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Ring-opening polymerization of bicyclic acetals, oxalactone, and oxalactam

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Polymerization Reactions

Part of the book series: Advances in Polymer Science ((POLYMER,volume 28))

Abstract

Reaction mechanisms of ring-opening polymerization and structures and properties of resulting polymers of bicyclic acetals including 6,8-dioxabicyclo[3.2.1]octane (abbreviated to DBO) and 6,8-dioxabicyclo[3.2.1]oct-3-ene (DBOE), bicyclic oxalactone 6,8-dioxabicyclo[3.2.1]octan-7-one (DBOO), bicyclic oxalactam 8-oxa-6-azabicyclo[3.2.1.]octan-7-one (BOL), and related hetero bicyclic compounds are reviewed. Polysaccharide analogues were prepared from DBO and DBOE. Novel macrocyclic oligoesters were obtained in high yields from DBOO. BOL yielded easily a novel hygroscopic polyamide membrane of high molecular weight.

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Authors and Affiliations

  1. Faculty of Agriculture, Nagoya University, Chikusa-ku, 464, Nagoya, Japan

    Hiroshi Sumitomo & Masahiko Okada

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  1. Hiroshi Sumitomo
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  2. Masahiko Okada
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© 1978 Springer-Verlag

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Sumitomo, H., Okada, M. (1978). Ring-opening polymerization of bicyclic acetals, oxalactone, and oxalactam. In: Polymerization Reactions. Advances in Polymer Science, vol 28. Springer, Berlin, Heidelberg. https://doi.org/10.1007/3-540-08885-7_2

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  • DOI: https://doi.org/10.1007/3-540-08885-7_2

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  • Publisher Name: Springer, Berlin, Heidelberg

  • Print ISBN: 978-3-540-08885-1

  • Online ISBN: 978-3-540-35798-8

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