SV et al (2007) Biased bilayer graphene: semiconductor with a gap tunable by the electric field effect. Phys Rev Lett 99:216802/1–216802/4
Morozov SV, Novoselov KS, Schedin F et al (2005) Two-dimensional electron and hole gases at the surface of graphite. Phys Rev B Condens Matter Mater Phys 72:201401/1–201401/4
Wang D, Choi D, Li J et al (2009) Self-assembled TiO2-graphene hybrid nanostructures for enhanced Li-ion insertion. ACS Nano 3:907–914
Paek SM, Yoo E, Honma I (2009) Enhanced cyclic performance and lithium storage capacity of SnO2/graphene nanoporous electrodes with three-dimensionally delaminated flexible structure. Nano Lett 9:72–75
Yu A, Roes I, Davies A et al (2010) Ultrathin, transparent, and flexible graphene films for supercapacitor application. Appl Phys Lett 96:253105
Vivekchand SRC, Rout CS, Subrahmanyam KS et al (2008) Graphene-based electrochemical supercapacitors. J Chem Sci 120:9–13
Wakabayashi K, Harigaya K (2003) Magnetic structure of nano-graphite Möbius ribbon. J Phys Soc Jpn 72:998–1001
Harigaya K, Yamashiro A, Shimoi Y et al (2004) Theoretical study on novel electronic properties in nanographite materials. J Phys Chem Solids 65:123–126
Harigaya K, Enoki T (2002) Theory on the mechanisms of novel magnetism in stacked nanographite. Mol Cryst Liq Cryst 386:205–209
Harigaya K, Kobayashi Y, Kawatsu N et al (2004) Tuning magnetism and novel electronic wave interference patterns in nanographite materials. Physica E Low Dimens Syst Nanostruct 22:708–711
Makarova TL (2004) Magnetic properties of carbon structures. Semiconductors 38:615–638
Enoki T, Kawatsu N, Shibayama Y et al (2001) Magnetism of nano-graphite and its assembly. Polyhedron 20:1311–1315
Wu J, Becerril HA, Bao Z et al (2008) Organic solar cells with solution-processed graphene transparent electrodes. Appl Phys Lett 92:263302/1–263302/3
Wang Y, Chen X, Zhong Y et al (2009) Large area, continuous, few-layered graphene as anodes in organic photovoltaic devices. Appl Phys Lett 95:063302/1–063302/3
Kumar A, Zhou C (2010) The race to replace tin-doped indium oxide: which material will win? ACS Nano 4:11–14
Matyba P, Yamaguchi H, Eda G et al (2010) Graphene and mobile ions: the key to all-plastic, solution-processed light-emitting devices. ACS Nano 4:637–642
Wu J, Agrawal M, Becerril HA et al (2010) Organic light-emitting diodes on solution-processed graphene transparent electrodes. ACS Nano 4:43–48
Tung VC, Chen L, Allen MJ et al (2009) Low-temperature solution processing of graphene-carbon nanotube hybrid materials for high-performance transparent conductors. Nano Lett 9:1949–1955
Eda G, Chhowalla M (2010) Chemically derived graphene oxide: towards large-area thin-film electronics and optoelectronics. Adv Mater 22:2392–2415
Li X, Li C, Zhu H et al (2010) Hybrid thin films of graphene nanowhiskers and amorphous carbon as transparent conductors. Chem Commun 46:3502–3504
Wang X, Zhi L, Tsao N et al (2008) Transparent carbon films as electrodes in organic solar cells. Angew Chem Int Ed 47:2990–2992
Tang CW, VanSlyke SA (1987) Organic electroluminescent diodes. Appl Phys Lett 51:913
Sun T, Wang ZL, Shi ZJ et al (2010) Multilayered graphene used as anode of organic light emitting devices. Appl Phys Lett 96:133301
Tongay S, Schumann T, Hebard AF (2009) Graphite based Schottky diodes formed on Si, GaAs, and 4H-SiC substrates. Appl Phys Lett 95:222103
O’Regan B, Grätzel M (1991) A low-cost, high-efficiency solar cell based on dye-sensitized colloidal TiO2 films. Nature 353:737–740
Kim SR, Parvez MK, Chhowalla M (2009) UV-reduction of graphene oxide and its application as an interfacial layer to reduce the back-transport reactions in dye-sensitized solar cells. Chem Phys Lett 483:124–127
Péchy P, Renouard T, Zakeeruddin SM et al (2001) Engineering of efficient panchromatic sensitizers for nanocrystalline TiO2-based solar cells. J Am Chem Soc 123:1613–1624
Zhu H, Wei J, Wang K et al (2009) Applications of carbon materials in photovoltaic solar cells. Solar Energy Mater Solar Cells 93:1461–1470
Kay A (1996) Low cost photovoltaic modules based on dye sensitized nanocrystalline titanium dioxide and carbon powder. Solar Energy Mater Solar Cells 44:99–117
Wang X, Zhi L, Muellen K (2008) Transparent, conductive graphene electrodes for dye-sensitized solar cells. Nano Lett 8:323–327
Yang N, Zhai J, Wang D et al (2010) Two-dimensional graphene bridges enhanced photoinduced charge transport in dye-sensitized solar cells. ACS Nano 4:887–894
Sun S, Gao L, Liu Y (2010) Enhanced dye-sensitized solar cell using graphene-TiO2 photoanode prepared by heterogeneous coagulation. Appl Phys Lett 96:083113
