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In situ study of the temperature stability of TiO1.05 titanium monooxide using synchrotron radiation

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Bulletin of the Russian Academy of Sciences: Physics Aims and scope

Abstract

The temperature stability of cubic TiO1.05 titanium monooxide is investigated. An in situ X-ray structural analysis is performed using synchrotron radiation in a high temperature vacuum chamber. It is found that under poor vacuum and at high heating rates of up to 1250°C, the structural transformations in TiO1.05 occur at 630°C. In particular, there is a phase transition from TiO1.05 (space group Fm-3m) to rhombohedraic Ti2O3 (space group R-3c) via Ti2.5O3 (space group Immm).

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Authors and Affiliations

  1. Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, 620990, Russia

    A. A. Valeeva & A. A. Rempel

  2. Ural Federal University named after First President of Russia B.N. Yeltsin, Yekaterinburg, 620002, Russia

    A. A. Valeeva & A. A. Rempel

  3. Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, Novosibirsk, 630090, Russia

    S. V. Tsybulya

Authors
  1. A. A. Valeeva
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  2. S. V. Tsybulya
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  3. A. A. Rempel
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Correspondence to A. A. Valeeva.

Additional information

Original Russian Text © A.A. Valeeva, S.V. Tsybulya, A.A. Rempel, 2013, published in Izvestiya Rossiiskoi Akademii Nauk. Seriya Fizicheskaya, 2013, Vol. 77, No. 2, pp. 156–159.

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Valeeva, A.A., Tsybulya, S.V. & Rempel, A.A. In situ study of the temperature stability of TiO1.05 titanium monooxide using synchrotron radiation. Bull. Russ. Acad. Sci. Phys. 77, 134–137 (2013). https://doi.org/10.3103/S1062873813020378

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  • DOI: https://doi.org/10.3103/S1062873813020378

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