Tang YB, Lee CS, Xu J et al (2010) Incorporation of graphenes in nanostructured TiO2 films via molecular grafting for dye-sensitized solar cell application. ACS Nano 4:3482–3488
Thompson BC, Frechet JMJ (2008) Polymer-fullerene composite solar cells. Angew Chem Int Ed 47:58–77
Liu Q, Liu Z, Zhang X et al (2009) Polymer photovoltaic cells based on solution-processable graphene and P3HT. Adv Funct Mater 19:894–904
Xu Y, Long G, Huang L et al (2010) Polymer photovoltaic devices with transparent graphene electrodes produced by spin-casting. Carbon 48:3308–3311
Yin Z, Wu S, Zhou X et al (2010) Electrochemical deposition of ZnO nanorods on transparent reduced graphene oxide electrodes for hybrid solar cells. Small 6:307–312
Guo CX, Yang HB, Sheng ZM et al (2010) Layered graphene/quantum dots for photovoltaic devices. Angew Chem Int Ed 49:3014–3017
Liang M, Luo B, Zhi L (2009) Application of graphene and graphene-based materials in clean energy-related devices. Int J Energy Res 33:1161–1170
Yin B, Liu Q, Yang L et al (2010) Buffer layer of PEDOT: PSS/graphene composite for polymer solar cells. J Nanosci Nanotechnol 10:1934–1938
Liu Z, He D, Wang Y et al (2010) Solution-processable functionalized graphene in donor/acceptor-type organic photovoltaic cells. Solar Energy Mater Solar Cells 94:1196–1200
Li SS, Tu KH, Lin CC et al (2010) Solution-processable graphene oxide as an efficient hole transport layer in polymer solar cells. ACS Nano 4:3169–3174
Liu Z, Liu Q, Huang Y et al (2008) Organic photovoltaic devices based on a novel acceptor material: graphene. Adv Mater 20:3924–3930
Liu Q, Liu Z, Zhang X et al (2008) Organic photovoltaic cells based on an acceptor of soluble graphene. Appl Phys Lett 92:223303
Liu Z, He D, Wang Y et al (2010) Graphene doping of P3HT:PCBM photovoltaic devices. Synth Met 160:1036–1039
Echtermeyer TJ, Lemme MC, Bolten J et al (2007) Graphene field-effect devices. Eur Phys J Spec Top 148:19–26
Williams JR, Dicarlo L, Marcus CM (2007) Quantum Hall effect in a gate-controlled p-n junction of graphene. Science 317:638–641
Lemme MC, Echtermeyer TJ, Baus M et al (2007) A graphene field-effect device. IEEE Electron Device Lett 28:282–284
Burghard M, Klauk H, Kern K (2009) Carbon-based field-effect transistors for nanoelectronics. Adv Mater 21:2586–2600
Cao Y, Steigerwald ML, Nuckolls C et al (2010) Current trends in shrinking the channel length of organic transistors down to the nanoscale. Adv Mater 22:20–32
Martin J, Akerman N, Ulbricht G et al (2008) Observation of electron–hole puddles in graphene using a scanning single-electron transistor. Nat Phys 4:144–148
Han M, Özyilmaz B, Zhang Y et al (2007) Energy band-gap engineering of graphene nanoribbons. Phys Rev Lett 98:206805
Li X, Wang X, Zhang L et al (2008) Chemically derived, ultrasmooth graphene nanoribbon semiconductors. Science 319:1229–1232
Zhao P, Chauhan J, Guo J (2009) Computational study of tunneling transistor based on graphene nanoribbon. Nano Lett 9:684–688
Zhang Q, Fang T, Xing H et al (2008) Graphene nanoribbon tunnel transistors. IEEE Electron Device Lett 29:1344–1346
Muñoz-Rojas F, Fernández-Rossier J, Brey L et al (2008) Performance limits of graphene-ribbon field-effect transistors. Phys Rev B 77:045301
Ryzhii V, Ryzhii M, Satou A et al (2008) Current-voltage characteristics of a graphene-nanoribbon field-effect transistor. J Appl Phys 103:094510
Ryzhii V, Ryzhii M, Satou A et al (2009) Device model for graphene bilayer field-effect transistor. J Appl Phys 105:104510
Chen Z, Lin Y, Rooks M et al (2007) Graphene nano-ribbon electronics. Physica E Low Dimens Syst Nanostruct 40:228–232
Ponomarenko LA, Schedin F, Katsnelson MI et al (2008) Chaotic dirac billiard in graphene quantum dots. Science 320:356–358
Zhang Y, Tang TT, Girit C et al (2009) Direct observation of a widely tunable bandgap in bilayer graphene. Nature 459:820–823
Kim S, Nah J, Jo I et al (2009) Realization of a high mobility dual-gated graphene field-effect transistor with Al2O3 dielectric. Appl Phys Lett 94:062107
Lin Y, Chiu H, Jenkins KA et al (2010) Dual-gate graphene FETs with $f_{T}$ of 50 GHz. IEEE Electron Device Lett 31:68–70
Anonymous (2008) Graphene 2.0. Nat Nanotechnol 3:517
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Pinzón, J.R., Villalta-Cerdas, A., Echegoyen, L. (2011). Fullerenes, Carbon Nanotubes, and Graphene for Molecular Electronics. In: Metzger, R. (eds) Unimolecular and Supramolecular Electronics I. Topics in Current Chemistry, vol 312. Springer, Berlin, Heidelberg. https://doi.org/10.1007/128_2011_176
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